Peroxide composition containing phenolic antioxidant

Claim 2

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent organic peroxide dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. an amount of phenolic antioxidant sufficient to reduce the rate of self induced homolytic decomposition of the organic peroxide at temperatures of from 0° C. to +5° C.

Claim 3

The peroxide composition of claim 1 wherein from 0.01 to about 5 mole percent of phenolic antioxidant, basis the organic peroxide, is used.

Claim 4

The peroxide composition of claim 1 wherein from 0.1 to about 2 mole percent of phenolic antioxidant, basis the organic peroxide, is used.

Claim 5

The peroxide composition of claim 2 wherein the phenolic antioxidant is selected from the group consisting of polyhydroxybenzenes, alkylated hydroquinones, alkylated phenols, bisphenols, and diphenols.

Claim 6

The peroxide composition of claim 1, 2 or 3 wherein the phenolic antioxidant is selected from the group consisting of: ##STR11## wherein n is the number 1 or 2; ##STR12## wherein R is hydrogen or hydroxy-substituted C 1 -C 4 alkyl, R' is hydrogen, C 1 -C 4 alkyl, phenyl, benzyl or hydroxy-substituted C 1 -C 4 alkyl, and R 1 and R 2 are each hydrogen or C 1 -C 6 alkyl; ##STR13## wherein R 3 is a C 4 -C 12 tertiary alkyl and m is the number 1, 2 or 3; ##STR14## wherein A is a divalent alkyl radical having from 1 to 4 carbon atoms, R 5 is a C 1 -C 12 alkyl or halo-substituted C 1 -C 12 alkyl, R 6 is hydrogen, C 1 -C 12 alkyl, cyclohexyl, or methylcyclohexyl, R 7 is hydrogen, C 1 -C 12 alkyl, R 8 is hydrogen or methyl, and R 9 is hydrogen or tertiary C 4 -C 12 alkyl, provided that when R 7 is hydrogen, R 8 is methyl; and ##STR15## wherein R 7 and R 9 are as defined above.

Claim 7

The peroxide composition of claim 5 where in: (i) graphic formula (b), R is hydrogen, R' is hydrogen, C 1 -C 2 alkyl or benzyl and R 1 and R 2 are tertiarybutyl or tertiaryamyl, (ii) graphic formula (c), R 3 is a tertiary C 4 -C 5 alkyl, (iii) graphic formula (d), (e) and (f) R 5 is a C 1 -C 5 alkyl or C 4 -C 5 tertiaryalkyl, R 6 is a C 1 -C 5 alkyl, and R 7 and R 9 are a C 4 -C 5 tertiaryalkyl.

Claim 8

The peroxide composition of claim 4 wherein the organic peroxide is an organic peroxydicarbonate ester, an organic peroxymonocarbonate ester, a diacyl peroxide, or an organic peroxyester.

Claim 9

The peroxide composition of claim 6 wherein the organic peroxide is a peroxydicarbonate ester having the graphic formula, ##STR16## wherein R 1 ' and R 1 " are each a C 2 -C 12 alkyl or C 6 -C 8 aryl radical.

Claim 10

The peroxide composition of claim 8 wherein the peroxydicarbonate is di-n-propyl peroxydicarbonate, di-isopropyl peroxydicarbonate, di-n-butyl peroxydicarbonate, di-secondarybutyl peroxydicarbonate and di-2-ethylhexylperoxydicarbonate.

Claim 11

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent of an organic peroxide selected from the group consisting of organic peroxydicarbonate ester, organic peroxymonocarbonate ester, diacyl peroxide or organic peroxyester dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. 0.01 to about 5 mole percent of phenolic antioxidant selected from the group consisting of: ##STR17## wherein n is the number 1 or 2; ##STR18## wherein R is hydrogen or hydroxy-substituted C 1 -C 4 alkyl, R' is hydrogen, C 1 -C 4 alkyl, phenyl, benzyl or hydroxy-substituted C 1 -C 4 alkyl, and R 1 and R 2 are each hydrogen or C 1 -C 6 alkyl; ##STR19## wherein R 3 is a C 4 -C 12 tertiary alkyl and m is the number 1, 2 or 3; ##STR20## wherein A is a divalent alkyl radical having from 1 to 4 carbon atoms, R 5 is a C 1 -C 12 alkyl or halo-substituted C 1 -C 12 alkyl, R 6 is hydrogen, C 1 -C 12 alkyl, cyclohexyl, or methylcyclohexyl, R 7 is hydrogen, C 1 -C 12 alkyl, R 8 is hydrogen or methyl, and R 9 is hydrogen or tertiary C 4 -C 12 alkyl, provided that when R 7 is hydrogen, R 8 is methyl; and ##STR21## wherein R 7 and R 9 are as defined above.

