US4826829A
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2-Substituted ethynyl thiophene pesticides
Assignee: FMC Corp
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Filing: 1988-03-09
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Granted: 1989-05-02
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Expires: 2008-03-09
Abstract
Abstract Thiophene derivatives of the following formula are effective as acaricdies: ##STR1## wherein A is selected from -phenylthienyl and -phenyl optionally carrying one or more substitutents selected from -lower alkyl, -lower alkoxy, -phenoxy, -hydroxy, -halogen, -lower haloalkyl, -phenylcarbonyl, -lower alkyl carbonyloxy, -lower alkyl sulfonyl, -lower alkyl sulfonyloxy, -amino, -lowr alkyl carboxamido, and -lower haloalkyl carboxamido; R 4 is selected from -hydrogen and -lower alkyl; and R 5 is selected from -thienyl optionally carrying one or more substituents selected from -lower alkyl, -phenylethynyl, -lower alkylthio, -lower haloalkyl carbonyl, and lower alkyl sulfoxy; or -phenyl optionally carrying one or more substituents selected from -lower alkyl and -lower alkoxy.
Inventors
- 👤 Susan E. Eurkart
- 👤 Richard B. Phillips
- 👤 David M. Roush
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:43
CPC Classifications
C; C07; C07D; C07D333/00; C07D333/02; C07D333/04; C07D333/06; C07D333/14; C07D333/16; A; A01; A01N; A01N43/00; A01N43/02; A01N43/04; A01N43/06; A01N43/10; C07D333/08; C07D333/12; C07D333/18; C07D333/20; C07D333/26; C07D333/30; C07D333/34
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
125 words
A compound of the formula ##STR3## in which: (a) R 5 is phenyl, R 4 is hydrogen, and A is selected from the group consisting of halophenyl, alkoxyphenyl, phenoxyphenyl, aminophenyl, alkylcarbonylaminophenyl, haloalkylcarbonylaminophenyl, haloalkoxyphenyl, halothienyl, alkoxycarbonylthienyl, haloalkoxyalkylphenyl, naphthyl, haloalkylphenyl, and (alkyl)halophenyl; or (b) A is phenyl, R 4 is hydrogen or methyl and R 5 is selected from the group consisting of alkoxyphenyl, phenylethynylthienyl, haloalkylcarbonylthienyl, halophenyl, halothienyl, alkoxycarbonylthienyl, cycloalkyloxycarbonylthienyl, naphthyl and phenylethynyl; (c) R 5 is 5-methylthienyl, R 4 is hydrogen and A is selected from the group consisting of haloalkylphenyl, formylphenyl, phenylcarbonylphenyl, alkylsulfonyloxyphenyl, alkylcarbonyloxyphenyl, alkylsulfonylphenyl, hydroxyphenyl, alkoxyphenyl and halophenyl; (d) A is alkylphenyl or alkoxyphenyl, R 4 is hydrogen and R 5 is selected from the group consisting of alkylthiothienyl, alkylsulfinylthienyl, O,O-dialkylphosphorylthienyl, alkoxyphenylethynyl and alkoxycarbonylthienyl.
Claim 2
Dependent Claim
125 words
A compound of the formula ##STR3## in which: (a) R 5 is phenyl, R 4 is hydrogen, and A is selected from the group consisting of halophenyl, alkoxyphenyl, phenoxyphenyl, aminophenyl, alkylcarbonylaminophenyl, haloalkylcarbonylaminophenyl, haloalkoxyphenyl, halothienyl, alkoxycarbonylthienyl, haloalkoxyalkylphenyl, naphthyl, haloalkylphenyl, and (alkyl)halophenyl; or (b) A is phenyl, R 4 is hydrogen or methyl and R 5 is selected from the group consisting of alkoxyphenyl, phenylethynylthienyl, haloalkylcarbonylthienyl, halophenyl, halothienyl, alkoxycarbonylthienyl, cycloalkyloxycarbonylthienyl, naphthyl and phenylethynyl; (c) R 5 is 5-methylthienyl, R 4 is hydrogen and A is selected from the group consisting of haloalkylphenyl, formylphenyl, phenylcarbonylphenyl, alkylsulfonyloxyphenyl, alkylcarbonyloxyphenyl, alkylsulfonylphenyl, hydroxyphenyl, alkoxyphenyl and halophenyl; (d) A is alkylphenyl or alkoxyphenyl, R 4 is hydrogen and R 5 is selected from the group consisting of alkylthiothienyl, alkylsulfinylthienyl, O,O-dialkylphosphorylthienyl, alkoxyphenylethynyl and alkoxycarbonylthienyl.
Claim 3
Dependent Claim
23 words
An acaricidal composition comprising an acaricidally effective amount of at least one compound of claim 1 in admixture with an agriculturally acceptable carrier.
Claim 4
Dependent Claim
31 words
A method for controlling acarids which comprises applying to the acarid, its habitat or plants upon which it feeds an acaricidally effective amount of at least one compound of claim 1.
Claim 5
Dependent Claim
9 words
The method of claim 3, employing the compound 1-(5-phenylthien-2-yl)-2-(4-methylphenyl)ethyne.
Claim 6
Dependent Claim
9 words
The method of claim 3, employing the compound 1-[5'-methyl(2,2'-bithien-5-yl)]-2-(4-chlorophenyl)ethyne.
References Cited (Backward Citations)
No citation records indexed.
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