US4619983A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Copolymer for fluorine-containing elastomer having excellent low temperature resistance and alcohol resistance
Assignee: AGC Inc
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Filing: 1985-01-28
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Granted: 1986-10-28
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Expires: 2005-01-28
Abstract
Abstract A copolymer for an fluorine-containing elastomer having excellent low temperature resistance and alcohol resistance comprises vinylidene fluoride units and fluorovinyl ether units having the formula CF 2 =CFOX (X represents a C 3 -C 9 perfluoroalkyl group which has ether bond having 1-3 oxygen atom) at a molar ratio of vinylidene fluoride units to fluorovinyl ether units of 95:5 to 50:50 and at a total content of the units of at least 80 mole %.
Inventors
- 👤 Masaaki Yamabe
- 👤 Gen Kojima
- 👤 Hiroshi Wachi
- 👤 Shun-ichi Kodama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 09:25
CPC Classifications
C; C08; C08F; C08F216/00; C08F216/12; C08F216/14; C08F216/1408; C08F214/00; C08F214/18; C08F214/22; C08F214/222
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
177 words
A fluorine-containing elastomer having excellent low temperature resistance and alcohol resistance, which consists essentially of a copolymer composed of vinylidene fluoride units and fluorovinyl ether units having the formula CF 2 ═CFOX, wherein X is a C 3 -C 9 perfluoroalkyl group which has an ether bond or bonds having 1-3 oxygen atoms at a molar ratio of vinylidene fluoride units to fluorovinyl ether units of 91:9 to 72.3:27.7, and a total content of the units of at least 80 mole percent, based on the total copolymer, with the balance of up to 20 mole percent being at least one comonomer selected from the group consisting of chlorotrifluoroethylene, vinyl fluoride, ethylene, propylene, isobutylene, butene-1, perfluoro(propyl vinyl ether), perfluoro(methyl vinyl ether), ethyl vinyl ether, 2-chloroethyl vinyl ether, and vinyl monochloroacetate, wherein said elastomer has an inherent viscosity of about 0.54 to 2.13 dl/g. obtained in a 90:10 mixture of trifluorotrichloroethylene and dimethylformamide at 30° C., a thermal decomposition temperature of from 388° C. to 412° C. and a glass transition temperature of from -29° C. to -36° C.
Claim 2
Dependent Claim
177 words
A fluorine-containing elastomer having excellent low temperature resistance and alcohol resistance, which consists essentially of a copolymer composed of vinylidene fluoride units and fluorovinyl ether units having the formula CF 2 ═CFOX, wherein X is a C 3 -C 9 perfluoroalkyl group which has an ether bond or bonds having 1-3 oxygen atoms at a molar ratio of vinylidene fluoride units to fluorovinyl ether units of 91:9 to 72.3:27.7, and a total content of the units of at least 80 mole percent, based on the total copolymer, with the balance of up to 20 mole percent being at least one comonomer selected from the group consisting of chlorotrifluoroethylene, vinyl fluoride, ethylene, propylene, isobutylene, butene-1, perfluoro(propyl vinyl ether), perfluoro(methyl vinyl ether), ethyl vinyl ether, 2-chloroethyl vinyl ether, and vinyl monochloroacetate, wherein said elastomer has an inherent viscosity of about 0.54 to 2.13 dl/g. obtained in a 90:10 mixture of trifluorotrichloroethylene and dimethylformamide at 30° C., a thermal decomposition temperature of from 388° C. to 412° C. and a glass transition temperature of from -29° C. to -36° C.
Claim 3
Dependent Claim
22 words
The elastomer according to claim 1, wherein the content of said comonomer ranges from 0.5 to 2.5 mole % in the copolymer.
Claim 4
Dependent Claim
16 words
The elastomer according to claim 1, wherein said comonomer is vinyl monochloroacetate or 2-chloroethyl vinyl ether.
Claim 5
Dependent Claim
33 words
The elastomer according to claim 1, wherein said fluorovinyl ether units are selected from the group consisting of perfluoro(2-n-propoxy-propyl vinyl ether), perfluoro(3-methoxypropyl vinyl ether), perfluoro(2-methoxypropyl vinyl ether), perfluoro(2-methoxyethyl vinyl ether) and perfluoro(3,6,9-trioxa-5,8-dimethyl dodeca-1-ene).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-10-27 | 1990-04-28 | 1990-10-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-10-27 | 1994-04-28 | 1994-10-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-10-27 | 1998-04-28 | 1998-10-28 | $7700.00 | Window Closed / Lapsed |