Claim 12

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent of an organic peroxide selected from the group consisting of organic peroxydicarbonate ester, organic peroxymonocarbonate ester, diacyl peroxide or organic peroxyester dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. 0.01 to about 5 mole percent of phenolic antioxidant selected from the group consisting of: ##STR17## wherein n is the number 1 or 2; ##STR18## wherein R is hydrogen or hydroxy-substituted C 1 -C 4 alkyl, R' is hydrogen, C 1 -C 4 alkyl, phenyl, benzyl or hydroxy-substituted C 1 -C 4 alkyl, and R 1 and R 2 are each hydrogen or C 1 -C 6 alkyl; ##STR19## wherein R 3 is a C 4 -C 12 tertiary alkyl and m is the number 1, 2 or 3; ##STR20## wherein A is a divalent alkyl radical having from 1 to 4 carbon atoms, R 5 is a C 1 -C 12 alkyl or halo-substituted C 1 -C 12 alkyl, R 6 is hydrogen, C 1 -C 12 alkyl, cyclohexyl, or methylcyclohexyl, R 7 is hydrogen, C 1 -C 12 alkyl, R 8 is hydrogen or methyl, and R 9 is hydrogen or tertiary C 4 -C 12 alkyl, provided that when R 7 is hydrogen, R 8 is methyl; and ##STR21## wherein R 7 and R 9 are as defined above.

Claim 13

The peroxide composition of claim 10 where in: (i) graphic formula (b), R is hydrogen, R' is hydrogen, C 1 -C 2 alkyl or benzyl and R 1 and R 2 are tertiarybutyl or tertiaryamyl, (ii) graphic formula (c), R 3 is a tertiary C 4 -C 5 alkyl, (iii) graphic formula (d), (e) and (f) R 5 is a C 1 -C 5 alkyl or C 4 -C 5 tertiaryalkyl, R 6 is a C 1 -C 5 alkyl, and R 7 and R 9 are a C 4 -C 5 tertiaryalkyl.

Claim 14

The peroxide composition of claim 10 wherein the organic peroxide is a peroxydicarbonate ester having the graphic formula, ##STR22## wherein R 1 ' and R 1 " are each a C 2 -C 12 alkyl or C 6 -C 8 aryl radical.

Claim 15

The peroxide composition of claim 11 wherein the organic peroxide is a peroxydicarbonate ester selected from the group di-n-propyl peroxydicarbonate, di-isopropylperoxydicarbonate, di-n-butyl peroxydicarbonate, di-secondarybutyl peroxydicarbonate and di-2-ethylhexylperoxydicarbonate.

Claim 16

The peroxide composition of claim 12 wherein from 0.1 to about 2 mole percent of phenolic antioxidant, basis the organic peroxide, is used.

Claim 17

The peroxide composition of claim 13 wherein from 0.1 to about 2 mole percent of phenolic antioxidant, basis the organic peroxide, is used.

Claim 18

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent organic peroxide dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. from 0.1 to about 2 mole percent of phenolic antioxidant selected from the group consisting of 2,6-di-tertiarybutyl-4-n-butylphenol and 2,6-di-tertiarybutyl-4-methylphenol.

Claim 19

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent organic peroxide dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. from 0.1 to about 2 mole percent of phenolic antioxidant selected from the group consisting of 2,6-di-tertiarybutyl-4-n-butylphenol and 2,6-di-tertiarybutyl-4-methylphenol.

Claim 20

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent of an organic peroxydicarbonate ester selected from the group consisting of di-n-propyl peroxydicarbonate, di-isopropyl peroxydicarbonate, di-n-butyl peroxydicarbonate, di-secondary butyl peroxydicarbonate and di-2-ethylhexyl peroxydicarbonate dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. 0.01 to about 5 mole percent of phenolic anti-oxidant selected from the group consisting of 2,6-di-tertiarybutyl-4-n-butylphenol and 2,6-di-tertiarybutyl-4-methylphenol.

Claim 21

A peroxide composition consisting essentially of: a. from about 10 to about 65 weight percent of an organic peroxydicarbonate ester selected from the group consisting of di-n-propyl peroxydicarbonate, di-isopropyl peroxydicarbonate, di-n-butyl peroxydicarbonate, di-secondary butyl peroxydicarbonate and di-2-ethylhexyl peroxydicarbonate dispersed in an aqueous medium containing sufficient surfactant to provide a stable dispersion, and b. 0.01 to about 5 mole percent of phenolic anti-oxidant selected from the group consisting of 2,6-di-tertiarybutyl-4-n-butylphenol and 2,6-di-tertiarybutyl-4-methylphenol.