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US4600685A Expired / Lapsed US ⏱️ 0.0 years remaining

Patterning process using ladder-type organosiloxane resin and process for production of electronic devices utilizing said patterning process

Assignee: Fujitsu Ltd
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Filing: 1985-05-29
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Granted: 1986-07-15
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Expires: 2005-05-29
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Abstract

Abstract A patterning process is provided wherein a material to be etched is coated with a ladder type organosiloxane resin, the coated resin is irradiated with energy rays according to a desired pattern, the irradiated resin is subjected to a development treatment, and then, the material is etched by using the resin left after the development as a mask. The ladder type organosiloxane resin used is represented by the formula: ##STR1## wherein each R 1 is independently selected from alkyl (Cl-6) groups, and phenyl and halophenyl groups, R 2 , R 3 , R 4 and R 5 are independently selected from hydrogen, alkoxy (Cl-3) groups, a hydroxyl group and alkyl (Cl-3) groups, and n is a number giving a Mw of about 1,000 to about 1,000,000. The patterning process can be advantageously employed for the production of electronic devices.

Inventors

  • 👤 Toshisuke Kitakohji
  • 👤 Shiro Takeda
  • 👤 Minoru Nakajima
  • 👤 Hiroshi Tokunaga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 04:32
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6921; H10P14/6922; H10P14/6926; G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; H10P14/65; H10P14/6516; H10P14/6536; H10P14/6538; H10P14/6539; H10P14/63; H10P14/6326; H10P14/6342; H10P14/66; H10P14/668; H10P14/6681; H10P14/6684; H10P14/6686

