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US4582589A Expired / Lapsed US ⏱️ 0.0 years remaining

pH sensor

Assignee: Terumo Corp
•
Filing: 1985-06-26
•
Granted: 1986-04-15
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Expires: 2005-06-26
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Abstract

Abstract A pH sensor includes a substrate formed of an electrically conductive carbon material. A hydrogen ion-sensitive layer is formed on the substrate surface. The layer is formed of an electrooxidation polymer of a nitrogen-containing aromatic compound selected from the group consisting of 1-aminopyrene and a mixture of 1-aminopyrene and pyridine.

Inventors

  • 👤 Norihiko Ushizawa
  • 👤 Tsutomu Murakami
  • 👤 Takeshi Shimomura
  • 👤 Noboru Oyama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 10:17
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; G01N27/333; G01N27/3335

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 52 words
A pH sensor comprising: a substrate formed of an electrically conductive carbon material; and a hydrogen ion-sensitive layer formed on the substrate surface, said hydrogen ion-sensitive layer being formed of an electrooxidation polymer of a nitrogen-containing aromatic compound selected from the group consisting of 1-aminopyrene and a mixture of 1-aminopyrene and pyridine.
Claim 2
Dependent Claim 52 words
A pH sensor comprising: a substrate formed of an electrically conductive carbon material; and a hydrogen ion-sensitive layer formed on the substrate surface, said hydrogen ion-sensitive layer being formed of an electrooxidation polymer of a nitrogen-containing aromatic compound selected from the group consisting of 1-aminopyrene and a mixture of 1-aminopyrene and pyridine.
Claim 3
Dependent Claim 31 words
The pH sensor according to claim 1, wherein said hydrogen ion-sensitive layer is formed of an electrolytic oxidation copolymer consisting of substantially the same molar amount of 1-aminopyrene and pyridine units.
Claim 4
Dependent Claim 22 words
The pH sensor according to claim 1, wherein the thickness of the hydrogen ion-sensitive layer ranges between 1 μm and 1 mm.
Claim 5
Dependent Claim 27 words
The pH sensor according to claim 1, which further comprises a protective layer formed on the hydrogen ion-sensitive layer, said protective layer being pervious to hydrogen ions.
Claim 6
Dependent Claim 32 words
The pH sensor according to claim 4, wherein said protective layer is formed of a material selected from the group consisting of poly(hydroxyethyl methacrylate), nitro cellulose, acetyl cellulose, regenerated cellulose and polycarbonate.
Claim 7
Dependent Claim 21 words
The pH sensor according to claim 4, wherein the thickness of the protective layer ranges between 0.1 μm and 300 μm.
Claim 8
Dependent Claim 41 words
The pH sensor according to claim 1, which further comprises a protective layer formed on the hydrogen ion-sensitive layer, said protective layer being pervious to hydrogen ions; and the thickness of said protective layer being between 0.1 μm and 300 μm.
Claim 9
Dependent Claim 31 words
The pH sensor according to claim 7, wherein said hydrogen ion-sensitive layer is formed of an electrolytic oxidation copolymer consisting of substantially the same molar amount of 1-aminopyrene and pyridine units.
Claim 10
Dependent Claim 22 words
The pH sensor according to claim 8 wherein said hydrogen ion-sensitive layer formed of said electrooxidation copolymer is partially in reduced form.

References Cited (Backward Citations)

US3869354A Cited
US4148305A Cited
US4273636A Cited
US4271002A Cited
US4454007A Cited
US4492622A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-04-14 1989-10-14 1990-04-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-04-14 1993-10-14 1994-04-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-04-14 1997-10-14 1998-04-15 $7700.00 Window Closed / Lapsed

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