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US4686262A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic block copolyesters, a process for the preparation thereof and their use for the production of mouldings

Assignee: Bayer AG
•
Filing: 1981-12-14
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Granted: 1987-08-11
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Expires: 2001-12-14
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Abstract

Abstract Block copolyesters based on polyalkylene terephthalates which contain polydiene blocks show an extremely low deformation even when they are processed into thin articles. They still have a crystallinity which is decreased by less than the ratio corresponding to the polydiene portion.

Inventors

  • 👤 Rudolf Binsack
  • 👤 Karl-Heinz Kohler
  • 👤 Ulrich Grigo
  • 👤 Leo Morbitzer
  • 👤 Ludwig Bottenbruch
  • 👤 Walter Heitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:50
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 202 words
Block copolyesters having a relative viscosity (measured in phenol/o-dichlorobenzene, weight ratio of 1:1, at 25° C.) of from 1.15 to 3.0, which consist of the following, the terminal groups not being considered: (A) from 1 to 60% by weight, based on the block copolyester, of long-chain units of the following formula: ##STR5## (B) from 40 to 99% by weight, based on the block copolyester, of short-chain units of the following formula: ##STR6## characterised in that D represents a divalent polydiene radical containing at least 50 mol % of 1,4-bonds, terminal-positioned bonding points and having an average molecular weight M n of from 400 to 5000 and side chains which may optionally be present must be methyl and/or vinyl groups; G represents a divalent aliphatic radical having from 1 to 12 carbon atoms, and/or a divalent cycloaliphatic radical having from 6 to 12 carbon atoms with a molecular weight of less than 300, at least 70 mol % of G representing a uniform radical; S represents a direct bond or a divalent aliphatic, cycloaliphatic and/or aromatic radical having from 1 to 14 carbon atoms and having a molecular weight of less than 300, at least 70 mol % of S being 1,4-phenylene radicals.
Claim 2
Dependent Claim 202 words
Block copolyesters having a relative viscosity (measured in phenol/o-dichlorobenzene, weight ratio of 1:1, at 25° C.) of from 1.15 to 3.0, which consist of the following, the terminal groups not being considered: (A) from 1 to 60% by weight, based on the block copolyester, of long-chain units of the following formula: ##STR5## (B) from 40 to 99% by weight, based on the block copolyester, of short-chain units of the following formula: ##STR6## characterised in that D represents a divalent polydiene radical containing at least 50 mol % of 1,4-bonds, terminal-positioned bonding points and having an average molecular weight M n of from 400 to 5000 and side chains which may optionally be present must be methyl and/or vinyl groups; G represents a divalent aliphatic radical having from 1 to 12 carbon atoms, and/or a divalent cycloaliphatic radical having from 6 to 12 carbon atoms with a molecular weight of less than 300, at least 70 mol % of G representing a uniform radical; S represents a direct bond or a divalent aliphatic, cycloaliphatic and/or aromatic radical having from 1 to 14 carbon atoms and having a molecular weight of less than 300, at least 70 mol % of S being 1,4-phenylene radicals.
Claim 3
Dependent Claim 29 words
Block copolyesters according to claim 1, characterised in that they have a relative viscosity (measured in phenol/o-dichlorobenzene, weight ratio of 1:1, at 25° C.) of from 1.3 to 2.5.
Claim 4
Dependent Claim 36 words
Block copolyesters according to claim 1 or 2, characterised in that they contain the following: (A) from 10 to 50% by weight of long-chain units, and (B) from 50 to 90% by weight of short-chain units.
Claim 5
Dependent Claim 34 words
Block copolyesters according to claim 1, characterised in that they contain the following: (A) from 16 to 45% by weight of long-chain units, and (B) from 55 to 84% by weight of short-chain units.
Claim 6
Dependent Claim 21 words
Block copolyesters according to claim 1, characterised in that D represents a radical containing at least 70 mol % of 1,4-bonds.
Claim 7
Dependent Claim 25 words
Block copolyesters according to claim 1, characterised in that D represents a radical having an average molecular weight M n of from 450 to 3000.
Claim 8
Dependent Claim 25 words
Block copolyesters according to claim 1, characterised in that D represents a radical having an average molecular weight M n of from 500 to 1200.
Claim 9
Dependent Claim 18 words
Block copolyesters according to claim 1, characterised in that G represents an ethylene radical or a 1,4-butylene radical.
Claim 10
Dependent Claim 14 words
Block copolyesters according to claim 1, characterised in that S represents a 1,4-phenylene radical.

References Cited (Backward Citations)

DE1720727A1 Cited
US3598882A Cited
DE2032818A1 Cited
US3853815A Cited
US3969306A Cited
DE2458472A1 Cited
DE2801145A1 Cited
US4207230A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-10 1991-02-09 1991-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-10 1995-02-09 1995-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-10 1999-02-09 1999-08-11 $7700.00 Window Closed / Lapsed

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