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US4555439A Expired / Lapsed US ⏱️ 0.0 years remaining

Tough thermoplastic resin sheet-like material

Assignee: Kuraray Co Ltd
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Filing: 1984-01-13
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Granted: 1985-11-26
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Expires: 2004-01-13
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Abstract

Abstract According to the present invention, rolled sheet-like materials having superior mechanical properties, in particular toughness and high-impact properties, as well as superior heat resistance and showing no whitening can be provided. Such rolled sheet-like materials are manufactured by isotropically rolling sheet-like materials, which were obtained by melting, blending and forming the mixture consisting of thermoplastic resin having the degree of crystallinity of 10% or more of 20 to 90% by weight and flaky fillers of 10 to 80% by weight, to orientate a part of crystals after it was melted at the melting point of said sheet-like materials and then recrystallizing the melted crystals under the rolled condition.

Inventors

  • 👤 Ryuhei Ueeda
  • 👤 Kiyonobu Fujii
  • 👤 Hiroshi Narukawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 21:55
CPC Classifications
C; C08; C08K; C08K7/00; C08K3/00; C08K3/34; C08K2201/00; C08K2201/016; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/249921; Y10T428/31504; Y10T428/31725; Y10T428/31739; Y10T428/31786; Y10T428/31855; Y10T428/31938

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 134 words
A pressed sheet like material characterized in that whitening is not found in the superficial layer upon electron microscope scanning, comprising: (1) a thermoplastic resin having a degree of crystallinity of 10% or more and present in amounts of 20 to 90% by weight, and (2) flaky fillers of 10 to 80% by weight, the degree of orientation of crystals in the crystal plane parallel to the molecular chain of said resin being 55% or more; the percentage change in thickness of said sheet-like material being 2% or less; said sheet-like material being further characterized by the fact that it is pressed and has a notched Izod impact strength which is 2 or more times that of unpressed sheet-like material, and a toughness which is 1.5 or more times that of unpressed sheet-like material.
Claim 2
Dependent Claim 134 words
A pressed sheet like material characterized in that whitening is not found in the superficial layer upon electron microscope scanning, comprising: (1) a thermoplastic resin having a degree of crystallinity of 10% or more and present in amounts of 20 to 90% by weight, and (2) flaky fillers of 10 to 80% by weight, the degree of orientation of crystals in the crystal plane parallel to the molecular chain of said resin being 55% or more; the percentage change in thickness of said sheet-like material being 2% or less; said sheet-like material being further characterized by the fact that it is pressed and has a notched Izod impact strength which is 2 or more times that of unpressed sheet-like material, and a toughness which is 1.5 or more times that of unpressed sheet-like material.
Claim 3
Dependent Claim 19 words
A pressed sheet-like material as set forth in claim 1, in which said thermoplastic resin is polyethylene or polypropylene.
Claim 4
Dependent Claim 33 words
A pressed sheet-like material as set forth in claim 1, in which said thermoplastic resin is polyethylene having molecular weight of 50,000 or more or polypropylene having molecular weight of 250,000 or more.
Claim 5
Dependent Claim 16 words
A pressed sheet-like material as set forth in claim 1, in which said fillers are mica.
Claim 6
Dependent Claim 22 words
The sheet-like material of claim 1, wherein said material is obtained by means of a flat sheet press or a roll press.
Claim 7
Dependent Claim 22 words
The sheet-like material of claim 1 wherein said thermoplastic resin comprises polyethylene, polypropylene, nylon-6, nylon-66, polyethylene terephthalate, polybutylene terephthalate and mixtures thereof.
Claim 8
Dependent Claim 32 words
The sheet-like material of claim 1 wherein said flaky filler comprises mica, glass flakes, calcium carbonate, glass beads, silica, glass fibers, carbon fibers, aramide fibers, woodmeal, titanium compounds, talc and mixtures thereof.
Claim 9
Dependent Claim 19 words
The sheet-like material of claim 4 wherein said mica comprises phlogopite mica, muscovite mica, fluorine mica and mixtures thereof.
Claim 10
Dependent Claim 20 words
The sheet-like material of claim 7 wherein said flaky filler has an average particle diameter of up to 1.5 mm.
Claim 11
Dependent Claim 26 words
The sheet-like material of claim 1 wherein said material further comprises pigments, stabilizers, lubricants, silane compiling agents, ultraviolet light absorbers, heat deterioration inhibitors or mixtures thereof.

References Cited (Backward Citations)

JPS54161667A Cited
US4282277A Cited
US4277594A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-11-25 1989-05-27 1989-11-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-11-25 1993-05-27 1993-11-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-11-25 1997-05-27 1997-11-26 $7700.00 Window Closed / Lapsed

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