UV-stabilized coatings

Claim 2

A composition, which comprises: (i) a polymerizable acrylic monomer or oligomer and (ii) an ultraviolet radiation-absorbing effective amount of an ultraviolet radiation absorber of the formula ##STR3## wherein R 1 is hydrogen, a halogen, a lower alkyl of from 1 to abut 6 carbon atoms or a lower alkoxy of from 1 to about 6 carbon atoms; R 2 is hydrogen, halogen, lower alkyl of from 1 to about 6 carbon atoms, or an arylsulfonyl, wherein the aryl group contains from 6 to about 10 carbon atoms; n is an integer from 1 to about 4; m is 3 and R 3 is a trivalent hydrocarbon radical or lower alkyl ether radical of from 2 to about 22 carbon atoms.

Claim 3

The composition of claim 1, wherein said composition contains a photoinitiator and said acrylic monomer is at least one ultraviolet light curable polyfunctional acrylate monomer represented by the general formula ##STR4## wherein p is an integer having a value of from 2 to 4, and R 4 is a substituted or unsubstituted p-valent aliphatic hydrocarbon residue.

Claim 4

The composition of claim 2, wherein said composition contains an amount of a photoinitiator effective to initiate the photocure of said ultraviolet light curable polyfunctional acrylate monomer upon exposure to ultraviolet light.

Claim 5

An article comprising a substrate having thereon an ultraviolet light cured thermoset coating comprised of the photoreaction products of: (i) at least one polyfunctional acrylate monomer represented by the general formula ##STR5## wherein p is an integer having a value of from 2 to 4, and R 4 is selected from the group consisting of a substituted or unsubstituted p-valent aliphatic hydrocarbon residue (ii) an ultraviolet radiation absorber having the general formula ##STR6## wherein R 1 is hydrogen, a halogen, a lower alkyl of from 1 to about 6 carbon atoms or a lower alkoxy of from 1 to about 6 carbon atoms; R 2 is hydrogen, halogen, lower alkyl of from 1 to about 6 carbon atoms, or an arylsulfonyl, wherein the aryl group contains from 6 to about 10 carbon atoms; n is an integer from 1 to about 4, m is 3 and R 3 is a trivalent hydrocarbon radical or lower alkyl ether radical of from 2 to about 22 carbon atoms.

Claim 6

An article comprising a substrate having thereon an ultraviolet light cured thermoset coating comprised of the photoreaction products of: (i) at least one polyfunctional acrylate monomer represented by the general formula ##STR5## wherein p is an integer having a value of from 2 to 4, and R 4 is selected from the group consisting of a substituted or unsubstituted p-valent aliphatic hydrocarbon residue (ii) an ultraviolet radiation absorber having the general formula ##STR6## wherein R 1 is hydrogen, a halogen, a lower alkyl of from 1 to about 6 carbon atoms or a lower alkoxy of from 1 to about 6 carbon atoms; R 2 is hydrogen, halogen, lower alkyl of from 1 to about 6 carbon atoms, or an arylsulfonyl, wherein the aryl group contains from 6 to about 10 carbon atoms; n is an integer from 1 to about 4, m is 3 and R 3 is a trivalent hydrocarbon radical or lower alkyl ether radical of from 2 to about 22 carbon atoms.

Claim 7

The composition of claim 2, wherein said p-valent aliphatic hydrocarbon contains from 1 to about 20 carbons.

Claim 8

The composition of claim 2, wherein said p-valent aliphatic hydrocarbon residue contains from 1 to about 5 ether linkages.

Claim 9

The composition of claim 2, wherein said acrylate monomer is diethyleneglycol diacrylate.

Claim 10

The composition of claim 2, wherein said coating composition contains a mixture of hexanediol diacrylate and trimethylolpropane triacrylate.

Claim 11

The composition of claim 2, wherein said coating composition contains a mixture of hexanediol diacrylate and pentaerythritol triacrylate.

Claim 12

The composition of claim 2, wherein said coating composition contains a mixture of diethyleneglycol diacrylate and pentaerythritol triacrylate.

