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US4622347A Expired / Lapsed US ⏱️ 0.0 years remaining

Expandable polypropylene interpolymer particles

Assignee: Lyondell Chemical Technology LP
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Filing: 1986-04-07
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Granted: 1986-11-11
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Expires: 2006-04-07
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Abstract

Abstract A process for producing a polypropylenepolystyrene interpolymer which can be impregnated with a blowing agent and can then be expanded under normal conditions for polystyrene particles to low density, fine cell structure foams. The interpolymer must be viscbroken, lubricated and stress relaxed in order to foam at 100 DEG C. to densities less than 2.0 pcf.

Inventors

  • 👤 Kent D. Fudge

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 22:25
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/16; C08J9/18; C08F; C08F255/00; C08F255/02; C08J2351/00; C08J2351/06

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 183 words
A process for producing expandable polypropylene particles comprising (a) suspending in an aqueous medium, a copolymer of propylene and sufficient olefin comonomers to give said copolymer a melting peak of less than 140° C., with the aid of a suitable suspending agent system; (b) adding to said suspension vinyl aromatic monomer and a catalyst system such that the amount of monomer is 40 to 80% by weight based on copolymer plus monomer; (c) polymerizing said monomer in the interior of said copolymer to form a polypropylene-polyvinylaromatic monomer interpolymer; (d) separating said interpolymer from said suspension by acidifying, filtering, washing with water and drying in air; (e) extruding said interpolymer in admixture with a lubricant and cell control agent and a peroxide, if used, to viscbreak said interpolymer to a melt flow (condition L) of at least 10, under conditions to minimize orientation stress in the final extrudate; (f) impregnating said extrudate with a blowing agent to give expandable polypropylene-polyvinyl aromatic monomer interpolymers which can be expanded at 100° C. to fine cell structure foams of density less than 2.0 pounds per cubic foot.
Claim 2
Dependent Claim 183 words
A process for producing expandable polypropylene particles comprising (a) suspending in an aqueous medium, a copolymer of propylene and sufficient olefin comonomers to give said copolymer a melting peak of less than 140° C., with the aid of a suitable suspending agent system; (b) adding to said suspension vinyl aromatic monomer and a catalyst system such that the amount of monomer is 40 to 80% by weight based on copolymer plus monomer; (c) polymerizing said monomer in the interior of said copolymer to form a polypropylene-polyvinylaromatic monomer interpolymer; (d) separating said interpolymer from said suspension by acidifying, filtering, washing with water and drying in air; (e) extruding said interpolymer in admixture with a lubricant and cell control agent and a peroxide, if used, to viscbreak said interpolymer to a melt flow (condition L) of at least 10, under conditions to minimize orientation stress in the final extrudate; (f) impregnating said extrudate with a blowing agent to give expandable polypropylene-polyvinyl aromatic monomer interpolymers which can be expanded at 100° C. to fine cell structure foams of density less than 2.0 pounds per cubic foot.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein said olefin comonomer may be ethylene.
Claim 4
Dependent Claim 14 words
The process of claim 1 wherein said olefin comonomers may be ethylene and butene.
Claim 5
Dependent Claim 30 words
The process of claim 1 wherein said vinyl aromatic monomer is at least one monomer selected from the group consisting of styrene, alpha-methylstyrene, nuclearmethylstyrene, p-tert-butylstyrene, chlorostyrene, bromostyrene, and mixtures thereof.
Claim 6
Dependent Claim 23 words
The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as an emulsion of monomer and catalysts in water.
Claim 7
Dependent Claim 21 words
The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as a solution of catalyst in monomer.
Claim 8
Dependent Claim 20 words
The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide based on interpolymer.
Claim 9
Dependent Claim 26 words
The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide and 0.2-0.4% by weight zinc stearate based on interpolymer.
Claim 10
Dependent Claim 19 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise slow air cool of the extrudate.
Claim 11
Dependent Claim 23 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise cooling in a blob followed by grinding to small particles.
Claim 12
Dependent Claim 18 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise slow cool with warm water.
Claim 13
Dependent Claim 23 words
The process of claim 1 wherein said blowing agent is selected from the group consisting of aliphatic hydrocarbons, cycloaliphatic hydrocarbons, and halogenated hydrocarbons.

References Cited (Backward Citations)

US3144436A Cited
US3743611A Cited
US3959189A Cited
US4168353A Cited
US4303757A Cited
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US4429059A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-11-10 1990-05-12 1990-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-11-10 1994-05-12 1994-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-11-10 1998-05-12 1998-11-11 $7700.00 Window Closed / Lapsed

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