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US4818658A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoactive esterification product of a diazooxide compound and a curcumin dye and photoresist materials with product

Assignee: Shipley Co Inc
•
Filing: 1987-04-17
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Granted: 1989-04-04
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Expires: 2007-04-17
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Abstract

Abstract The subject invention involves reduction of light reflection into a photoresist coating over a reflective substrate by the use of a photoactive compound in a photoresist formulation that is the reaction product of a diazooxide and curcumin.

Inventors

  • 👤 Robert L. Martin
  • 👤 M. Martha Rajaratnam
  • 👤 Pamela Turci

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:05
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/022; G03F7/09; G03F7/091

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 73 words
A photoresist composition responsive to activating radiation at a wavelength within the range of from 200 to 460 nm comprising an admixture of a polymer binder and a photoactive compound, said photoactive compound having a concentration varying from between 1.0 and 35.0 weight percent of the total solids of the photoresist composition and containing at least ten percent of an esterification product of a diazooxide and curcumin dye having two pendant hydroxyl groups.
Claim 2
Dependent Claim 73 words
A photoresist composition responsive to activating radiation at a wavelength within the range of from 200 to 460 nm comprising an admixture of a polymer binder and a photoactive compound, said photoactive compound having a concentration varying from between 1.0 and 35.0 weight percent of the total solids of the photoresist composition and containing at least ten percent of an esterification product of a diazooxide and curcumin dye having two pendant hydroxyl groups.
Claim 3
Dependent Claim 39 words
The photoresist of claim 1 wherein the diazooxide corresponds to the following general formula: ##STR4## where X and X' are N 2 or O and are different from each other, Y is hydrogen or halogen and Y' is halogen.
Claim 4
Dependent Claim 40 words
The photoresist of claim 2 wherein the photoactive compound corresponds to the following general formula: ##STR5## wherein X and X' are N 2 or O and are different from each other, Y is hydrogen or halogen and Y' is 1,7-bis-(4-hydroxy-3-methoxyphenyl)-1,6-heptadiene-3,5-dione.
Claim 5
Dependent Claim 51 words
The photoresist of claim 2 wherein the binder is a member selected from the group of novolak resins; polyglutarimides; polyvinyl alcohol; a terpolymer that is the reaction product os an alkyl acrylate, a styrene and an acid; and the polyamic condensation products of an aromatic dianhydride and an aromatic di-primary amine.
Claim 6
Dependent Claim 35 words
The photoresist of claim 1 wherein the photoactive compound is a mixture of a diazo oxide photoactive compound free of curcim in its structure and the esterification product of a diazo oxide and curcumin dye.
Claim 7
Dependent Claim 20 words
The photoresist of claim 1 wherein the photoactive compound is the esterification product of a diazo oxide and curcumin dye.
Claim 8
Dependent Claim 12 words
The photoresist of claim 4 wherein the binder is a novolak resin.
Claim 9
Dependent Claim 12 words
The photoresist of claim 7 in the form of a dry film.
Claim 10
Dependent Claim 13 words
The photoresist of claim 7 where the photoresist is a liquid coating composition.
Claim 11
Dependent Claim 11 words
The photoresist of claim 4 wherein the binder is a polyglutarimide.
Claim 12
Dependent Claim 12 words
The photoresist of claim 10 in the form of a dry film.
Claim 13
Dependent Claim 16 words
The photoresist of claim 11 where the dry film is one of several layers of photoresist.
Claim 14
Dependent Claim 18 words
The photoresist of claim 11 where the dry film is a planarizing layer in a multilayer film combination.
Claim 15
Dependent Claim 12 words
The photoresist of claim 4 where the binder is a polyvinyl phenol.
Claim 16
Dependent Claim 12 words
The photoresist of claim 14 in the form of a dry film.
Claim 17
Dependent Claim 13 words
The photoresist of claim 14 where the photoresist is a liquid coating composition.
Claim 18
Dependent Claim 53 words
A photoactive compound that is the esterification product of curcumin dye having two pendant hydroxyl groups and a diazooxide where the diazooxide corresponds to the following general formula: ##STR6## where X and X' are N 2 or O and are different from each other, Y is hydrogen or halogen and Y' is halogen.
Claim 19
Dependent Claim 53 words
A photoactive compound that is the esterification product of curcumin dye having two pendant hydroxyl groups and a diazooxide where the diazooxide corresponds to the following general formula: ##STR6## where X and X' are N 2 or O and are different from each other, Y is hydrogen or halogen and Y' is halogen.
Claim 20
Dependent Claim 26 words
The photoactive compound of claim 17 where the esterification product is a member selected from the group of monoesters, diesters and mixtures of monoesters and diesters.
Claim 21
Dependent Claim 19 words
The photoactive compound of claim 18 where the esterification product is a mixture of a monoester and a diester.

References Cited (Backward Citations)

US3046116A Cited
US3046115A Cited
GB1039475A Cited
GB1052699A Cited
US4594306A Cited
EP0200129A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-03 1992-10-03 1993-04-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-03 1996-10-03 1997-04-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-03 2000-10-03 2001-04-04 $7700.00 Window Closed / Lapsed

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