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US4767550A Expired / Lapsed US ⏱️ 0.0 years remaining

Vicinal diol containing monomers and polymers and methods of treating a subterranean formation

Assignee: Halliburton Co
•
Filing: 1987-03-31
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Granted: 1988-08-30
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Expires: 2007-03-31
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Abstract

Abstract The present invention provides vicinal diol containing monomers and polymers and methods of preparing and using such monomers and polymers. When crosslinked in aqueous fluids, the polymers form high viscosity gels which are stable at high temperatures.

Inventors

  • 👤 David Hanlon
  • 👤 Marlin Holtmyer
  • 👤 Mike Conway
  • 👤 Charles Hunt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:53
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/84; C09K8/86; C09K8/88; C09K8/887; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36; C08F20/52; C08F20/54; C08F20/60; C09K8/02; C09K8/04; C09K8/06; C09K8/12; C09K8/56; C09K8/57; C09K8/575; C09K8/5751; C09K8/5756; C09K8/62; C09K8/66; C09K8/68; C09K8/685; C09K8/72; C09K8/74; Y; Y10; Y10S; Y10S507/00; Y10S507/925; Y10S507/935

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 109 words
A method of treating a high temperature subterranean formation comprising contacting said formation with a highly viscous gel formed of an aqueous fluid, a water soluble polymer containing crosslinkable vicinal diol groups and a crosslinking agent selected from the group consisting of water soluble salts and complexes of multivalent cations, said water soluble polymer comprising a copolymer containing a monomer having the structural formula: ##STR12## wherein R 1 is hydrogen or methyl; Y is oxygen of NH; R 3 and R 4 are independently methyl or ethyl; n is 2 or 3; and X - is a halogen, sulfate, CH 3 SO 4 or CH 3 COO - .
Claim 2
Independent Claim 109 words
A method of treating a high temperature subterranean formation comprising contacting said formation with a highly viscous gel formed of an aqueous fluid, a water soluble polymer containing crosslinkable vicinal diol groups and a crosslinking agent selected from the group consisting of water soluble salts and complexes of multivalent cations, said water soluble polymer comprising a copolymer containing a monomer having the structural formula: ##STR12## wherein R 1 is hydrogen or methyl; Y is oxygen of NH; R 3 and R 4 are independently methyl or ethyl; n is 2 or 3; and X - is a halogen, sulfate, CH 3 SO 4 or CH 3 COO - .
Claim 3
Dependent Claim 31 words
The method of claim 1 wherein said one or more other polymers are selected from the group consisting of N,N-dimethylacrylamide, acrylamide, methacrylamide, 2-acrylamido-2-methylpropanesulfonic acid, sodium styrene sulfonate, N-vinyl-2-pyrrolidone and acrylic acid.
Claim 4
Dependent Claim 22 words
The method of claim 1 wherein said water soluble polymer containing crosslinkable vicinal diol groups is a copolymer of MAPDMDHPAS and NNDMA.
Claim 5
Dependent Claim 22 words
The method of claim 1 wherein said water soluble polymer containing crosslinkable vicinal diol groups is a copolymer of MAPDMDHPAC and NNDMA.
Claim 6
Dependent Claim 29 words
The method of claim 1 wherein Y is NH, n is 3, R 1 is methyl, R 3 and R 4 are each methyl and X - is sulfate.
Claim 7
Dependent Claim 31 words
The method of claim 1 wherein Y is NH, n is 3, R 1 is methyl, R 3 and R 4 are each methyl and X - is Cl - .

References Cited (Backward Citations)

US4056496A Cited
US4147681A Cited
US4319013A Cited
US4319013B1 Cited
US4224150A Cited
US4610305A Cited
US4605718A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-08-30 1992-02-29 1992-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-08-30 1996-02-29 1996-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-08-30 2000-02-29 2000-08-30 $7700.00 Window Closed / Lapsed

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