US4808637A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Superabsorbent composition and process
Assignee: Ethicon Inc
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Filing: 1987-05-14
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Granted: 1989-02-28
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Expires: 2007-05-14
Abstract
Abstract The present invention provides an acrylate superabsorbent composition having an improved rate of absorbency, low residual acid content, and a low acrylate monomer content. Acrylic acid, an alkali metal salt of carbonic acid, aluminum acetate, sodium sulfate and water are uniformly reacted preferably using microwave radiation as the heat source.
Inventors
- 👤 Franklin Boardman
- 👤 John M. Lesniak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:10
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/04; C08F20/06; A; A61; A61L; A61L15/00; A61L15/16; A61L15/42; A61L15/60; Y; Y10; Y10S; Y10S525/00; Y10S525/917; Y10S525/918
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
29 words
An ionically cross-linked poly (potassium) acrylate superabsorbent composition, which is substantially fully neutralized and water insoluble and which has a low residual monomer content of less than 200 ppm.
Claim 2
Dependent Claim
29 words
An ionically cross-linked poly (potassium) acrylate superabsorbent composition, which is substantially fully neutralized and water insoluble and which has a low residual monomer content of less than 200 ppm.
Claim 3
Dependent Claim
33 words
The superabsorbent of claim 1 which is neutralized to the degree it requires less than 3.0 milliequivalents of 0.1N potassium hydroxide when 3.3 grams of alkali metal polyacrylate are titrated to pH 8.6.
Claim 4
Dependent Claim
78 words
An ionically cross-linked poly (alkali metal acrylate) superabsorbent composition comprising a foam product resulting from the process of uniformly reacting acrylic acid, an alkali metal salt of carbonic acid, aluminum acetate, sodium persulfate and water at a temperature of at least 70° C. said composition being substantially neutral and water insoluble and is an alkali metal polyacrylate having a total residual monomer content of both acrylic acid and alkali metal acrylate monomers of less than about 800 ppm.
Claim 5
Dependent Claim
78 words
An ionically cross-linked poly (alkali metal acrylate) superabsorbent composition comprising a foam product resulting from the process of uniformly reacting acrylic acid, an alkali metal salt of carbonic acid, aluminum acetate, sodium persulfate and water at a temperature of at least 70° C. said composition being substantially neutral and water insoluble and is an alkali metal polyacrylate having a total residual monomer content of both acrylic acid and alkali metal acrylate monomers of less than about 800 ppm.
Claim 6
Dependent Claim
22 words
The reaction product of claim 3 wherein said alkali metal salt is comprised of a sodium or potassium salt of carbonic acid.
Claim 7
Dependent Claim
16 words
The reaction product of claim 4 wherein said carbonic acid salt is a sodium carbonate salt.
Claim 8
Dependent Claim
12 words
The reaction product of claim 5 wherein said salt is potassium carbonate.
Claim 9
Dependent Claim
18 words
The superabsorbent composition of claim 3 wherein said total residual monomer content is less than about 200 ppm.
Claim 10
Dependent Claim
107 words
An ionically cross-linked poly (alkali metal acrylate) superabsorbent composition comprising the reaction product of about 100 parts of acrylic acid by weight, sufficient parts of an alkali metal salt of carbonic acid to substantially neutralize said acrylic acid, from about 1 to about 7 parts of aluminum acetate, from about 0.2 to about 2 parts of sodium persulfate, and from about 75 to about 175 parts of water reacted in a microwave oven at a temperature of at least 70° C., said reaction product being an alkali metal polyacrylate in the form of a foam having a residual total monomer content of less than about 800 ppm.
Claim 11
Dependent Claim
107 words
An ionically cross-linked poly (alkali metal acrylate) superabsorbent composition comprising the reaction product of about 100 parts of acrylic acid by weight, sufficient parts of an alkali metal salt of carbonic acid to substantially neutralize said acrylic acid, from about 1 to about 7 parts of aluminum acetate, from about 0.2 to about 2 parts of sodium persulfate, and from about 75 to about 175 parts of water reacted in a microwave oven at a temperature of at least 70° C., said reaction product being an alkali metal polyacrylate in the form of a foam having a residual total monomer content of less than about 800 ppm.
Claim 12
Dependent Claim
22 words
The reaction product of claim 8 wherein said alkali metal said is comprised of a sodium or potassium salt of carbonic acid.
Claim 13
Dependent Claim
16 words
The reaction product of claim 9 wherein said carbonic acid salt is a sodium carbonate salt.
Claim 14
Dependent Claim
12 words
The reaction product of claim 9 wherein said salt is potassium carbonate.
Claim 15
Dependent Claim
28 words
The superabsorbent composition of claim 8 wherein the alkali metal salt is potassium and said total residual acrylic acid acrylate monomer content is less than about 200 ppm.
Claim 16
Dependent Claim
90 words
A free radical polymerization process for preparing a poly (alkali metal acrylate) using a chemical free-radical initiator, an ionic crosslinking agent, acrylic acid, an alkali metal salt of carbonic acid, and water comprising the steps of: conducting the polymerization reaction by treatment with ultra high frequency waves to obtain a temperature of at least 70° C. for a time sufficient to obtain polymerization whereby the polymerization reaction occurs virtually simultaneously throughout the reaction mixture, thereby obtaining a poly (alkali metal acrylate) having a total residual monomer content below 800 ppm.
Claim 17
Dependent Claim
90 words
A free radical polymerization process for preparing a poly (alkali metal acrylate) using a chemical free-radical initiator, an ionic crosslinking agent, acrylic acid, an alkali metal salt of carbonic acid, and water comprising the steps of: conducting the polymerization reaction by treatment with ultra high frequency waves to obtain a temperature of at least 70° C. for a time sufficient to obtain polymerization whereby the polymerization reaction occurs virtually simultaneously throughout the reaction mixture, thereby obtaining a poly (alkali metal acrylate) having a total residual monomer content below 800 ppm.
Claim 18
Dependent Claim
25 words
The process of claim 13 wherein the reaction mixture is acrylic acid, an alkali metal salt of carbonic acid, aluminum acetate, sodium persulfate and water.
Claim 19
Dependent Claim
28 words
The process of claim 4 wherein the alkali metal salt of carbonic acid is potassium carbonate and said total residual monomer content is less than about 200 ppm.
Claim 20
Dependent Claim
19 words
The process of claim 13 wherein the treatment with ultra high frequency waves is conducted in a microwave oven.
Claim 21
Dependent Claim
20 words
The process of claim 13 wherein the treatment with ultra high frequency waves is conducted for at least 1 minute.
Claim 22
Dependent Claim
9 words
A product produced by the process of claim 13.
Claim 23
Dependent Claim
9 words
A product produced by the process of claim 14.
Claim 24
Dependent Claim
9 words
A product produced by the process of claim 15.
References Cited (Backward Citations)
US4090013A
Cited
US4524186A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-02-28 | 1992-08-29 | 1993-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-02-28 | 1996-08-29 | 1997-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-02-28 | 2000-08-29 | 2001-02-28 | $7700.00 | Window Closed / Lapsed |