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US4716337A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorescent lamp

Assignee: US Philips Corp
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Filing: 1987-01-06
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Granted: 1987-12-29
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Expires: 2007-01-06
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Abstract

Abstract Low-pressure mercury vapor discharge lamp having a very satisfactory color rendition and a color temperature from 2300 to 3300 K. The lamp is provided with a luminescent layer comprising: (a) a luminescent alkaline earth metal halophosphate activated by Sb3+ and Mn2+ and having a color temperature of 2900-5000 K.; (b) a luminescent material activated by Eu2+ and having an emission maximum of 470-500 nm; (c) a luminescent rate earth metal metaborate activated by Ce3+ and Mn2+ and having a red Mn2+ emission, and (d) a luminescent aluminate activated by Ce3+ and having a garnet crystal structure absorbing blue radiation below 480 nm; (e) a green luminescing Mn2+ activated material having an emission maximum in the range from 510 to 535 nm. As a result of the addition of the material e the quantity of the material d can be limited so that color point differences among the lamps are avoided.

Inventors

  • 👤 Cornelis Huiskes
  • 👤 Evert D. Schutten

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 19:22
CPC Classifications
H; H01; H01J; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/44; C; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7766; C09K11/7774; C09K11/778

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 251 words
A low-pressure mercury vapour discharge lamp having a very satisfactory colour rendition, a colour temperature of emitted white light in the range from 2300 to 3300 K. and a colour point on or near the Planckian locus, said lamp having a gas-tight radiation emitting envelope containing mercury and a rare gas, and a luminescent layer comprising: a. at least one luminescent alkaline earth metal halophosphate activated by trivalent antimony and by bivalent manganese with a colour temperature of the emitted radiation from 2900 to 5000 K.; b. at least one luminescent material activated by bivalent europium having an emission maximum in the range from 470 to 500 nm and a half-value width of the emission band of not more than 90 nm; c. a luminescent rare earth metal metaborate activated by trivalent cerium and by bivalent manganese and having a monoclinic crystal structure whose fundamental lattice is defined by the formula Ln(Mg,Zn,Cd)B 5 O 10 , in which Ln represents at least one of the elements ytrrium, lanthanum and gadolinium, and in which up to 20 mol. % of the B may be replaced by Al and/or Ga, which metaborate has a red Mn 2+ emission; and d. a luminescent aluminate activated by trivalent cerium and having a garnet crystal structure at least partly absorbing blue radiation at wavelengths below 480 nm, characterized in that the luminescent layer also comprises: e. a green luminescing material activated by bivalent manganese having an emission maximum in the range from 510 to 535 nm.
Claim 2
Dependent Claim 251 words
A low-pressure mercury vapour discharge lamp having a very satisfactory colour rendition, a colour temperature of emitted white light in the range from 2300 to 3300 K. and a colour point on or near the Planckian locus, said lamp having a gas-tight radiation emitting envelope containing mercury and a rare gas, and a luminescent layer comprising: a. at least one luminescent alkaline earth metal halophosphate activated by trivalent antimony and by bivalent manganese with a colour temperature of the emitted radiation from 2900 to 5000 K.; b. at least one luminescent material activated by bivalent europium having an emission maximum in the range from 470 to 500 nm and a half-value width of the emission band of not more than 90 nm; c. a luminescent rare earth metal metaborate activated by trivalent cerium and by bivalent manganese and having a monoclinic crystal structure whose fundamental lattice is defined by the formula Ln(Mg,Zn,Cd)B 5 O 10 , in which Ln represents at least one of the elements ytrrium, lanthanum and gadolinium, and in which up to 20 mol. % of the B may be replaced by Al and/or Ga, which metaborate has a red Mn 2+ emission; and d. a luminescent aluminate activated by trivalent cerium and having a garnet crystal structure at least partly absorbing blue radiation at wavelengths below 480 nm, characterized in that the luminescent layer also comprises: e. a green luminescing material activated by bivalent manganese having an emission maximum in the range from 510 to 535 nm.
Claim 3
Dependent Claim 29 words
A lamp as claimed in claim 1, in which the luminescent layer also comprises a luminescent material (f) activated by trivalent terbium and having a green Tb 3+ emission.
Claim 4
Dependent Claim 73 words
A lamp as claimed in claim 2, in which the luminescent metaborate c is also activated by trivalent terbium and the metaborate c is also the material f and is defined by the formula (Y,La,GD) 1-x-y Ce x Tb y (Mg,Zn,Cd) 1-p Mn p B 5 O 10 , in which 0.0123 x≦1-y 0.01≦y≦0.75 0.01≦p≦0.30, and in which up to 20 mol. % of the B may be replaced by Al and/or Ga.
Claim 5
Dependent Claim 50 words
A lamp as claimed in claim 1 in which the material d is defined by the formula Ln 3-x Ce x Al 5-p-q Ga p Sc q O 12 in which Ln represents at least one of the elements yttrium, gadolinium, lanthanum and lutetium and in which 0.01≦x≦0.15 0≦p≦3 0≦q≦1.
Claim 6
Dependent Claim 65 words
A lamp as claimed in claim 1, characterized in that the material e is at least a material from the group of the zinc orthosilicates activated by bivalent manganese, the barium aluminates activated by bivalent europium and by bivalent manganese and having a hexagonal crystal structure, and the barium magnesium aluminates activated by bivalent europium and by bivalent manganese and having a hexagonal crystal structure.
Claim 7
Dependent Claim 26 words
A lamp as claimed in claim 5, characterized in that the luminescent layer comprises the material e in a quantity of 1 to 20% by weight.
Claim 8
Dependent Claim 22 words
A lamp as claimed in claim 1, characterized in that the luminescent layer consists of a homogeneous mixture of the luminescent materials.
Claim 9
Dependent Claim 87 words
A lamp as claimed in claim 7, in which the luminescent layer is located on the inner wall of the envelope, characterized in that a second luminescent layer is located between the luminescent layer and the envelope, which second luminescent layer comprises a mixture of a luminescent alkaline earth metal halophosphate activated by trivalent antimony and by bivalent manganese and having a colour temperature of the emitted radiation from 2900 to 5000 K. and a luminescent aluminate activated by trivalent cerium and having a garnet crystal structure.

References Cited (Backward Citations)

US4602188A Cited
US4644223A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-28 1991-06-29 1991-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-28 1995-06-29 1995-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-28 1999-06-29 1999-12-29 $7700.00 Window Closed / Lapsed

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