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US4612352A
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Water-soluble or water-dispersible graft polymers, their preparation and their use
Assignee: BASF Corp
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Filing: 1984-11-19
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Granted: 1986-09-16
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Expires: 2004-11-19
Abstract
Abstract Water-soluble or water-dispersible graft polymers comprising at least 20% by weight, based on said graft polymer, of a hydrophilic graft constituent bonded to a carbon atom and at least one hydrophobic radical which is bonded to the graft constituent via a polyglycol ether chain, the polyglycol ether chain containing 2 to 200 ##STR1## groups. These graft polymers can be used individually, as mixtures or in combination with other active substances as, for example, antifoams, antistatic agents, builders, emulsifiers, padding assistants, wetting agents, paper deaerators, sludge dewatering assistants, textile assistants, greying inhibitors or detergents.
Inventors
- 👤 Paul Schafer
- 👤 Heinz Abel
- 👤 Christian Guth
- 👤 Albert Stehlin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 09:13
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3788; C08; C08F; C08F283/00; C08F283/06; D; D06; D06P; D06P1/00; D06P1/44; D06P1/60; D21; D21C; D21C3/00; D21C3/22; D21C3/28; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/46; D21H17/53
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
103 words
A water-soluble or water-dispersible graft polymer comprising: (a) as a parent chain an anionic, cationic, amphoteric or non-ionic polyalkylene oxide containing from 2 to 200 --C--C--O-- groups; (b) at least one hydrophobic radical bound to said polyalkylene oxide and comprising a straight or branched alkyl or alkenyl chain of 8 to 22 carbon atoms, alkylphenyl containing from 4 to 16 carbon atoms in the alkyl chain, or phenyl substituted with a phenyl group; and (c) at least 20% by weight of hydrophilic graft substituent derived from ethylenically unsturated polymerizable monomers containing hydrophilic groups and grafted onto carbon atoms in said polyalkylene oxide chain.
Claim 2
Dependent Claim
103 words
A water-soluble or water-dispersible graft polymer comprising: (a) as a parent chain an anionic, cationic, amphoteric or non-ionic polyalkylene oxide containing from 2 to 200 --C--C--O-- groups; (b) at least one hydrophobic radical bound to said polyalkylene oxide and comprising a straight or branched alkyl or alkenyl chain of 8 to 22 carbon atoms, alkylphenyl containing from 4 to 16 carbon atoms in the alkyl chain, or phenyl substituted with a phenyl group; and (c) at least 20% by weight of hydrophilic graft substituent derived from ethylenically unsturated polymerizable monomers containing hydrophilic groups and grafted onto carbon atoms in said polyalkylene oxide chain.
Claim 3
Dependent Claim
21 words
A graft polymer according to claim 1 wherein the hydrophilic groups of said hydrophilic side chains are acidic water solubilizing groups.
Claim 4
Dependent Claim
41 words
A graft polymer according to claim 1 wherein said polyalkylene oxide is non-ionic polyalkylene oxide, one hydrophobic radical is bound to one terminus of said non-ionic polyalkylene oxide, and the second terminal hydroxyl group of said polyalkylene oxide chain is unsubstituted.
Claim 5
Dependent Claim
72 words
A graft polymer according to claim 3, wherein the parent chain consists of a radical of an adduct of 2 to 200 mols of an alkylene oxide with 1 mol of an aliphatic monoalcohol having a least 8 carbon atoms, of a tri-, tetra-penta- or hexa-hydric aliphatic alcohol, of a phenol which is unsubstituted or substituted by alkyl, benzyl or phenyl, or of a fatty acid having 8 to 22 carbon atoms.
Claim 6
Dependent Claim
63 words
A graft polymer according to claim 4, wherein the parent chain consists of a radical of an adduct of 2 to 40 mols of ethylene oxide with 1 mol of a fatty alcohol or fatty acid, each having 12 to 22 carbon atoms, or with 1 mol of an alkylphenol having a total of 4 to 12 carbon atoms in the alkyl moiety.
Claim 7
Dependent Claim
72 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of an acid ester, or salt thereof, of an adduct of 2 to 100 mols of ethylene oxide with 1 mol of a fatty alcohol having 12 to 22 carbon atoms or with 1 mol of a phenol containing at least one benzyl group, one phenyl group or one alkyl group having at least 4 carbon atoms.
Claim 8
Dependent Claim
78 words
A graft polymer according to claim 6, which contains, in the parent chain, the radical of an anionic polyalkylene oxide adduct of the formula Y--O--(CH.sub.2 --CH.sub.2 O).sub.m X (1) wherein Y is alkyl or alkenyl, each having 8 to 22 carbon atoms, alkylphenyl having 4 to 16 carbon atoms in the alkyl moiety or o-phenylphenyl, X is the acid radical of an inorganic oxygen-containing acid or the radical of an organic acid and m is 2 to 40.
Claim 9
Dependent Claim
64 words
A graft polymer according to claim 7, which contains, in the parent chain, the radical of an anionic polyalkylene oxide adduct of the formula ##STR18## wherein Y' is octyl or nonyl, m 1 is 2 to 15 and X' is derived form sulfuric acid or o-phosphoric acid, and the adduct is in the form of the free acid or the sodium or ammonium salt.
