US4782175A
Expired / Lapsed
US
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Urethanes composed of aliphatic fluoroalcohols, isocyanates and aromatic compounds, a process for their preparation and their use
Assignee: Hoechst AG
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Filing: 1987-07-01
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Granted: 1988-11-01
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Expires: 2007-07-01
Abstract
Abstract The molecule of the new urethanes contains an aliphatic fluoroalcohol, an isocyanate and an aromatic dihydroxy, diamino, aminohydroxy, aminocarboxy or hydroxycarboxy compound. They are prepared by reacting an aliphatic fluoroalcohol with a diisocyanate or triisocyanate to give the fluoroalcohol/isocyanate adduct and by reacting this adduct with said aromatic compound to give the desired urethanes composed of an aliphatic fluoroalcohol, an isocyanate and the bifunctional aromatic compound mentioned, and also be reacting a urethane of this type which also carries an active hydrogen atom on the bifunctional aromatic compound, with an isocyanate compound containing one or more isocyanate groups. The new urethanes are preferably used for imparting an oleophobic and hydrophobic finish to textiles and leather.
Inventors
- 👤 Frank Wehowsky
- 👤 Rolf Kleber
- 👤 Lothar Jaeckel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 09:05
CPC Classifications
C; C07; C07C; C07C271/00; C07C271/06; C07C271/40; C07C271/58; C07C275/00; C07C275/46; C07C275/58; C07C275/62; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/2805; C08G18/288; C08G18/2885; C08G18/30; C08G18/32; C08G18/3203; C08G18/3215; D; D06; D06M; D06M15/00; D06M15/19; D06M15/37; D06M15/564; D06M15/576
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
269 words
A urethane formed from aliphatic fluoroalcohols, isocyanates and aromatic compounds and having the formula 1 below ##STR24## in which R f denotes a perfluoroalkyl group having 4 to 20 carbon atoms, or an R' f SO 2 NR 1 group in which R' f is a perfluoroalkyl group having 4 to 20 carbon atoms, and R 1 is H or an alkyl group having 1 to 4 carbon atoms, x denotes an integer from 1 to 4, y denotes a number from 0 to 10, m denotes a number from 1 to 2 and n denotes a number from 1 to 2, the sum of m+n being not more than 3, A denotes one of the groups corresponding to the formulae 2 to 10 below ##STR25## X denotes one of the groups corresponding to the formulae 11 to 19 below, which can be monosubstituted or polysubstituted by an alkyl group having 1 to 4 carbon atoms ##STR26## in which Z 1 and Z 2 represent O, NH or COO in which the two substituents are not identical; in the case where Z 1 and Z 2 are COO, the carbonyl of the COO group is attached to the aromatic ring; or Z 1 and Z 2 represent 0 or NH in which the two substituents are identical, and B denotes a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a group corresponding to the formula 20 below ##STR27## in which R" f , x', y', m', n' and A', have one of the meanings of R f , x, y, m, n and A, respectively.
Claim 2
Dependent Claim
269 words
A urethane formed from aliphatic fluoroalcohols, isocyanates and aromatic compounds and having the formula 1 below ##STR24## in which R f denotes a perfluoroalkyl group having 4 to 20 carbon atoms, or an R' f SO 2 NR 1 group in which R' f is a perfluoroalkyl group having 4 to 20 carbon atoms, and R 1 is H or an alkyl group having 1 to 4 carbon atoms, x denotes an integer from 1 to 4, y denotes a number from 0 to 10, m denotes a number from 1 to 2 and n denotes a number from 1 to 2, the sum of m+n being not more than 3, A denotes one of the groups corresponding to the formulae 2 to 10 below ##STR25## X denotes one of the groups corresponding to the formulae 11 to 19 below, which can be monosubstituted or polysubstituted by an alkyl group having 1 to 4 carbon atoms ##STR26## in which Z 1 and Z 2 represent O, NH or COO in which the two substituents are not identical; in the case where Z 1 and Z 2 are COO, the carbonyl of the COO group is attached to the aromatic ring; or Z 1 and Z 2 represent 0 or NH in which the two substituents are identical, and B denotes a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a group corresponding to the formula 20 below ##STR27## in which R" f , x', y', m', n' and A', have one of the meanings of R f , x, y, m, n and A, respectively.
Claim 3
Dependent Claim
108 words
A urethane as claimed in claim 1, in which: R f denotes a perfluoroalkyl group having 6 to 16 carbon atoms, x denotes 2, y denotes 1 to 5, m denotes 1 to 2, n denotes 1 to 2, the sum of m+n being not more than 3, A denotes a toluylene group or one of the three groups corresponding to the formulae 8 to 10, X denotes a group corresponding to the formulae 11, 15, 16, 17 or 18 and B denotes H or a group corresponding to the formula 20 in which A' is one of the three groups corresponding to the formulae 8 to 10.
Claim 4
Dependent Claim
148 words
A urethane as claimed in claim 1, in which: R f denotes a perfluoroalkyl group having 6 to 16 carbon atoms, x denotes 2, y denotes 1 to 5, m denotes 1 to 2, n denotes 1 to 2, the sum of m+n being not more than 3, A denotes a toluylene group or one of the three groups corresponding to the formulae 8 to 10, X denotes a group corresponding to the formulae 11, 15, 16, 17 or 18 and B denotes H or a group corresponding to the formula 20 in which A' is one of the three groups corresponding to the formulae 8 to 10, R" f is a perfluoroalkyl group having 6 to 16 carbon atoms, x' is 2, y' is 1 to 5, m' is 1 to 2 and n' is 1 to 2, the sum of m'+n' being not more than 3.
References Cited (Backward Citations)
US3681426A
Cited
US3657320A
Cited
US3721700A
Cited
US3746742A
Cited
US4289892A
Cited
US4065630A
Cited
US4321404A
Cited
US4525305A
Cited
EP0172717A2
Cited
DE3530967A1
Cited
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