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US4835093A Expired / Lapsed US ⏱️ 0.0 years remaining

Internally doped silver halide emulsions

Assignee: Eastman Kodak Co
•
Filing: 1988-04-08
•
Granted: 1989-05-30
•
Expires: 2008-04-08
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Abstract

Abstract A photographic silver halide emulsion is disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure and internally containing rhenium ions.

Inventors

  • 👤 Gaile A. Janusonis
  • 👤 Ralph W. Jones
  • 👤 James R. Buntaine
  • 👤 Myra T. Olm
  • 👤 Raymond S. Eachus

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:37
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/09; G03C1/015; G03C1/485; G03C1/48515; G03C1/48523

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 24 words
A photographic silver halide emulsion comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing rhenium ions.
Claim 2
Dependent Claim 24 words
A photographic silver halide emulsion comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing rhenium ions.
Claim 3
Dependent Claim 19 words
A photographic emulsion according to claim 1 in which the emulsion is a silver bromide or silver bromoiodide emulsion.
Claim 4
Dependent Claim 16 words
A photographic emulsion according to claim 1 in which the emulsion is a high chloride emulsion.
Claim 5
Dependent Claim 23 words
A photographic emulsion according to claim 1 in which rhenium is present in the emulsion in an amount sufficient to reduce photographic speed.
Claim 6
Dependent Claim 29 words
A photographic emulsion according to claim 1 in which a ligand differing from the halide forming the silver halide grains is incorporated in the grains along with rhenium ions.
Claim 7
Dependent Claim 18 words
A photographic emulsion according to claim 5 in which the incorporated ligand is a halide or aquo ligand.
Claim 8
Dependent Claim 62 words
A photographic emulsion according to claim 1 in which the rhenium ion is introduced into the emulsion in the form of a hexacoordination complex satisfying the formula: [ReL.sub.6 ].sup.k where L is chosen from halide and aquo ligands, with the proviso that no more than two of the ligands are aquo ligands k is the integer zero, -1, -2, -3, or -4.
Claim 9
Dependent Claim 20 words
A photographic emulsion according to claim 7 in which the silver halide grains are silver bromide or silver bromoiodide grains.
Claim 10
Dependent Claim 16 words
A photographic emulsion according to claim 8 in which the halide forming the ligands is chloride.
Claim 11
Dependent Claim 30 words
A photographic emulsion according to claim 9 in which rhenium ion is present in the grains in a concentration of from 10 -8 to 10 -7 mole per silver mole.
Claim 12
Dependent Claim 16 words
A photographic emulsion according to claim 8 in which the halide forming the ligands is bromide.
Claim 13
Dependent Claim 30 words
A photographic emulsion according to claim 11 in which rhenium ion is present in the grains in a concentration of from 10 -7 to 10 -5 mole per silver mole.
Claim 14
Dependent Claim 35 words
A photographic emulsion according to claim 1 in which the silver halide grains are surface fogged and the rhenium ions are present in a concentration sufficient to internally trap free electrons generated by photographic exposure.
Claim 15
Dependent Claim 28 words
A photographic emulsion according to claim 13 in which the rhenium ions are present in a concentration of from 10 -3 to 10 -8 mole per silver mole.
Claim 16
Dependent Claim 28 words
A photographic emulsion according to claim 14 in which the rhenium ions are present in a concentration of from 10 -4 to 10 -6 mole per silver mole.
Claim 17
Dependent Claim 21 words
A photographic emulsion according to claim 13 in which the silver halide grains are reduction and gold fogged at their surfaces.

References Cited (Backward Citations)

US2448060A Cited
US2458442A Cited
US2950972A Cited
US3287136A Cited
US3890154A Cited
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US3901711A Cited
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EP0242190A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-05-29 1992-11-28 1993-05-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-05-29 1996-11-28 1997-05-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-05-29 2000-11-28 2001-05-30 $7700.00 Window Closed / Lapsed

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