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US4887671A Expired / Lapsed US ⏱️ 0.0 years remaining

Fracturing with a mixture of carbon dioxide and alcohol

Assignee: Texaco Development Corp
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Filing: 1988-12-23
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Granted: 1989-12-19
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Expires: 2008-12-23
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Abstract

Abstract The invention is a method of fracturing an underground formation penetrated by a wellbore, which comprises injecting into a formation a mixture of carbon dioxide and a polar alcohol or polar glycol additive at a temperature and pressure above the critical temperature and pressure of carbon dioxide. The alcohol or glycol additive should have less than about 9 carbon atoms and comprises about 0.1% to about 10% by weight of the injected mixture. The mixture is injected with sufficient volume and pressure to cause a fracture to be formed in the underground formation.

Inventors

  • 👤 James F. Stevens, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 21:12
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/25; E21B43/26; E21B43/2605; C; C09; C09K; C09K8/00; C09K8/60; C09K8/62; Y; Y10; Y10S; Y10S507/00; Y10S507/922

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 94 words
A method of fracturing an underground, formation penetrated by a wellbore, which consists essentially of: injecting into an underground formation through a wellbore a mixture of carbon dioxide and a polar alcohol or polar glycol additive at a temperature and pressure above the critical temperature and pressure of carbon dioxide, said alcohol or glycol additive having less than about 9 carbon atoms and comprising about 0.1% to about 10% by weight of the injected mixture; said mixture injected with sufficient volume and pressure to cause a fracture to be formed in said underground formation.
Claim 2
Independent Claim 94 words
A method of fracturing an underground, formation penetrated by a wellbore, which consists essentially of: injecting into an underground formation through a wellbore a mixture of carbon dioxide and a polar alcohol or polar glycol additive at a temperature and pressure above the critical temperature and pressure of carbon dioxide, said alcohol or glycol additive having less than about 9 carbon atoms and comprising about 0.1% to about 10% by weight of the injected mixture; said mixture injected with sufficient volume and pressure to cause a fracture to be formed in said underground formation.
Claim 3
Dependent Claim 14 words
The method of claim 1, wherein the injected mixture further comprises a proppant material.
Claim 4
Dependent Claim 10 words
The method of claim 1, wherein the additive is methanol.
Claim 5
Dependent Claim 10 words
The method of claim 1, wherein the additive is ethanol.
Claim 6
Dependent Claim 11 words
The method of claim 1, wherein the additive is ethylene glycol.
Claim 7
Dependent Claim 20 words
The method of claim 1, wherein the additive comprises about 1% to about 4% by weight of the injected mixture.
Claim 8
Independent Claim 79 words
A method of fracturing an underground formation penetrated by a wellbore, which consists essentially of: injecting into an underground formation through a wellbore a mixture of carbon dioxide and ethylene glycol at a temperature and pressure above the critical temperature and pressure of carbon dioxide, said ethylene glycol comprising about 1% to about 4% by weight of the injected mixture, said mixture injected with sufficient volume and pressure to cause a fracture to be formed in said underground formation.
Claim 9
Independent Claim 79 words
A method of fracturing an underground formation penetrated by a wellbore, which consists essentially of: injecting into an underground formation through a wellbore a mixture of carbon dioxide and ethylene glycol at a temperature and pressure above the critical temperature and pressure of carbon dioxide, said ethylene glycol comprising about 1% to about 4% by weight of the injected mixture, said mixture injected with sufficient volume and pressure to cause a fracture to be formed in said underground formation.

References Cited (Backward Citations)

US3664422A Cited
US4156464A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-18 1993-06-19 1993-12-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-18 1997-06-19 1997-12-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-18 2001-06-19 2001-12-19 $7700.00 Window Closed / Lapsed

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