US4713270A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Heatset high barrier container
Assignee: Graham Packaging Plastic Products Inc
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Filing: 1986-03-20
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Granted: 1987-12-15
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Expires: 2006-03-20
Abstract
Abstract A high barrier heatset intimate fusion blend article is disclosed where the article includes a blend of a high barrier copolyester, formed from terephthalic acid, ethylene glycol and 1,3 bis(2-hydroxyethoxy) benzene, and poly(ethylene terephthalate) (PET). The PET/copolyester blend articles are formed using a blowmolding and heatsetting process to rapidly achieve a high percentage of crystallinity of the PET in the article. The articles have excellent gas barrier and mechanical strength properties, high thermal stability and remain optically clear after heatsetting.
Inventors
- 👤 Saleh A. Jabarin
- 👤 Prakash R. Ajmera
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:04
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; Y; Y10; Y10S; Y10S428/00; Y10S428/911; Y10S525/00; Y10S525/933; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1379
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
202 words
A transparent hollow high barrier, thermally stable article obtained by blow molding and heatsetting an intimate fusion blend of a poly(ethylene terephthalate), and a high barrier copolyester formed of the polymeric reaction product of (A) reactant(s) selected from the group consisting of isophthalic acid, terephalic acid, and their C 1 to C 4 alkyl esters, and any mixture thereof in any proportion, (B) reactants, 1,3(2-hydroxyethoxy)benzene plus ethylene glycol, and optionally one or more other ester forming dihydroxy organic hydrocarbon reactant(s), and optionally, (C) reactant, bis(4-betahydroxyethoxyphenyl)sulfone, wherein: (1) the amount of said 1,3 bis(2-hydroxyethoxy)benzene is 5-90 mole percent of the amount of A reactants, (2) the combined amount of B and C reactant is about 110 to 300 mole percent of the amount of A reactants, (3) the amount of said other ester forming dihydroxy organic hydrocarbon reactant(s) is zero to 20 mole percent of the amount of said A reactants, and (4) the combined amount of said (C) reactant plus said 1,3 bis(2-hydroxyethoxy)benzene and said other ester forming dihydroxy organic hydrocarbon reactant(s) is not over 90 mole percent of said A reactants, said copolyester being present in an amount from about 20 percent to about 30 percent, by weight, of said article.
Claim 2
Dependent Claim
202 words
A transparent hollow high barrier, thermally stable article obtained by blow molding and heatsetting an intimate fusion blend of a poly(ethylene terephthalate), and a high barrier copolyester formed of the polymeric reaction product of (A) reactant(s) selected from the group consisting of isophthalic acid, terephalic acid, and their C 1 to C 4 alkyl esters, and any mixture thereof in any proportion, (B) reactants, 1,3(2-hydroxyethoxy)benzene plus ethylene glycol, and optionally one or more other ester forming dihydroxy organic hydrocarbon reactant(s), and optionally, (C) reactant, bis(4-betahydroxyethoxyphenyl)sulfone, wherein: (1) the amount of said 1,3 bis(2-hydroxyethoxy)benzene is 5-90 mole percent of the amount of A reactants, (2) the combined amount of B and C reactant is about 110 to 300 mole percent of the amount of A reactants, (3) the amount of said other ester forming dihydroxy organic hydrocarbon reactant(s) is zero to 20 mole percent of the amount of said A reactants, and (4) the combined amount of said (C) reactant plus said 1,3 bis(2-hydroxyethoxy)benzene and said other ester forming dihydroxy organic hydrocarbon reactant(s) is not over 90 mole percent of said A reactants, said copolyester being present in an amount from about 20 percent to about 30 percent, by weight, of said article.
Claim 3
Dependent Claim
27 words
The transparent hollow high barrier, thermally stable article of claim 1 wherein said copolyester is in an amount of about 30 percent, by weight, of said article.
Claim 4
Dependent Claim
29 words
The transparent hollow high barrier, thermally stable article of claim 1 wherein said high barrier copolyester is in an amount of about 20 percent, by weight, of said article.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-12-14 | 1991-06-15 | 1991-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-12-14 | 1995-06-15 | 1995-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-12-14 | 1999-06-15 | 1999-12-15 | $7700.00 | Window Closed / Lapsed |