US4564690A
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Macrocyclic compounds
Assignee: Mitsubishi Chemical Corp
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Filing: 1982-12-06
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Granted: 1986-01-14
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Expires: 2002-12-06
Abstract
Abstract A macrocyclic compound represented by the following general formula: <IMAGE> (I) and a process for preparing thereof which comprises reacting an alpha , omega -dihalogenated hydrocarbon and an active methylene compound with a base in a solvent to obtain a macrocyclic compound represented by the following general formula (II): <IMAGE> (II) and then inducing the functional group of Y1, Y3 and Y5 by means of a hydrolysis, oxidation or such, and an uranyl ion capturing agent comprising a polymer chemically bonded to a functional group in a macrocyclic compound and preparation thereof.
Inventors
- 👤 Iwao Tabushi
- 👤 Yoshiaki Kobuke
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 15:53
CPC Classifications
C; C07; C07C; C07C255/00; C07C61/00; C07D; C07D323/00; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/3804; C07F9/3839; C07F9/40; C07F9/4003; C07F9/4006; C07F9/4025; C07F9/50; C07F9/53; C07F9/5329; C08; C08F; C08F8/00; C08F8/30; C22; C22B; C22B60/00; C22B60/02; C22B60/0204; C22B60/0217; C22B60/0252; C22B60/0265
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
238 words
A macrocyclic compound of formula (I) ##STR36## wherein X 1 , X 3 and X 5 are individually taken from the first class consisting of --COOH, ##STR37## --SO 3 H, --PO 3 H 2 and --PO 4 H 2 ; and X 2 , X 4 and X 6 are individually taken from the class consisting of said first class hydrogen, alkyl having 1-18 carbon atoms, phenyl, --COOR 2 , ##STR38## --COR 1 , --CN, --SOR 2 , ##STR39## --SO 2 R 2 , --NO 2 , --PO 3 R 21 R 22 and --PO 4 R 21 R 22 ; wherein R 1 is hydrogen, an alkyl having 1-18 carbon atoms, or a phenyl group, R 2 is an alkyl having 1-18 carbon atoms or a phenyl group, R 11 and R 12 are individually selected from the same group as R 1 , and R 21 and R 22 are individually selected from the same group as R 2 ; and W is a divalent group taken from --(CH 2 ) n -- wherein n=2-18 and wherein 0-9 (CH 2 ) groups have been replaced by a moiety selected from the group consisting of O, S, N--H, provided that any hetero atoms appearing within W are separated from each other by at least two carbon atoms and that the two terminal atoms of each W which are linked to non-W atoms of said compound are carbons.
Claim 2
Dependent Claim
238 words
A macrocyclic compound of formula (I) ##STR36## wherein X 1 , X 3 and X 5 are individually taken from the first class consisting of --COOH, ##STR37## --SO 3 H, --PO 3 H 2 and --PO 4 H 2 ; and X 2 , X 4 and X 6 are individually taken from the class consisting of said first class hydrogen, alkyl having 1-18 carbon atoms, phenyl, --COOR 2 , ##STR38## --COR 1 , --CN, --SOR 2 , ##STR39## --SO 2 R 2 , --NO 2 , --PO 3 R 21 R 22 and --PO 4 R 21 R 22 ; wherein R 1 is hydrogen, an alkyl having 1-18 carbon atoms, or a phenyl group, R 2 is an alkyl having 1-18 carbon atoms or a phenyl group, R 11 and R 12 are individually selected from the same group as R 1 , and R 21 and R 22 are individually selected from the same group as R 2 ; and W is a divalent group taken from --(CH 2 ) n -- wherein n=2-18 and wherein 0-9 (CH 2 ) groups have been replaced by a moiety selected from the group consisting of O, S, N--H, provided that any hetero atoms appearing within W are separated from each other by at least two carbon atoms and that the two terminal atoms of each W which are linked to non-W atoms of said compound are carbons.
Claim 3
Dependent Claim
163 words
The macrocyclic compound of claim 1 wherein ##STR40## wherein X 1 , X 3 and X 5 are individually taken from the first class consisting of --COOH, ##STR41## --SO 3 H, --PO 3 H 2 and --PO 4 H 2 ; and X 2 , X 4 and X 6 are individually taken from the class consisting of said first class hydrogen, alkyl having 1-4 carbon atoms, phenyl, --COOR 2 , ##STR42## --COR 1 , --CN, --SOR 2 , ##STR43## --SO 2 R 2 , --NO 2 , --PO 3 R 21 R 22 and --PO 4 R 21 R 22 ; wherein R 1 is hydrogen, an alkyl having 1-18 carbon atoms, or a phenyl group, R 2 is an alkyl having 1-18 carbon atoms or a phenyl group, R 11 and R 12 are individually selected from the same group as R 1 , and R 21 and R 22 are individually selected from the same group as R 2 .
Claim 4
Dependent Claim
9 words
The compounds of claim 1 wherein n=6 to 10.
Claim 5
Dependent Claim
9 words
The compounds of claim 3 wherein n=7 to 9.
Claim 6
Dependent Claim
7 words
The compounds of claim 4 whererin n=8.
Claim 7
Dependent Claim
34 words
The compounds of claim 1 wherein W is --(CH 2 ) n -- or --(CH 2 ) 2 Y(CH 2 ) 2 Y(CH 2 ) 2 -- wherein Y is O, S or N--H.
Claim 8
Dependent Claim
9 words
The compounds of claim 6 wherein Y is O.
Claim 9
Dependent Claim
48 words
The compounds of claim 1 wherein X 1 , X 3 , and X 5 are --COOH and X 2 , X 4 , and X 6 are individually selected from --COOH, --COO(CH 2 CH 3 ), --CN, and --PO 3 (CH 2 CH 3 ) 2 .
Claim 10
Dependent Claim
27 words
A macrocyclic compound as defined in claim 1, wherein the compound represented by the above-shown general formula (I) is 1,1,10,10,19,19-hexacarboxy-cycloheptacosane represented by the following chemical formula: ##STR44##
Claim 11
Dependent Claim
27 words
A macrocyclic compound as defined in claim 1, wherein the compound represented by the above-shown general formula (I) is 1,10,19-tricarboxy-1,10,19-tricyano-4,7,13,16,22,25-hexaoxacycloheptacosane represented by the following chemical formula: ##STR45##
Claim 12
Dependent Claim
27 words
A macrocyclic compound as defined in claim 1, wherein the compound represented by the above-shown general formula (I) is 1,10,19-tricarboxy-1,10,19-triphosphonocycloheptacosane represented by the following chemical formula: ##STR46##
References Cited (Backward Citations)
JPS53141295A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1989-01-13 | 1989-07-15 | 1990-01-14 | $2000.00 | Window Closed / Lapsed |
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