US4824947A
Expired / Lapsed
US
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Substituted phthalocyanine
Assignee: Syngenta Ltd
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Filing: 1988-03-01
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Granted: 1989-04-25
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Expires: 2008-03-01
Abstract
Abstract A phthalocyanine compound of the formula: <CHEM> wherein Pc is a phthalocyanine nucleus; each R independently is optionally substituted phenyl; m is 4 to 12; V is H or C1-4-alkyl; each R<1> independently is optionally substituted phenylene or naphthylene in which the S atom and group N-C are attached to adjacent nuclear carbon atoms; and n is 2 to 6; provided that R is not R<1>-NHV. The compounds have a significant absorption band in the near infra red and are soluble in non-polar organic media. The compounds are useful in many applications where absorption of infra-red radiation is desirable, such as in OCR readable inks, security printing and reprographic toners.
Inventors
- 👤 William M. Stark
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 14:16
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/03; C09D11/037; C09B; C09B47/00; C09B47/04; C09B47/045; C09B47/06; C09B47/063; C09B47/064; C09B47/08; C09B47/20; C09B47/22; G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/246; G11B7/248
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
178 words
A phthalocyanine compound of the formula: ##STR6## wherein Pc is a phthalocyanine nucleus; each R independently is selected from phenyl, naphthyl and phenyl substituted by from 1 to 3 substituents selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; m is 4 to 12; V is H or C 1-4 -alkyl; each R 1 independently is selected from phenylene, naphthylene, substituted phenylene and substituted naphthylene in which the substituents are selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; and the S atom and the group N-V are attached to adjacent nuclear carbon atoms; and n is 2 to 6.
Claim 2
Dependent Claim
178 words
A phthalocyanine compound of the formula: ##STR6## wherein Pc is a phthalocyanine nucleus; each R independently is selected from phenyl, naphthyl and phenyl substituted by from 1 to 3 substituents selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; m is 4 to 12; V is H or C 1-4 -alkyl; each R 1 independently is selected from phenylene, naphthylene, substituted phenylene and substituted naphthylene in which the substituents are selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; and the S atom and the group N-V are attached to adjacent nuclear carbon atoms; and n is 2 to 6.
Claim 3
Dependent Claim
10 words
A compound according to claim 1 wherein Pc is Cu(II)Pc.
Claim 4
Dependent Claim
17 words
A compound according to claim 1 wherein R is phenyl, 4-(C 1-4 -alkyl)phenyl or 4-(C 1-4 -alkoxyphenyl).
Claim 5
Dependent Claim
25 words
A compound according to claim 1 wherein m is 6 to 10, n is from 3 to 5 and 2m+n is from 13 to 16.
Claim 6
Dependent Claim
137 words
A compound of the formula: ##STR7## wherein Pc is a phthalocyanine nucleus; each R independently is selected from phenyl, naphthyl and phenyl substituted by from 1 to 3 substituents selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; m is 4 to 12; V is H or C 1-4 -alkyl; n is 2 to 6; and W, X, Y & Z are each independently selected from H, halogen and C 1-10 -alkyl; or any adjacent pair of W, X, Y & Z represents a fused benzene ring which is unsubstituted or substituted by halogen or C 1-10 -alkyl.
Claim 7
Dependent Claim
137 words
A compound of the formula: ##STR7## wherein Pc is a phthalocyanine nucleus; each R independently is selected from phenyl, naphthyl and phenyl substituted by from 1 to 3 substituents selected from C 1-10 -alkyl, C 1-10 -alkoxy, S-C 1-10 -alkyl, halogen, phenyl, COOH, COT 1 , CONT 1 T 2 , SO 2 T 1 and SO 2 NT 1 T 2 in which T 1 and T 2 are selected from H, alkyl, aryl and aralkyl; m is 4 to 12; V is H or C 1-4 -alkyl; n is 2 to 6; and W, X, Y & Z are each independently selected from H, halogen and C 1-10 -alkyl; or any adjacent pair of W, X, Y & Z represents a fused benzene ring which is unsubstituted or substituted by halogen or C 1-10 -alkyl.
Claim 8
Dependent Claim
38 words
A phthalocyanine compound of the formula: ##STR8## wherein: R is phenyl, 4-(C 1-4 -alkyl)phenyl or 4-(C 1-4 -alkoxy)phenyl; m is 7 or 8; n is 4; V, W, X, Y & Z are H; and Pc is Cu(II)Pc.
Claim 9
Dependent Claim
38 words
A phthalocyanine compound of the formula: ##STR8## wherein: R is phenyl, 4-(C 1-4 -alkyl)phenyl or 4-(C 1-4 -alkoxy)phenyl; m is 7 or 8; n is 4; V, W, X, Y & Z are H; and Pc is Cu(II)Pc.
References Cited (Backward Citations)
DE2455675A1
Cited
US4606859A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-04-24 | 1992-10-24 | 1993-04-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-04-24 | 1996-10-24 | 1997-04-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-04-24 | 2000-10-24 | 2001-04-25 | $7700.00 | Window Closed / Lapsed |