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 276 words
A process comprising the steps of: coating a substrate with a ladder-type organosiloxane resin represented by the general formula: ##STR4## wherein: each R 1 is independently selected from alkyl groups having 1 to 6 carbon atoms, and phenyl and halophenyl groups; R 2 and R 3 are indpendently selected from alkoxy groups having 1 to 3 carbon atoms, a hydroxyl group and alkyl groups having 1 to 3 carbon atoms; R 4 and R 5 are independently selected from hydrogen and alkyl groups having 1 to 3 carbon atoms; and n is a number giving a weight average molecular weight of about 1,000 to 1,000,000 to the ladder-type organosiloxane resin, said ladder-type organosiloxane resin having a dispersivity of from about 1.5 to about 4; directly irradiating the coated organosiloxane resin with energy rays according to a desired pattern; subjecting the irradiated coated organosiloxane resin to a development treatment to remove the non-irradiated portion of the resin to form a mask of said ladder-type resin with said desired pattern; after forming said mask, heating said mask at a temperature of from 200° to 500° C. in an inert gas atmosphere, wherein said mask after said heating comprises said ladder-type resin; using said mask to etch a respective exposed part of said substrate; leaving at least a portion of said mask permanently on said substrate as an insulating layer; and heating said portion of said mask remaining as said insulating layer to a temperature of at least 450° C.; wherein said insulating layer after said heating, has said ladder-type structure and is provided with a low weight loss characteristic for a temperature of up to approximately 700° C.
Claim 2
Dependent Claim 276 words
A process comprising the steps of: coating a substrate with a ladder-type organosiloxane resin represented by the general formula: ##STR4## wherein: each R 1 is independently selected from alkyl groups having 1 to 6 carbon atoms, and phenyl and halophenyl groups; R 2 and R 3 are indpendently selected from alkoxy groups having 1 to 3 carbon atoms, a hydroxyl group and alkyl groups having 1 to 3 carbon atoms; R 4 and R 5 are independently selected from hydrogen and alkyl groups having 1 to 3 carbon atoms; and n is a number giving a weight average molecular weight of about 1,000 to 1,000,000 to the ladder-type organosiloxane resin, said ladder-type organosiloxane resin having a dispersivity of from about 1.5 to about 4; directly irradiating the coated organosiloxane resin with energy rays according to a desired pattern; subjecting the irradiated coated organosiloxane resin to a development treatment to remove the non-irradiated portion of the resin to form a mask of said ladder-type resin with said desired pattern; after forming said mask, heating said mask at a temperature of from 200° to 500° C. in an inert gas atmosphere, wherein said mask after said heating comprises said ladder-type resin; using said mask to etch a respective exposed part of said substrate; leaving at least a portion of said mask permanently on said substrate as an insulating layer; and heating said portion of said mask remaining as said insulating layer to a temperature of at least 450° C.; wherein said insulating layer after said heating, has said ladder-type structure and is provided with a low weight loss characteristic for a temperature of up to approximately 700° C.
Claim 3
Dependent Claim 243 words
A process comprising the steps of: forming a layer on a substrate having a lower wiring layer of a ladder-type organosiloxane resin represented by the general formula: ##STR5## wherein: each R 1 is independently selected from alkyl groups having 1 to 6 carbon atoms, and phenyl and halophenyl groups; each R 2 , R 3 , R 4 , and R 5 is independently selected from hydrogen, alkoxy groups having 1 to 3 carbon atoms, a hydroxyl group and alkyl groups having 1 to 3 carbon atoms; and n is a number giving a weight average molecular weight of about 1,000 to about 1,000,000 to the ladder-type resin, said ladder-type organosiloxane resin having a dispersivity of from about 1.5 to about 4; directly subjecting the resin layer to selective irradiation with energy rays and to a subsequent development treatment to remove the non-irradiated portion of the resin layer, so as to form through-holes in the resin layer for contacting said lower wiring layer; forming an upper wiring layer having portions connecting to the lower wiring layer via said through-holes and extending on the surface of the remaining portion of the resin layer; heating the remaining portion of the resin layer to a temperature of at least 450° C.; and wherein the remaining portion of the resin layer has said ladder-type structure of the organosiloxane resin, and is provided with a low weight loss characteristic for a temperature of up to approximately 700° C.
Claim 4
Dependent Claim 243 words
A process comprising the steps of: forming a layer on a substrate having a lower wiring layer of a ladder-type organosiloxane resin represented by the general formula: ##STR5## wherein: each R 1 is independently selected from alkyl groups having 1 to 6 carbon atoms, and phenyl and halophenyl groups; each R 2 , R 3 , R 4 , and R 5 is independently selected from hydrogen, alkoxy groups having 1 to 3 carbon atoms, a hydroxyl group and alkyl groups having 1 to 3 carbon atoms; and n is a number giving a weight average molecular weight of about 1,000 to about 1,000,000 to the ladder-type resin, said ladder-type organosiloxane resin having a dispersivity of from about 1.5 to about 4; directly subjecting the resin layer to selective irradiation with energy rays and to a subsequent development treatment to remove the non-irradiated portion of the resin layer, so as to form through-holes in the resin layer for contacting said lower wiring layer; forming an upper wiring layer having portions connecting to the lower wiring layer via said through-holes and extending on the surface of the remaining portion of the resin layer; heating the remaining portion of the resin layer to a temperature of at least 450° C.; and wherein the remaining portion of the resin layer has said ladder-type structure of the organosiloxane resin, and is provided with a low weight loss characteristic for a temperature of up to approximately 700° C.
Claim 5
Dependent Claim 35 words
A process according to claim 1 or 2 wherein n in said general formula is a number giving a weight average molecular weight of about 1,500 to about 200,000 to the ladder type organosiloxane resin.
Claim 6
Dependent Claim 26 words
A process according to claim 1 or 2 wherein R 1 in said general formula is selected from the group consisting of methyl and phenyl groups.
Claim 7
Dependent Claim 45 words
A process according to claim 1 or 2 wherein the ladder-type organosiloxane resin is used in the form of a solution of a 4 to 50% by weight concentration in at least one solvent selected from the group consisting of hydrocarbons, cellosolves, alcohols and ketones.
Claim 8
Dependent Claim 42 words
A process according to claim 1 or 2 wherein, prior to the irradiation with energy rays, the organosiloxane resin layer is pre-baked in an inert gas atmosphere at a temperature of from 50° to 200° C. for 30 minutes to 2 hours.
Claim 9
Dependent Claim 23 words
A process according to claim 2, wherein said layer of the ladder-type organosiloxane resin has a thickness of from 0.8 to 2.0 μm.
Claim 10
Dependent Claim 32 words
A process according to claim 2, wherein another layer of a ladder-type organosiloxane resin represented by said general formula is formed as a surface protecting insulating layer on the upper wiring layer.
Claim 11
Dependent Claim 23 words
A process according to claim 8, wherein said surface protecting insulating layer has a thickness in the range from 1.0 to 4.0 μm.
Claim 12
Dependent Claim 15 words
A process according to claim 1 or 2, wherein said energy rays are light rays.
Claim 13
Dependent Claim 14 words
A process according to claim 1 or 2, wherein said energy rays are X-rays.
Claim 14
Dependent Claim 15 words
A process according to claim 1 or 2, wherein said energy rays are light rays.
Claim 15
Dependent Claim 15 words
A process according to claim 1 or 2, wherein said energy rays are ion beams.
Claim 16
Dependent Claim 29 words
The process of claim 1, wherein said portion of the mask remaining as said insulating layer is provided with a thickness in the range from 0.8 to 2.0 micron.
Claim 17
Dependent Claim 39 words
The process of claim 2, wherein a further layer of said ladder-type organosiloxane resin is formed according to said forming step to provide a surface protecting insulating layer with a thickness in the range of 1.0 to 4.0 microns.

References Cited (Backward Citations)

US4041190A Cited
US4349609A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-07-14 1990-01-13 1990-07-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-07-14 1994-01-13 1994-07-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-07-14 1998-01-13 1998-07-15 $7700.00 Window Closed / Lapsed

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