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US4608189A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergents and liquid cleaners free of inorganic builders

Assignee: Henkel AG and Co KGaA
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Filing: 1985-05-08
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Granted: 1986-08-26
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Expires: 2005-05-08
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Abstract

Abstract Aqueous liquid laundering and cleaning detergent compositions, essentially free from inorganic builder salts, comprising: (a) 20-40 wt. % of a mixture of nonionic surfactants of the formula: RO--[CH.sub.2 --CH(CH.sub.3)--O]m--(CH.sub.2 --CH.sub.2 --O)n--H (I) where R is a C 10 -C 20 aliphatic hydrocarbon group; m=1-5; n=3-20; n>m; and the mixture is composed of: (i) 5-9 parts by weight of a Formula I compound where n=3-9, (ii) 1-5 parts by weight of a Formula I compound where n=10-20, and (iii) 0-6 parts by weight of a Formula I compound where m=1-3, and n=9-11; (b) 2-25 wt. % of a sodium, potassium, mono-, di- or trialkanolamine soap of a C 10 1-C 20 fatty acid; (c) 0.001-2 wt. % of a proteolytic enzyme; and (d) 5-25 wt. % C 2 14 C 4 mono- or polyhydroxy alcohol; wherein (a) and (b) together are 30-50 wt. % of the composition, and a 1% aqueous solution thereof has a pH of 6.5-9.

Inventors

  • 👤 Karlheinz Koch
  • 👤 Ingo Wegener
  • 👤 Brigitte Giesen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 17:01
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/38; C11D3/386; C11D3/38618; C11D10/00; C11D10/04; C11D10/045; C11D3/38663; C11D3/43; C11D1/00; C11D1/66; C11D1/72

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 297 words
A homogeneous aqueous liquid laundering and cleaning detergent composition, essentially free from inorganic builder salt consisting essentially of: (a) from about 20 to about 40 wt. % of a mixture of nonionic surfactants of the formula: RO--[CH.sub.2 --CH(CH.sub.3)--O].sub.m --(CH.sub.2 --CH.sub.2 --O).sub.n --H (I) wherein R is a C 10 -C 20 aliphatic hydrocarbon group which is linear or methylated in the 2-position and can be saturated or unsaturated, or R represents a mixture of such groups; m is a number from 1 to 5; n is a number from 3 to 20; n>m; and wherein the mixture of nonionic surfactants is composed of the following components: (i) from about 5 to about 9 parts by weight of at least one compound of the above Formula I wherein n=3 to 9, (ii) from about 1 to about 5 parts by weight of at least one compound of the above Formula I wherein n=10 to 20, and (iii) from 0 to about 6 parts by weight of a compound of the above Formula I wherein m=1 to 3 and n=9 to 11; (b) from about 2 to about 25 wt. % based on fatty acid of at least one sodium, potassium monoalkanolamine, dialkanolamine or trialkanolamine soap of a C 10 -C 20 saturated or monounsaturated fatty acid; (c) from about 0.001 to about 2 wt. % of at least one proteolytic enzyme; and (d) from about 5 to about 25 wt. % of at least one monohydroxy or polyhydroxy alcohol having 2 to 4 carbon atoms; wherein (a) and (b) taken together constitute from about 30 to about 50 wt. % of the detergent composition, and wherein a 1% aqueous solution of the detergent composition has a pH value in the range of from about 6.5 to about 9.
Claim 2
Dependent Claim 297 words
A homogeneous aqueous liquid laundering and cleaning detergent composition, essentially free from inorganic builder salt consisting essentially of: (a) from about 20 to about 40 wt. % of a mixture of nonionic surfactants of the formula: RO--[CH.sub.2 --CH(CH.sub.3)--O].sub.m --(CH.sub.2 --CH.sub.2 --O).sub.n --H (I) wherein R is a C 10 -C 20 aliphatic hydrocarbon group which is linear or methylated in the 2-position and can be saturated or unsaturated, or R represents a mixture of such groups; m is a number from 1 to 5; n is a number from 3 to 20; n>m; and wherein the mixture of nonionic surfactants is composed of the following components: (i) from about 5 to about 9 parts by weight of at least one compound of the above Formula I wherein n=3 to 9, (ii) from about 1 to about 5 parts by weight of at least one compound of the above Formula I wherein n=10 to 20, and (iii) from 0 to about 6 parts by weight of a compound of the above Formula I wherein m=1 to 3 and n=9 to 11; (b) from about 2 to about 25 wt. % based on fatty acid of at least one sodium, potassium monoalkanolamine, dialkanolamine or trialkanolamine soap of a C 10 -C 20 saturated or monounsaturated fatty acid; (c) from about 0.001 to about 2 wt. % of at least one proteolytic enzyme; and (d) from about 5 to about 25 wt. % of at least one monohydroxy or polyhydroxy alcohol having 2 to 4 carbon atoms; wherein (a) and (b) taken together constitute from about 30 to about 50 wt. % of the detergent composition, and wherein a 1% aqueous solution of the detergent composition has a pH value in the range of from about 6.5 to about 9.
Claim 3
Dependent Claim 27 words
A detergent composition in accordance with claim 1 wherein (a) and (b) taken together constitute from about 35 to about 45 wt. % of the detergent composition.
Claim 4
Dependent Claim 55 words
A detergent composition in accordance with claim 1 wherein there is present in (a) from about 6 to about 8 parts by weight of component (i) wherein m=1 to 3, and n=4 to 8; and from about 2 to about 4 parts by weight of component (ii) wherein m=1 to 4, and n=12 to 16.
Claim 5
Dependent Claim 48 words
A detergent composition in accordance with claim 1 wherein in (a) the R group in Formula I is a mixture of groups which are from 25 to 100 wt. % monounsaturated and from 0 to 75 wt. % saturated, and which contain from 12 to 18 carbon atoms.
Claim 6
Dependent Claim 58 words
A detergent composition in accordance with claim 1 wherein (b) is from about 5 to about 20 wt. % of a sodium or triethanolamine soap of fatty acids which comprise from about 40 to 100 wt. % oleyl groups and from 0 to about 60 wt. % saturated linear fatty acids having from 12 to 18 carbon atoms.
Claim 7
Dependent Claim 41 words
A detergent composition in accordance with claim 1 wherein (d) is a mixture of 1,2-propylene glycol, and at least one of ethanol and isopropanol, wherein the weight ratio of monohydroxy alcohol to 1,2-propylene glycol is from about 5:1 to about 1:5.
Claim 8
Dependent Claim 24 words
A detergent composition in accordance with claim 1 wherein from about 0.5 to about 10 wt. % of free alkanolamine is also present therein.
Claim 9
Dependent Claim 40 words
A detergent composition in accordance with claim 1 wherein from about 0.1 to about 3 wt. %, based on free acid, of at least one water-soluble salt of a polycarboxylic acid or of a polyphosphonic acid is also present therein.
Claim 10
Dependent Claim 35 words
A detergent composition in accordance with claim 8 wherein the water-soluble salt of a polycarboxylic acid is a water-soluble salt of citric acid, and is present in from about 0.5 to about 3 wt. %.
Claim 11
Dependent Claim 25 words
A detergent composition in accordance with claim 8 wherein the water-soluble salt of a polyphosphonic acid is a water-soluble salt of an aminoalkane polyphosphonic acid.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-08-25 1990-02-24 1990-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-08-25 1994-02-24 1994-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-08-25 1998-02-24 1998-08-26 $7700.00 Window Closed / Lapsed

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