US4902650A
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Gradient-index glass
Assignee: University of Rochester
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Filing: 1988-07-15
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Granted: 1990-02-20
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Expires: 2008-07-15
Abstract
Abstract A sol-gel method for making gradient-index glass and a novel composition therefor, comprising at least a ternary system of metal alkoxides.
Inventors
- 👤 J. Brian Caldwell
- 👤 Duncan T. Moore
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 07:31
CPC Classifications
C; C03; C03C; C03C1/00; C03C1/006; C03B; C03B2201/00; C03B2201/06; C03B2201/08; C03B2201/10; C03B2201/30; C03B2201/32; C03B2201/40; C03B2201/42; Y; Y10; Y10S; Y10S501/00; Y10S501/90
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
188 words
A gradient-index glass having a generally parabolic index of refraction about a central axis and which is produced from a sol-gel consisting essentially of at least three oxide components which are silicon dioxide (SiO 2 ) and, an index modifying dopant generally uniformly decreasing radially outward from the axis and consisting of a metal oxide selected from the group consisting of titanium oxide TiO 2 ) and zirconium oxide (ZrO 2 ) and at least one additional oxide element for gel modification selected from the group consisting of oxides of aluminum (Al 2 O 3 ), boron (B 2 O 3 ) and germanium (GeO 2 ), wherein said oxides are in an interconnected network and wherein the concentration of SiO 2 in the gel is between 60 and 98 mole percent of the total oxide content in the gel, the concentration of the index modifying dopant oxide in the gel is between 0.1 and 25 mole percent of the total oxide content in the gel, and the concentration of the additional metal oxide is less than 25 mole percent of the total oxide content in the gel.
Claim 2
Dependent Claim
188 words
A gradient-index glass having a generally parabolic index of refraction about a central axis and which is produced from a sol-gel consisting essentially of at least three oxide components which are silicon dioxide (SiO 2 ) and, an index modifying dopant generally uniformly decreasing radially outward from the axis and consisting of a metal oxide selected from the group consisting of titanium oxide TiO 2 ) and zirconium oxide (ZrO 2 ) and at least one additional oxide element for gel modification selected from the group consisting of oxides of aluminum (Al 2 O 3 ), boron (B 2 O 3 ) and germanium (GeO 2 ), wherein said oxides are in an interconnected network and wherein the concentration of SiO 2 in the gel is between 60 and 98 mole percent of the total oxide content in the gel, the concentration of the index modifying dopant oxide in the gel is between 0.1 and 25 mole percent of the total oxide content in the gel, and the concentration of the additional metal oxide is less than 25 mole percent of the total oxide content in the gel.
Claim 3
Dependent Claim
15 words
The gradient-index glass according to claim 1 wherein the index modifying dopant is titanium oxide.
Claim 4
Dependent Claim
17 words
The gradient-index glass according to claim 1 wherein the gel modification metal oxide element is aluminum oxide.
Claim 5
Dependent Claim
20 words
The gradient-index glass according to claim 1 wherein the gel modification metal oxide element is aluminum oxide and germanium oxide.
Claim 6
Dependent Claim
15 words
The gradient-index glass according to claim 1 wherein the index modifying dopant is zirconium oxide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-02-19 | 1993-08-21 | 1994-02-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-02-19 | 1997-08-21 | 1998-02-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-02-19 | 2001-08-21 | 2002-02-20 | $7700.00 | Window Closed / Lapsed |