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US4640003A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making planar geometry Schottky diode using oblique evaporation and normal incidence proton bombardment

Assignee: United States Department of the Navy
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Filing: 1985-09-30
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Granted: 1987-02-03
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Expires: 2005-09-30
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Abstract

Abstract A Schottky diode and method of making same in which a n+ doped layer, an noped layer and an undoped layer of a semi-insulating material selected from the group consisting of gallium arsenide, aluminum gallium arsenide and indium phosphide is grown consecutively on a semi-insulating substrate made of the same material. A mesa with acute angled sides is etched on the undoped layer to such a depth that the n doped layer is exposed. A Schottky and ohmic contact are then deposited on opposite sides of the mesa. The exposed n layer is then bombarded with protons at normal incidence.

Inventors

  • 👤 Nicolas A. Papanicolaou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 12:06
CPC Classifications
H; H10; H10D; H10D8/00; H10D8/01; H10D8/051; H10D64/00; H10D64/01; H10D64/011; H10D64/0116; H10D64/012; H10D64/0124; H10D64/0125; H10D8/60; H10P; H10P50/00; H10P50/60; H10P50/64; H10P50/642; H10P50/646; H10P50/648; H10D62/00; H10D62/80; H10D62/85; Y; Y10; Y10S; Y10S148/00; Y10S148/084; Y10S148/14; Y10S438/00; Y10S438/978

