US4611029A
Expired / Lapsed
US
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Process for continuously hydrolyzing ethylene-vinyl acetate
Assignee: Mitsubishi Chemical Corp
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Filing: 1984-12-24
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Granted: 1986-09-09
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Expires: 2004-12-24
Abstract
Abstract A process for continuously hydrolyzing ethylene-vinyl acetate copolymer which comprises feeding a methanol solution in which an ethylene-vinyl acetate copolymer having ethylene of 25 to 50 % by mole into the upper portion of a tower reactor and supplying an alkaline catalyst into the middle portion of the tower, and blowing a methanol vapor into the lower portion of the tower to remove a methyl acetate vapor together with a methanol vapor from the top of the tower and taking out the highly hydrolyzed ethylene-vinyl acetate copolymer from the bottom of the tower, and whereby a highly hydrolyzed ethylene-vinyl acetate copolymer is easily obtained in the presence of a small amount of alkaline catalyst.
Inventors
- 👤 Masazumi Takahashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 15:45
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/12; C08F2800/00; C08F2800/10
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
137 words
A process for continuously hydrolyzing an ethylene-vinyl acetate copolymer in the presence of an alkaline catalyst which comprises feeding a methanol solution consisting essentially of methanol and an ethylene-vinyl acetate copolymer having an ethylene content of 25 to 50% by mole into an upper portion of a tower reactor, supplying all of the alkaline catalyst into a middle portion of the tower in an amount of from 2 to 10 millimoles per 1 mole of vinyl acetate in the ethylene-vinyl acetate copolymer, blowing a methanol vapor into a lower portion of the tower, removing a methyl acetate vapor together with a methanol vapor from the top of the tower and taking out a highly hydrolyzed ethylene-vinyl acetate copolymer having a residual vinyl acetate unit of not more than 0.5% by mole from the bottom of the tower.
Claim 2
Dependent Claim
137 words
A process for continuously hydrolyzing an ethylene-vinyl acetate copolymer in the presence of an alkaline catalyst which comprises feeding a methanol solution consisting essentially of methanol and an ethylene-vinyl acetate copolymer having an ethylene content of 25 to 50% by mole into an upper portion of a tower reactor, supplying all of the alkaline catalyst into a middle portion of the tower in an amount of from 2 to 10 millimoles per 1 mole of vinyl acetate in the ethylene-vinyl acetate copolymer, blowing a methanol vapor into a lower portion of the tower, removing a methyl acetate vapor together with a methanol vapor from the top of the tower and taking out a highly hydrolyzed ethylene-vinyl acetate copolymer having a residual vinyl acetate unit of not more than 0.5% by mole from the bottom of the tower.
Claim 3
Dependent Claim
22 words
The process of claim 1, wherein the concentration of said copolymer in the methanol solution is from 25 to 60% by weight.
Claim 4
Dependent Claim
27 words
The process of claim 1, wherein said methanol vapor has a temperature equal to a boiling point of methanol under the internal pressure of the tower reactor.
Claim 5
Dependent Claim
19 words
The process of claim 1, wherein said alkaline catalyst is a strong base or an alcoholate of alkali metal.
Claim 6
Dependent Claim
15 words
The process of claim 4, wherein said strong base is caustic soda or caustic potash.
Claim 7
Dependent Claim
17 words
The process of claim 4, wherein said alcoholate of alkali metal is sodium methylate or potassium ethylate.
Claim 8
Dependent Claim
13 words
The process of claim 1, wherein said tower reactor is a plate column.
Claim 9
Dependent Claim
18 words
The process of claim 7, wherein said plate column is a perforated plate tower or a bubble-cap tower.
Claim 10
Dependent Claim
17 words
The process of claim 1, wherein the pressure within the tower is from 0.5 to 10 atms.
Claim 11
Dependent Claim
17 words
The process of claim 1, wherein the temperature in the tower is from 45° to 150° C.
Claim 12
Dependent Claim
49 words
The process of claim 2, wherein the methanol vapor is blown in an amount required for completely removing the methyl acetate produced during the hydrolyzing reaction, the pressure within the tower is from 0.5 to 10 atms. and the temperature in the tower is from 45° to 150° C.
References Cited (Backward Citations)
GB1120189A
Cited
US3560461A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-09-08 | 1990-03-10 | 1990-09-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-09-08 | 1994-03-10 | 1994-09-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-09-08 | 1998-03-10 | 1998-09-09 | $7700.00 | Window Closed / Lapsed |