Claim 13

The composition of claims 2, 4 or 5 wherein R 3 is --CH 2 CH 2 --OCH 2 CH 2 -- y or --(CH 2 ) 6 --, wherein y is an integer from 2 to about 4, or a mixture thereof.

Claim 14

The composition of claims 2, 4 or 5 wherein R 2 is tert-butyl.

Claim 15

A thermoplastic article coated with the composition of claims 2 or 5, wherein the composition contains an ultraviolet light-absorbing effective amount of said ultraviolet radiation absorber.

Claim 16

A polycarbonate article coated with the composition of claims 2 or 5.

Claim 17

The article of claim 14, which is a lens for a vehicular headlamp.

Claim 18

A process for coating a thermoplastics substrate with an ultraviolet radiation-absorbing coating, comprising: (i) applying a thin layer of a coating composition onto the surface of said solid substrate, said coating composition containing (a) at least one polyfunctional acrylate monomer represented by the general formula ##STR7## wherein p is an integer having a value of from 2 to 4, and R 4 is selected from the group consisting of a substituted or unsubstituted p- valent aliphatic hydrocarbon residue, (b) a photoinitiator, and (c) an ultraviolet radiation absorber having the general formula ##STR8## wherein R 1 is hydrogen, a halogen, a lower alkyl of from 1 to about 6 carbon atoms or a lower alkoxy of from 1 to about 6 carbon atoms; R 2 is hydrogen, halogen, lower alkyl of from 1 to about 6 carbon atoms, or an arylsulfonyl, wherein the aryl group contains from 6 to about 10 carbon atoms; n is an integer from 1 to about 4, m is 3 and R 3 is a trivalent hydrocarbon radical or lower alkyl ether radical of from 2 to about 10 carbon atoms; and (ii) exposing said coated substrate to polymerizing radiation under polymerizing conditions for a period of time sufficient to polymerized and crosslink said polyfunctional acrylate monomers, thereby forming said coating.

Claim 19

A process for coating a thermoplastics substrate with an ultraviolet radiation-absorbing coating, comprising: (i) applying a thin layer of a coating composition onto the surface of said solid substrate, said coating composition containing (a) at least one polyfunctional acrylate monomer represented by the general formula ##STR7## wherein p is an integer having a value of from 2 to 4, and R 4 is selected from the group consisting of a substituted or unsubstituted p- valent aliphatic hydrocarbon residue, (b) a photoinitiator, and (c) an ultraviolet radiation absorber having the general formula ##STR8## wherein R 1 is hydrogen, a halogen, a lower alkyl of from 1 to about 6 carbon atoms or a lower alkoxy of from 1 to about 6 carbon atoms; R 2 is hydrogen, halogen, lower alkyl of from 1 to about 6 carbon atoms, or an arylsulfonyl, wherein the aryl group contains from 6 to about 10 carbon atoms; n is an integer from 1 to about 4, m is 3 and R 3 is a trivalent hydrocarbon radical or lower alkyl ether radical of from 2 to about 10 carbon atoms; and (ii) exposing said coated substrate to polymerizing radiation under polymerizing conditions for a period of time sufficient to polymerized and crosslink said polyfunctional acrylate monomers, thereby forming said coating.

Claim 20

The process of claim 16, wherein said polymerizing conditions include an inert atmosphere.

Claim 21

The process of claim 16, wherein R 4 is a p-valent saturated aliphatic hydrocarbon residue or a p-valent substituted saturated alphatic hydrocarbon residue.

Claim 22

The process of claim 16, wherein R 4 is p-valent hydroxyl-substituted saturated aliphatic hydrocarbon residue.

Claim 23

The process of claim 16, wherein R 4 is a p-valent saturated aliphatic hydrocarbon residue containing from 1 to 5 ether linkages.

Claim 24

The process of claim 16, wherein said thermoplastic substrate is a polycarbonate or a polyestercarbonate.

Claim 25

The article of claim 4 wherein said substrate comprises a resin selected from the group consisting of aromatic polycarbonates and polyestercarbonates.