US4703067A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for preparing dry solid water absorbing polyacrylate resin
Assignee: BASF SE
•
Filing: 1987-02-19
•
Granted: 1987-10-27
•
Expires: 2007-02-19
Abstract
Abstract A process for preparing a solid, water absorbing, cross-linked polyacrylate resin including combining potassium acrylate and a polyvinyl monomer, such as N,N-methylene bisacrylamide, with water in an amount of 55 to 80 combined weight percent of potassium acrylate and polyvinyl monomer based on the total weight of potassium acrylate, polyvinyl monomer and water to form a monomer mixture, and adding a polymerization initiator to the monomer mixture to initiate polymerization of the monomer mixture. The monomer mixture then is polymerized without external heating by utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form the cross-linked polyacrylate resin having a water content sufficiently low (i.e. 15% or less) to be powdered, such as by pulverization, without an intermediate drying step.
Inventors
- 👤 Muneharu Mikita
- 👤 Shozo Tanioku
- 👤 Takayasu Touda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 01:58
CPC Classifications
C; C08; C08F; C08F220/00; C08F220/02; C08F220/04; C08F220/06
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
162 words
A process for preparing a solid, water absorbing, cross-linked resin comprising: combining a monomer mixture of (A) potassium acrylate; and (B) a water miscible or water soluble polyvinyl monomer, with water in an amount of 55 to 80 combined weight percent of (A) plus (B) based on the total weight of (A) plus (B) plus water to form a monomer mixture wherein the monomers of the monomer mixture consist essentially of (A) and (B); adding a polymerization initiator to said monomer mixture capable of initiating, and in an amount sufficient to initiate polymerization of said monomer mixture; depositing said monomer mixture including said initiator onto a support surface in sheet form for polymerization and cross-linking; and polymerizing said monomer mixture while utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form said cross-linked polyacrylate resin having a water content sufficiently low to be powdered without an intermediate drying step.
Claim 2
Dependent Claim
162 words
A process for preparing a solid, water absorbing, cross-linked resin comprising: combining a monomer mixture of (A) potassium acrylate; and (B) a water miscible or water soluble polyvinyl monomer, with water in an amount of 55 to 80 combined weight percent of (A) plus (B) based on the total weight of (A) plus (B) plus water to form a monomer mixture wherein the monomers of the monomer mixture consist essentially of (A) and (B); adding a polymerization initiator to said monomer mixture capable of initiating, and in an amount sufficient to initiate polymerization of said monomer mixture; depositing said monomer mixture including said initiator onto a support surface in sheet form for polymerization and cross-linking; and polymerizing said monomer mixture while utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form said cross-linked polyacrylate resin having a water content sufficiently low to be powdered without an intermediate drying step.
Claim 3
Dependent Claim
17 words
The process of claim 1 wherein said sheet is deposited in a thickness of about 10 mm.
Claim 4
Dependent Claim
162 words
A process for preparing a solid, water absorbing, cross-linked resin comprising: combining a monomer mixture of (A) potassium acrylate; and (B) a water miscible or water soluble polyvinyl monomer, with water in an amount of 55 to 80 combined weight percent of (A) plus (B) based on the total weight of (A) plus (B) plus water to form a monomer mixture wherein the monomers of the monomer mixture consist essentially of (A) and (B); adding a polymerization initiator to said monomer mixture capable of initiating, and in an amount sufficient to initiate polymerization of said monomer mixture; adding a non-aqueous solvent having a boiling point of 40°-150° C. with said monomers (A) and (B); and polymerizing said monomer mixture while utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form said cross-linked, porous polyacrylate resin having a water content sufficiently low to be powdered without an intermediate drying step.
Claim 5
Dependent Claim
162 words
A process for preparing a solid, water absorbing, cross-linked resin comprising: combining a monomer mixture of (A) potassium acrylate; and (B) a water miscible or water soluble polyvinyl monomer, with water in an amount of 55 to 80 combined weight percent of (A) plus (B) based on the total weight of (A) plus (B) plus water to form a monomer mixture wherein the monomers of the monomer mixture consist essentially of (A) and (B); adding a polymerization initiator to said monomer mixture capable of initiating, and in an amount sufficient to initiate polymerization of said monomer mixture; adding a non-aqueous solvent having a boiling point of 40°-150° C. with said monomers (A) and (B); and polymerizing said monomer mixture while utilizing the exothermic heat of reaction as substantially the only non-ambient energy source to drive water away from said polyacrylate resin to form said cross-linked, porous polyacrylate resin having a water content sufficiently low to be powdered without an intermediate drying step.
Claim 6
Dependent Claim
12 words
The process of claim 3 wherein said solvent is a blowing agent.
Claim 7
Dependent Claim
12 words
The process of claim 3 wherein said solvent is an organic solvent.
Claim 8
Dependent Claim
18 words
The process of claim 3 wherein said non-aqueous solvent has a boiling point of 55° to 120° C.
References Cited (Backward Citations)
US2956046A
Cited
US4071650A
Cited
US4154910A
Cited
US4093776A
Cited
US4167464A
Cited
US4486489A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-10-26 | 1991-04-27 | 1991-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-10-26 | 1995-04-27 | 1995-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-10-26 | 1999-04-27 | 1999-10-27 | $7700.00 | Window Closed / Lapsed |