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US4723908A
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US
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Dielectric probe; method and apparatus including its use
Assignee: Sunoco Inc R&M
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Filing: 1985-05-01
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Granted: 1988-02-09
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Expires: 2005-05-01
Abstract
Abstract A dielectric probe for use with conventional frequency and time domain impedance analyzers comprises two chemically resistant electrodes deposited in an interdigitated pectinate configuration on particular non-conductive substrates, the spaces between the digits thereof being no greater than about 0.01 inch; methods and apparatus for monitoring and/or controlling chemical reactions, particularly polymerization reactions, in contact therewith, wherein the complex permittivity may be calculated over a wide range of frequencies and temperatures.
Inventors
- 👤 David E. Kranbuehl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 23:44
CPC Classifications
B; B01; B01J; B01J19/00; B01J19/0006; B29; B29C; B29C35/00; B29C35/02; B29C35/0288; G; G01; G01N; G01N27/00; G01N27/02; G01N27/22; G01N27/221; G01R; G01R1/00; G01R1/02; G01R1/06; G01R1/067; G01R1/07; G01R27/00; G01R27/02; G01R27/26; G01R27/2617; G01R27/2635; G01R27/2676
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
107 words
A dielectric probe useful for sensing electrical characteristics of materials in contact with it comprising (a) a substrate having an electrical conductivity no greater than 10 -7 mho/cm -1 over a frequency range of use, a loss tangent at one megahertz of less than 0.001, a stable capacitance curve exhibiting little or no hysteresis through the range of 1 herz to 10 megahertz at the temperatures of use, and a known dielectric permittivity of less than 13, and (b) at least two chemically resistant, electrically conductive parallel interdigitated electrodes affixed thereto, the spaces between the digits of the interdigitated electrodes being no greater than about 0.01 inch.
Claim 2
Dependent Claim
107 words
A dielectric probe useful for sensing electrical characteristics of materials in contact with it comprising (a) a substrate having an electrical conductivity no greater than 10 -7 mho/cm -1 over a frequency range of use, a loss tangent at one megahertz of less than 0.001, a stable capacitance curve exhibiting little or no hysteresis through the range of 1 herz to 10 megahertz at the temperatures of use, and a known dielectric permittivity of less than 13, and (b) at least two chemically resistant, electrically conductive parallel interdigitated electrodes affixed thereto, the spaces between the digits of the interdigitated electrodes being no greater than about 0.01 inch.
Claim 3
Dependent Claim
15 words
A probe of claim 1 wherein the electrodes are affixed in a pectinate interdigitated configuration.
Claim 4
Dependent Claim
20 words
A probe of claim 1 wherein the electrodes are made of gold, platinum, titanium, tungsten, palladium, chromium or combinations thereof.
Claim 5
Dependent Claim
19 words
A probe of claim 1 wherein the substrate has reproducible capacitance, conductivity, and frequency-responsive characteristics through a temperature range.
Claim 6
Dependent Claim
11 words
Probe of claim 1 including two terminal means for each electrode.
Claim 7
Dependent Claim
17 words
The probe of claim 1 wherein the substrate is selected from a polyimide, glass, or aluminum oxide.
Claim 8
Dependent Claim
166 words
Apparatus for controlling process variables of a medium undergoing chemical or physical change comprising (i) a dielectric probe useful for sensing electrical characteristics of materials in contact with it comprising (a) a substrate having an electrical conductivity no greater than 10 -7 mho/cm -1 over a frequency range of use, a loss tangent at one megahertz of less than 0.001, a stable capacitance curve exhibiting little or no hysteresis through the range of 1 herz to 10 megahertz at the temperatures of use, and a known dielectric permittivity of less than 13, and (b) at least two chemically resistant, electrically conductive parallel interdigitated electrodes affixed thereto, the spaces between the digits of the interdigitated electrodes being no greater than about 0.01 inch, (ii) means for generating a control signal as a predetermined function of an electrical characteristic of a medium in contact with said probe, and (iii) means responsive to said control signal for changing at least one process variable affecting said chemical or physical change.
Claim 9
Dependent Claim
166 words
Apparatus for controlling process variables of a medium undergoing chemical or physical change comprising (i) a dielectric probe useful for sensing electrical characteristics of materials in contact with it comprising (a) a substrate having an electrical conductivity no greater than 10 -7 mho/cm -1 over a frequency range of use, a loss tangent at one megahertz of less than 0.001, a stable capacitance curve exhibiting little or no hysteresis through the range of 1 herz to 10 megahertz at the temperatures of use, and a known dielectric permittivity of less than 13, and (b) at least two chemically resistant, electrically conductive parallel interdigitated electrodes affixed thereto, the spaces between the digits of the interdigitated electrodes being no greater than about 0.01 inch, (ii) means for generating a control signal as a predetermined function of an electrical characteristic of a medium in contact with said probe, and (iii) means responsive to said control signal for changing at least one process variable affecting said chemical or physical change.
Claim 10
Dependent Claim
14 words
Apparatus of claim 7 wherein said control signal generating means is a temperature controller.
Claim 11
Dependent Claim
14 words
Apparatus of claim 7 wherein the control signal responsive means is a heating element.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-02-08 | 1991-08-10 | 1992-02-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-02-08 | 1995-08-10 | 1996-02-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-02-08 | 1999-08-10 | 2000-02-09 | $7700.00 | Window Closed / Lapsed |