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US4582111A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation absorbing surfaces

Assignee: 3M Co
•
Filing: 1983-03-10
•
Granted: 1986-04-15
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Expires: 2003-03-10
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Abstract

Abstract A substantially radiation absorbing layer of metal having a microstructured surface characterized by a plurality of randomly positioned discrete protuberances of varying heights and shapes, which protuberances have a height of not less than 20 nanometers nor more than 1500 nm, and the bases of which contact the bases of substantially all adjacent protuberances is disclosed. The metal layer, which may be a coating on a variety of substrates, is useful as a radiation absorber (particularly solar). A method is disclosed for producing such layers.

Inventors

  • 👤 Robert D. Kuehn
  • 👤 Valdis Mikelsons
  • 👤 Gary L. Dorer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:35
CPC Classifications
F; F24; F24S; F24S70/00; F24S70/20; F24S70/25; F24S70/225; Y; Y02; Y02E; Y02E10/00; Y02E10/40

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 240 words
A method for absorbing radiant energy by a metal having a radiation absorbing surface said method comprising the steps: (a) preparing a metal having a substantially radiation absorbing surface by a process comprising the steps: (1) providing a substrate having on at least one surface thereof a first microstructured layer, said layer being an oxide or hydroxyoxide of a metal, selected from the group consisting of aluminum, magnesium and zinc or alloys thereof, which layer is a substantially complete conversion of a thin-film of said metal, the thickness of said thin-film prior to conversion being at least 5 nanometers and exhibiting a surface after said conversion characterized by a plurality of randomly positioned discrete protuberances of varying heights and shapes, which protuberances extend from said substrate surface a distance of not less than 20 nanometers nor more than 1500 nm, and the bases of which contact the bases of substantially all adjacent protuberances, (2) replicating said first microstructured layer by embossing, casting, or vacuum metallizing onto the surface of a second layer, said second layer being a metal, to provide said metal with a microstructured surface of randomly positioned discrete protuberances, and (3) removing said second layer from said first microstructured layer to provide said metal with a substantially radiation absorbing surface of randomly positioned discrete protuberances, and (b) orienting said radiation absorbing surface such that said microstructured surface is contacted with radiant energy so as to absorb radiant energy.
Claim 2
Independent Claim 240 words
A method for absorbing radiant energy by a metal having a radiation absorbing surface said method comprising the steps: (a) preparing a metal having a substantially radiation absorbing surface by a process comprising the steps: (1) providing a substrate having on at least one surface thereof a first microstructured layer, said layer being an oxide or hydroxyoxide of a metal, selected from the group consisting of aluminum, magnesium and zinc or alloys thereof, which layer is a substantially complete conversion of a thin-film of said metal, the thickness of said thin-film prior to conversion being at least 5 nanometers and exhibiting a surface after said conversion characterized by a plurality of randomly positioned discrete protuberances of varying heights and shapes, which protuberances extend from said substrate surface a distance of not less than 20 nanometers nor more than 1500 nm, and the bases of which contact the bases of substantially all adjacent protuberances, (2) replicating said first microstructured layer by embossing, casting, or vacuum metallizing onto the surface of a second layer, said second layer being a metal, to provide said metal with a microstructured surface of randomly positioned discrete protuberances, and (3) removing said second layer from said first microstructured layer to provide said metal with a substantially radiation absorbing surface of randomly positioned discrete protuberances, and (b) orienting said radiation absorbing surface such that said microstructured surface is contacted with radiant energy so as to absorb radiant energy.
Claim 3
Dependent Claim 22 words
The method according to claim 1 wherein said metallized second layer is selected from chromium, aluminum, copper, gold, nickel, and metal alloys.
Claim 4
Dependent Claim 25 words
The method according to claim 1 wherein the tips of said protuberances are spaced apart a distance in the range of 3 to 500 nm.
Claim 5
Dependent Claim 30 words
The method according to claim 1 wherein the average spacing between the tips of said protuberances is in the range of 1/10 and 1/4 the average height of the protuberances.
Claim 6
Dependent Claim 32 words
The method according to claim 1 wherein the radiant energy absorbance by said metal over the total solar range of said article is within the range of 70 percent to 98 percent.
Claim 7
Dependent Claim 14 words
The method according to claim 1 wherein said metal is a selective solar absorber.
Claim 8
Dependent Claim 15 words
The method according to claim 1 wherein said metal is a flat plate solar collector.

References Cited (Backward Citations)

US2891879A Cited
US3690944A Cited
US3666527A Cited
US4148294A Cited
US4138262A Cited
US4190321A Cited
US4252843A Cited
US4233107A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-14 1989-10-14 1990-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-14 1993-10-14 1994-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-14 1997-10-14 1998-04-15 $7700.00 Window Closed / Lapsed

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