US4830893A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Silicone rubber-covered copier roll
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1988-01-20
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Granted: 1989-05-16
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Expires: 2008-01-20
Abstract
Abstract The silicone rubber obtained by curing in the presence of a platinum-containing catalyst a composition comprising an organopolysiloxane containing a plurality of lower alkenyl radicals and a organohydrogensiloxane consisting essentially of R3SiO1/2 units, R2SiO units, RHSiO units, and RSiO3/2 units in a specified molar ratio is uniquely suitable as the coating material for the press roll in the fixing assembly of an electrophotographic copier.
Inventors
- 👤 Akito Nakamura
- 👤 Junpei Sugihara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 11:58
CPC Classifications
G; G03; G03G; G03G15/00; G03G15/65; C; C08; C08L; C08L83/00; C08L83/04; G03G15/20; G03G15/2003; G03G15/2014; G03G15/2053; G03G15/2057; G03G15/206; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/20; C08G77/22; C08G77/24; C08G77/70; G03G2215/00; G03G2215/00362; G03G2215/00367; G03G2215/00371; G03G2215/00535; G03G2215/00679; G03G2215/00683; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355; Y10T428/1386; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T428/2973; Y10T428/2975; Y10T428/31504; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
225 words
In a silicone rubber-covered roll for use in an electrophotographic copier, said roll comprising a roll axle and a layer of silicone rubber obtained by curing a composition comprising (A) 100 parts by weight of an organopolysiloxane having at least 2 silicon-bonded lower alkenyl radicals in each molecule; (B) an organohydrogensiloxane wherein each molecule contains at least two silicon-bonded hydrogen atoms, and the amount of said organohydrogensiloxane is equivalent to a molar ratio of silicon-bonded hydrogen atoms in (B) to lower alkenyl radicals in (A) of from 0.5 to 20; and (C) a platinum-containing catalyst in a quantity providing 0.1 to 500 parts by weight of platinum metal for each 1 million weight parts of the total quantity of components (A) and (B), the improvement characterized by (1) selecting said cured silicone rubber from those exhibiting a hardness value in the range of from 10 to 70 measured on the A scale in accordance with Japanese Industrial Standard C 2123 and a compression set of 10% or less, and (2) selecting said organohydrogensiloxane from organosiloxane copolymers comprising R 3 SiO 1/2 units, R 2 SiO units, RHSiO units, and RSiO 3/2 units, where each R is individually selected from monovalent hydrocarbon or halogenated hydrocarbon radicals free of ethylenic unsaturation, and where from 0.5 to 50 mol % of said copolymer consists of RSiO 3/2 units.
Claim 2
Dependent Claim
225 words
In a silicone rubber-covered roll for use in an electrophotographic copier, said roll comprising a roll axle and a layer of silicone rubber obtained by curing a composition comprising (A) 100 parts by weight of an organopolysiloxane having at least 2 silicon-bonded lower alkenyl radicals in each molecule; (B) an organohydrogensiloxane wherein each molecule contains at least two silicon-bonded hydrogen atoms, and the amount of said organohydrogensiloxane is equivalent to a molar ratio of silicon-bonded hydrogen atoms in (B) to lower alkenyl radicals in (A) of from 0.5 to 20; and (C) a platinum-containing catalyst in a quantity providing 0.1 to 500 parts by weight of platinum metal for each 1 million weight parts of the total quantity of components (A) and (B), the improvement characterized by (1) selecting said cured silicone rubber from those exhibiting a hardness value in the range of from 10 to 70 measured on the A scale in accordance with Japanese Industrial Standard C 2123 and a compression set of 10% or less, and (2) selecting said organohydrogensiloxane from organosiloxane copolymers comprising R 3 SiO 1/2 units, R 2 SiO units, RHSiO units, and RSiO 3/2 units, where each R is individually selected from monovalent hydrocarbon or halogenated hydrocarbon radicals free of ethylenic unsaturation, and where from 0.5 to 50 mol % of said copolymer consists of RSiO 3/2 units.
Claim 3
Dependent Claim
25 words
A roll according to claim 1 where said R radicals are lower alkyl, phenyl or 3,3,3-trifluoropropyl and said hardness value is from 10 to 30.
Claim 4
Dependent Claim
51 words
A roll according to claim 2 where said R radicals are methyl, said organopolysiloxane is a dimethylvinylsiloxy-terminated dimethylpolysiloxane, said hardness value is from 10 to 25, said molar ratio is from 1 to 3, and said layer of silicone rubber is cured at a temperature of from 100 to 170° C.
Claim 5
Dependent Claim
13 words
A roll according to claim 1 where said roll is a press roll.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-05-15 | 1992-11-14 | 1993-05-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-15 | 1996-11-14 | 1997-05-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-15 | 2000-11-14 | 2001-05-16 | $7700.00 | Window Closed / Lapsed |