Claim 10
Dependent Claim
69 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of a cationic polyalkylene oxide adduct of the formula ##STR19## wherein R 1 alkyl or alkenyl, each having 10 to 22 carbon atoms, one of the radicals X 1 and X 2 is hydrogen or methyl and the other is hydrogen and p and s are integers, the sum p+s being 3 to 25.
Claim 11
Dependent Claim
125 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of a cationic polyalkylene oxide adduct of the formula ##STR20## wherein R 1 is alkyl or alkenyl, each having 10 to 22 carbon atoms, R 2 is alkyl having 1 to 4 carbon atoms, hydroxyalkyl having 2 to 4 carbon atoms, carbamoylmethyl or benzyl, one of the radicals Y 1 and Y 2 is hydrogen and the other is phenyl, one of the radicals X 1 and X 2 is hydrogen or methyl and the other is hydrogen, An⊖ is the anion of an inorganic or organic acid, n 1 and n 2 are 0 or 1 and p and s are integers, the sum p+s being 3 to 25.
Claim 12
Dependent Claim
44 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of a monosulfuric acid ester of an adduct of 3 to 15 mols of ethylene oxide with 1 mol of a fatty amine having 12 to 22 carbon atoms.
Claim 13
Dependent Claim
24 words
A graft polymer according to claim 1, which contains, in the side chains, monocarboxylic acids having 3 to 5 carbon atoms as grafted-on monomers.
Claim 14
Dependent Claim
17 words
A graft polymer according to claim 12, which contains acrylic acid grafted on in the side chains.
Claim 15
Dependent Claim
43 words
A graft polymer according to claim 1, which comprises 5 to 80% by weight of an anionic, cationic, amphoteric or non-ionic polyalkylene oxide adduct in the parent chain and 95 to 20% by weight of the monomers grafted on in the side chain.
Claim 16
Dependent Claim
38 words
A graft polymer according to claim 14, which contains 5 to 50% by weight of the polyalkylene oxide adduct in the parent chain and 95 to 50% by weight of the monomers grafted on in the side chains.
Claim 17
Dependent Claim
78 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of an adduct of 2 to 40 mols of ethylene oxide with 1 mol of a fatty alcohol having 12 to 22 carbon atoms or with 1 mol of an alkylphenol having a total of 4 to 12 carbon atoms in the alkyl moiety, and, in the side chains, at least 30% by weight, based on the graft polymer, of grafted-on acrylic acid.
Claim 18
Dependent Claim
33 words
A graft polymer according to claim 16, which contains, as the parent chain, the radical of the adduct of 2 to 35 mols of ethylene oxide with 1 mol of octylphenol or nonylphenol.
Claim 19
Dependent Claim
58 words
A graft polymer according to claim 1, which contains, in the parent chain, the radical of an adduct of 3 to 40 mols of ethylene oxide with 1 mole of a fatty amine having 10 to 22 carbon atoms, and, in the side chains, at least 30% by weight, based on the graft polymer, of grafted-on acrylic acid.
Claim 20
Dependent Claim
14 words
An aqueous solution or emulsion, which comprises a graft polymer according to claim 1.
Claim 21
Dependent Claim
73 words
A process for the preparation of a water-soluble or water-dispersible graft polymer, which comprises bringing together (1) an anionic, cationic, amphoteric or non-ionic polyalkylene oxide adduct containing a hydrophobic radical and a polyglycol ether chain of 2 to 200 ##STR21## groups and (2) at least 20% by weight, based on the graft polymer, of an ethylenically unsaturated polymerisable monomer containing hydrophilic groups, and carrying out the polymerisation in the presence of a catalyst.
Claim 22
Dependent Claim
73 words
A process for the preparation of a water-soluble or water-dispersible graft polymer, which comprises bringing together (1) an anionic, cationic, amphoteric or non-ionic polyalkylene oxide adduct containing a hydrophobic radical and a polyglycol ether chain of 2 to 200 ##STR21## groups and (2) at least 20% by weight, based on the graft polymer, of an ethylenically unsaturated polymerisable monomer containing hydrophilic groups, and carrying out the polymerisation in the presence of a catalyst.
Claim 23
Dependent Claim
21 words
A process according to claim 20, wherein an organic or inorganic initiator which forms free radicals is used as the catalyst.
Claim 24
Dependent Claim
25 words
A graft polymer according to claim 4, wherein the parent chain is the adduct of 10 mols of ethylene oxide with 1 mol of nonylphenol.
Claim 25
Dependent Claim
33 words
A graft polymer according to claim 15 which contains 50% by weight of the adduct of 10 mols of ethylene oxide with 1 mol of nonylphenol and 50% by weight of acrylic acid.
Claim 26
Dependent Claim
33 words
A graft polymer according to claim 8, wherein the parent chain is the acid phosphoric acid ester of the adduct of 5 to 12 mols of ethylene oxide with 1 mol of p-nonylphenol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-09-15 | 1990-03-17 | 1990-09-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-09-15 | 1994-03-17 | 1994-09-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-09-15 | 1998-03-17 | 1998-09-16 | $7700.00 | Window Closed / Lapsed |