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 215 words
A method of fabricating a Schottky diode comprising the steps of: providing a semi-insulating substrate of material selected from the group consisting of aluminum gallium arsenide, gallium arsenide and indium phosphide; growing sequentially an n+ doped layer of the material, an n doped layer of the material, and an undoped layer of the material consecutively on the substrate; depositing a polyimide on at least one region of the undoped layer; masking at least one region on the undoped layer to produce at least one masked and one unmasked region; etching away said unmasked region to produce a mesa with acute angled sides sloping inward from the top on the undoped layer so that the sides of the mesa define two recessed areas underneath the mesa; depositing a Schottky material at an angle on the exposed n doped layer so that the recessed area on one side of the mesa is not covered with Schottky material; depositing an ohmic material at an angle on the exposed n doped layer and on the Schottky material so that the recessed area on the other side of the mesa is not covered with ohmic material; bombarding the Schottky material and ohmic material with protons at normal incidence so that the recessed areas are untouched; and annealing the ohmic contact.
Claim 2
Independent Claim 215 words
A method of fabricating a Schottky diode comprising the steps of: providing a semi-insulating substrate of material selected from the group consisting of aluminum gallium arsenide, gallium arsenide and indium phosphide; growing sequentially an n+ doped layer of the material, an n doped layer of the material, and an undoped layer of the material consecutively on the substrate; depositing a polyimide on at least one region of the undoped layer; masking at least one region on the undoped layer to produce at least one masked and one unmasked region; etching away said unmasked region to produce a mesa with acute angled sides sloping inward from the top on the undoped layer so that the sides of the mesa define two recessed areas underneath the mesa; depositing a Schottky material at an angle on the exposed n doped layer so that the recessed area on one side of the mesa is not covered with Schottky material; depositing an ohmic material at an angle on the exposed n doped layer and on the Schottky material so that the recessed area on the other side of the mesa is not covered with ohmic material; bombarding the Schottky material and ohmic material with protons at normal incidence so that the recessed areas are untouched; and annealing the ohmic contact.
Claim 3
Dependent Claim 106 words
A method as in claim 1 wherein the n + doped layer is from about 1 micrometer to about 4 micrometers preferably 2.5 micrometers thick and has a doping concentration of from about 1×10 18 cm 3 to about 1×10 19 cm -3 preferably 2×10 18 cm -3 , the n doped layer is from about 0.2 micrometers to about 0.6 micrometers preferably 0.5 micrometers thick and has a doping concentration of from about 5×10 16 cm -3 to about 3×10 17 c, -3 preferably 1×10 17 cm -3 and the undoped layer is from about 1 micrometer to 5 micrometers preferably 2.5 2.5 micrometers thick.
Claim 4
Dependent Claim 49 words
A method as in claim 1 wherein the step of masking further comprises the steps of: producing a rectangular pattern on the undoped layer by use of a positive photoresist and a mask with a rectangular pattern and a photoresist developer; etching the undoped layer to produce a mesa.
Claim 5
Dependent Claim 86 words
A method as in claim 1 wherein the step of depositing the ohmic and Schottky contacts comprises the steps of: producing a pattern on each side of the mesa for contact metallization with a positive photoresist; evaporating the Schottky material in a vacuum with the n doped layer oriented from about 55° to about 65° preferably 60° with respect to the beam; rotating the Schottky diode from about 55° to about 65° preferably 60°; evaporating the ohmic material in vacuum; and dissolving the photoresist with acetone.
Claim 6
Dependent Claim 43 words
A method as in claim 1 wherein the n doped layer is bombarded at normal incidence with protons of a dosage preferably 150 KeV, capable of penetrating the n doped layer and the n+ doped layer but not capable of penetrating the polyimide.
Claim 7
Dependent Claim 24 words
A method as in claim 1 wherein the ohmic contact is annealed at from about 390° to 450° preferably 425° C. for two minutes.
Claim 8
Independent Claim 233 words
A method of fabricating a Schottky diode comprising the steps of: growing an n + doped layer of gallium arsenide on a semi-insulating gallium arsenide substrate; growing an n doped layer of gallium arsenide on the n + doped layer; growing an undoped layer of gallium arsenide on the n doped layer; depositing a polyimide with a spinner on the undoped layer; curing the polyimide at approximately 150° C. for one half hour; aligning the substrate and n + layer, n layer, and undoped layer along the 011 orientation; providing a rectangular pattern on the undoped layer by use of a positive photoresist and a photoresist developer; etching a mesa on the undoped layer with a solution of one part sulfuric acid, one part hydrogen peroxide and two parts water to a depth so that all the undoped layer is removed exposing the n active layer; defining a pattern on each side of the mesa for contact metallization with positive photoresist; evaporating the Schottky material in vacuum on one side of the mesa with the n layer oriented approximately 60° with respect to the beam; rotating the n layer by approximately 60°; evaporating ohmic material in vacuum on the other side of the mesa; dissolving the photoresist with acetone; bombarding the n layer at normal incidence with approximately 150 KeV protons; and annealing the ohmic contact at approximately 425° for approximately two minutes.
Claim 9
Independent Claim 233 words
A method of fabricating a Schottky diode comprising the steps of: growing an n + doped layer of gallium arsenide on a semi-insulating gallium arsenide substrate; growing an n doped layer of gallium arsenide on the n + doped layer; growing an undoped layer of gallium arsenide on the n doped layer; depositing a polyimide with a spinner on the undoped layer; curing the polyimide at approximately 150° C. for one half hour; aligning the substrate and n + layer, n layer, and undoped layer along the 011 orientation; providing a rectangular pattern on the undoped layer by use of a positive photoresist and a photoresist developer; etching a mesa on the undoped layer with a solution of one part sulfuric acid, one part hydrogen peroxide and two parts water to a depth so that all the undoped layer is removed exposing the n active layer; defining a pattern on each side of the mesa for contact metallization with positive photoresist; evaporating the Schottky material in vacuum on one side of the mesa with the n layer oriented approximately 60° with respect to the beam; rotating the n layer by approximately 60°; evaporating ohmic material in vacuum on the other side of the mesa; dissolving the photoresist with acetone; bombarding the n layer at normal incidence with approximately 150 KeV protons; and annealing the ohmic contact at approximately 425° for approximately two minutes.

References Cited (Backward Citations)

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US4325747A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-02-02 1990-08-04 1991-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-02-02 1994-08-04 1995-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-02-02 1998-08-04 1999-02-03 $7700.00 Window Closed / Lapsed

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