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US4578445A Expired / Lapsed US ⏱️ 0.0 years remaining

Halogen-containing lens material

Assignee: Kureha Corp
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Filing: 1985-03-27
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Granted: 1986-03-25
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Expires: 2005-03-27
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Abstract

Abstract A lens material having a refractive index n D 20 of at least 1.57 or more and an Abbe's number ν of at least 30, comprising: a copolymer comprising (I) 10 to 85% by weight of a halogen-containing monomer represented by the following formula (1), (II) 15 to 90% by weight of a halogen-containing monomer represented by the following formula (2), and (III) 0 to 20% by weight of a monomer copolymerizable with the above mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): ##STR1## wherein: D represents ##STR2## in which n represents an integer selected from the group consisting of 0, 1, and 2; each R 1 represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X 1 and X 2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X 3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X 1 , X 2 , and X 3 contains at least one bromine or iodine; ##STR3## wherein: each R 2 represents hydrogen or a methyl group; p represents an integer selected from the group consisting of 0, 1, 2, and 3; X 4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2, 3, 4, and 5. An example of the copolymer is 1-methacryloxy-2,2-di(bromomethyl)-3-bromopropane/methacryloxypolyethyoxy-2,4,6-tribromobenzene/styrene/divinylbenzene having a n D 20 of 1.596 and a ν of 35.3.

Inventors

  • 👤 Teruo Sakagami
  • 👤 Yasufumi Fujii
  • 👤 Naohiro Murayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 18:17
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/22; C08F220/26; C08F220/30; C08F220/302; C08F222/00; C08F222/10; C08F222/1006; C08F222/102

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 315 words
A lens having a refractive index n D 20 of at least 1.57 and an Abbe's number ν of at least 30 or more, which lens is made of a copolymer comprising: a copolymer comprising 10 to 85% by weight of a halogen-containing monomer (I) represented by the formula (1) set forth below, 15 to 90% by weight of a halogen-containing monomer (II) represented by the formula (2) set forth below, and 0 to 20% by weight of a monomer (III) copolymerizable with the above-mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): ##STR9## wherein D represents ##STR10## in which: n represents an integer selected from the group consisting of 0, 1, and 2; each R 1 represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X 1 and X 2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a number selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X 3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X 1 , X 2 , and X 3 contains at least one bromine or iodine atom; ##STR11## wherein each R 2 represents hydrogen or a methyl group; p represents an integer selected from the group consisting of 0, 1, 2, and 3; X 4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2, 3, 4, and 5.
Claim 2
Dependent Claim 315 words
A lens having a refractive index n D 20 of at least 1.57 and an Abbe's number ν of at least 30 or more, which lens is made of a copolymer comprising: a copolymer comprising 10 to 85% by weight of a halogen-containing monomer (I) represented by the formula (1) set forth below, 15 to 90% by weight of a halogen-containing monomer (II) represented by the formula (2) set forth below, and 0 to 20% by weight of a monomer (III) copolymerizable with the above-mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): ##STR9## wherein D represents ##STR10## in which: n represents an integer selected from the group consisting of 0, 1, and 2; each R 1 represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X 1 and X 2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a number selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X 3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X 1 , X 2 , and X 3 contains at least one bromine or iodine atom; ##STR11## wherein each R 2 represents hydrogen or a methyl group; p represents an integer selected from the group consisting of 0, 1, 2, and 3; X 4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2, 3, 4, and 5.
Claim 3
Dependent Claim 25 words
A lens material as claimed in claim 1, wherein the monomer (I) is selected from the group consisting of 1-methacryloxy-2,2-di(bromomethyl)-3-bromopropane, 1-(3-methacryloxy-2-hydroxy-propoxy)-2,2-di(bromomethyl)-3-methacryloxypropane, 1,3-dimethacryloxy-2,2-di(bromomethyl)propane, 1,3-diacryloxyethoxy-2,2-di(bromomethyl)propane and 1-acryloxyethoxy-2,2-di(bromomethyl)-3-bromopropane.
Claim 4
Dependent Claim 31 words
A lens material as claimed in claim 1, wherein the monomer (II) is selected from the group consisting of 1-methacryloxyethoxy-2,4,6-tribromobenzene, 1-methacryloxydiethoxy-2,4,6-tribromobenzene, 1-methacryloxypolyethoxy-2,4,6-tribromobenzene, 1-methacryloxy-2,4,6-tribromobenzene, 1-acryloxyethoxy-2,4,6-tribromobenzene, 1-acryloxydiethoxy-2,4,6-tribromobenzene, 1-acryloxypolyethoxy-2,4,6-tribromobenzene, 1-acryloxyethoxy-2,4,6-triiodobenzene, 1-acryloxydiethoxy-2,4,6-triiodobenzene, 1-acryloxypolyethoxy-2,4,6-triiodobenzene and 1-methacryloxypropyoxy-2,4,6-tribromobenzene.
Claim 5
Dependent Claim 40 words
A lens material as claimed in claim 1, wherein the monomer (I) is a halogen-containing monomer of the formula (1) in which X 3 represents no D, and the monomer (III) is a comonomer having a plurality of ethylenical unsaturation.
Claim 6
Dependent Claim 38 words
A lens material as claimed in claim 1, wherein the monomer (I) is a halogen-containing monomer of the formula in which X 3 represents D, and the monomer (III) is a comonomer having no plurality of ethylenical unsaturation.

References Cited (Backward Citations)

US3210326A Cited
US3165502A Cited
US3277053A Cited
US3817913A Cited
JPS4969788A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-03-24 1989-09-23 1990-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-03-24 1993-09-23 1994-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-03-24 1997-09-23 1998-03-25 $7700.00 Window Closed / Lapsed

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