US4622347A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Expandable polypropylene interpolymer particles
Assignee: Lyondell Chemical Technology LP
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Filing: 1986-04-07
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Granted: 1986-11-11
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Expires: 2006-04-07
Abstract
Abstract A process for producing a polypropylenepolystyrene interpolymer which can be impregnated with a blowing agent and can then be expanded under normal conditions for polystyrene particles to low density, fine cell structure foams. The interpolymer must be viscbroken, lubricated and stress relaxed in order to foam at 100 DEG C. to densities less than 2.0 pcf.
Inventors
- 👤 Kent D. Fudge
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 22:25
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/16; C08J9/18; C08F; C08F255/00; C08F255/02; C08J2351/00; C08J2351/06
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
183 words
A process for producing expandable polypropylene particles comprising (a) suspending in an aqueous medium, a copolymer of propylene and sufficient olefin comonomers to give said copolymer a melting peak of less than 140° C., with the aid of a suitable suspending agent system; (b) adding to said suspension vinyl aromatic monomer and a catalyst system such that the amount of monomer is 40 to 80% by weight based on copolymer plus monomer; (c) polymerizing said monomer in the interior of said copolymer to form a polypropylene-polyvinylaromatic monomer interpolymer; (d) separating said interpolymer from said suspension by acidifying, filtering, washing with water and drying in air; (e) extruding said interpolymer in admixture with a lubricant and cell control agent and a peroxide, if used, to viscbreak said interpolymer to a melt flow (condition L) of at least 10, under conditions to minimize orientation stress in the final extrudate; (f) impregnating said extrudate with a blowing agent to give expandable polypropylene-polyvinyl aromatic monomer interpolymers which can be expanded at 100° C. to fine cell structure foams of density less than 2.0 pounds per cubic foot.
Claim 2
Dependent Claim
183 words
A process for producing expandable polypropylene particles comprising (a) suspending in an aqueous medium, a copolymer of propylene and sufficient olefin comonomers to give said copolymer a melting peak of less than 140° C., with the aid of a suitable suspending agent system; (b) adding to said suspension vinyl aromatic monomer and a catalyst system such that the amount of monomer is 40 to 80% by weight based on copolymer plus monomer; (c) polymerizing said monomer in the interior of said copolymer to form a polypropylene-polyvinylaromatic monomer interpolymer; (d) separating said interpolymer from said suspension by acidifying, filtering, washing with water and drying in air; (e) extruding said interpolymer in admixture with a lubricant and cell control agent and a peroxide, if used, to viscbreak said interpolymer to a melt flow (condition L) of at least 10, under conditions to minimize orientation stress in the final extrudate; (f) impregnating said extrudate with a blowing agent to give expandable polypropylene-polyvinyl aromatic monomer interpolymers which can be expanded at 100° C. to fine cell structure foams of density less than 2.0 pounds per cubic foot.
Claim 3
Dependent Claim
12 words
The process of claim 1 wherein said olefin comonomer may be ethylene.
Claim 4
Dependent Claim
14 words
The process of claim 1 wherein said olefin comonomers may be ethylene and butene.
Claim 5
Dependent Claim
30 words
The process of claim 1 wherein said vinyl aromatic monomer is at least one monomer selected from the group consisting of styrene, alpha-methylstyrene, nuclearmethylstyrene, p-tert-butylstyrene, chlorostyrene, bromostyrene, and mixtures thereof.
Claim 6
Dependent Claim
23 words
The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as an emulsion of monomer and catalysts in water.
Claim 7
Dependent Claim
21 words
The process of claim 1 wherein said vinyl aromatic monomer and catalysts are added as a solution of catalyst in monomer.
Claim 8
Dependent Claim
20 words
The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide based on interpolymer.
Claim 9
Dependent Claim
26 words
The process of claim 1 wherein said lubricant and cell control agent is 2-4% by weight ethylene-bis-stearamide and 0.2-0.4% by weight zinc stearate based on interpolymer.
Claim 10
Dependent Claim
19 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise slow air cool of the extrudate.
Claim 11
Dependent Claim
23 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise cooling in a blob followed by grinding to small particles.
Claim 12
Dependent Claim
18 words
The process of claim 1 wherein said conditions to minimize orientation stress comprise slow cool with warm water.
Claim 13
Dependent Claim
23 words
The process of claim 1 wherein said blowing agent is selected from the group consisting of aliphatic hydrocarbons, cycloaliphatic hydrocarbons, and halogenated hydrocarbons.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1989-11-10 | 1990-05-12 | 1990-11-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1993-11-10 | 1994-05-12 | 1994-11-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1997-11-10 | 1998-05-12 | 1998-11-11 | $7700.00 | Window Closed / Lapsed |