US4917948A
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Reversible thermosensitive recording material
Assignee: Ricoh Co Ltd
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Filing: 1989-01-27
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Granted: 1990-04-17
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Expires: 2009-01-27
Abstract
Abstract A reversible thermosensitive recording material is disclosed, which comprises (a) a support, and (b) a reversible thermosensitive recording layer formed thereon, which comprises as the main components a matrix resin, at least one higher monocarboxylic fatty acid having 16 or more carbon atoms, and at least one aliphatic saturated dicarboxylic acid or a derivative thereof, with the ratio by weight of the amount of the higher monocarboxylic fatty acid to the amount of the aliphatic saturated dicarboxylic acid or a derivative thereof being in the range of (95:5) to (20:80).
Inventors
- 👤 Yoshihiko Hotta
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 14:22
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/36; B41M5/363; B41M5/30; B41M5/305; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/25; Y10T428/254; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T428/31725; Y10T428/31786; Y10T428/31855; Y10T428/31931; Y10T428/31935
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
205 words
A reversible thermosensitive recording material comprising: (a) a support, and (b) a reversible thermosensitive recording layer formed thereon, which comprises as the main components a matrix resin, at least one higher monocarboxylic fatty acid having 16 or more carbon atoms, and at least one aliphatic saturated dicarboxylic acid or derivative thereof, wherein said derivative is selected from the group consisting of p-nitrobenzyl esters, S-p-bromobenzylthiuronium salts, benzylammonium salts, diamides, anilides, phenacyl esters, monoamides, dihydrazides, p-bromophenacyl esters, dianilides, dibenzalhydrazides, S-p-chlorobenzylthiuronium salts, and p-phenylphenacyl esters, with the ratio by weight of the amount of said higher monocarboxylic fatty acid to the amount of said aliphatic saturated dicarboxylic acid or derivative thereof being in the range of (95:5) to (20:80), wherein said higher monocarboxylic fatty acid and said aliphatic saturated dicarboxylic acid or derivative thereof are dispersed as particles in said matrix resin and wherein said higher monocarboxylic fatty acid has a melting point ranging from about 30° C. to about 150° C., and said aliphatic saturated dicarboxylic acid or derivative thereof has a melting point ranging from about 80° C. to about 200° C., with the melting point of said higher monocarboxylic acid being higher than the melting point of said aliphatic saturated dicarboxylic acid or derivative thereof.
Claim 2
Dependent Claim
205 words
A reversible thermosensitive recording material comprising: (a) a support, and (b) a reversible thermosensitive recording layer formed thereon, which comprises as the main components a matrix resin, at least one higher monocarboxylic fatty acid having 16 or more carbon atoms, and at least one aliphatic saturated dicarboxylic acid or derivative thereof, wherein said derivative is selected from the group consisting of p-nitrobenzyl esters, S-p-bromobenzylthiuronium salts, benzylammonium salts, diamides, anilides, phenacyl esters, monoamides, dihydrazides, p-bromophenacyl esters, dianilides, dibenzalhydrazides, S-p-chlorobenzylthiuronium salts, and p-phenylphenacyl esters, with the ratio by weight of the amount of said higher monocarboxylic fatty acid to the amount of said aliphatic saturated dicarboxylic acid or derivative thereof being in the range of (95:5) to (20:80), wherein said higher monocarboxylic fatty acid and said aliphatic saturated dicarboxylic acid or derivative thereof are dispersed as particles in said matrix resin and wherein said higher monocarboxylic fatty acid has a melting point ranging from about 30° C. to about 150° C., and said aliphatic saturated dicarboxylic acid or derivative thereof has a melting point ranging from about 80° C. to about 200° C., with the melting point of said higher monocarboxylic acid being higher than the melting point of said aliphatic saturated dicarboxylic acid or derivative thereof.
Claim 3
Dependent Claim
28 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said higher monocarboxylic fatty acid is a saturated higher fatty acid having 16 to 26 carbon atoms.
Claim 4
Dependent Claim
52 words
The reversible thermosensitive recording material as claimed in claim 2, wherein said saturated higher fatty acid is selected from the group consisting of palmitic acid, margaric acid, stearic acid, nonadecanoic acid, eicosanic acid, heneicosanic acid, behenic acid, lignoceric acid, pentacosanoic acid, cerotoic acid, heptacosanoic acid, montanic acid, nonacosanoic acid, and melissic acid.
Claim 5
Dependent Claim
30 words
The reversible thermosensitive recording material as claimed in claim 3, wherein said saturated higher fatty acid is selected from the group consisting of stearic acid, eicosanic acid and behenic acid.
Claim 6
Dependent Claim
48 words
The reversible thermosensitive recording material as claimed in claim 1, wherein the ratio by weight of the amount of said higher monocarboxylic fatty acid and said aliphatic saturated dicarboxylic acid or derivative thereof to the amount of said matrix resin is in the range of (1:0.5) to (1:16).
Claim 7
Dependent Claim
48 words
The reversible thermosensitive recording material as claimed in claim 5, wherein the ratio by weight of the amount of said higher monocarboxylic fatty acid and said aliphatic saturated dicarboxylic acid or derivative thereof to the amount of said matrix resin is in the range of (1:1) to (1:3).
Claim 8
Dependent Claim
77 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said reversible thermosensitive recording layer further comprises at least one additive selected from the group consisting of a surface active agent and a plasticizer, in such an amount that the ratio by weight of the amount of said higher monocarboxylic fatty acid and said aliphatic saturated dicarboxylic acid or derivative thereof to the amount of said additive is approximately in the range of (1:0.01) to (1:0.8).
Claim 9
Dependent Claim
28 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said reversible thermosensitive recording layer has a thickness in the range of 1 μm to 30 μm.
Claim 10
Dependent Claim
58 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said matrix resin is selected from the group consisting of polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, vinyl chloride-vinyl acetate-vinyl alcohol copolymer, vinyl chloride-vinyl acetate-maleic acid copolymer, vinyl chloride-acrylate copolymer, polyvinylidene chloride, vinylidene chloride-vinyl chloride copolymer, vinylidene chloride-acrylonitrile copolymer, polyester, polyamide, polyacrylate, polymethacrylate, acrylate-methacrylate copolymer, and silicone resin.
Claim 11
Dependent Claim
69 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said higher monocarboxylic fatty acid is a saturated higher fatty acid selected from the group consisting of 2-hexadecenoic acid, trans-3-hexadecenoic acid, 2-heptadecenoic acid, trans-2-octadecenoic acid, cis-2-octadecenoic acid, trans-4-octadecenoic acid, cis-6-octadecenoic acid, elaidic acid, trans-11-octadecenoic acid, trans-11-eicosenoic acid, erucic acid, brassidic acid, selacholeic acid, trans-selacholeic acid, trans-8-trans-10-octadecadienoic acid, linoelaidic acid, α-eleostearic acid, β-eleostearic acid, pseudoeleostearic acid, and 12,20-heneicosadienoic acid.
Claim 12
Dependent Claim
56 words
The reversible thermosensitive recording material as claimed in claim 1, wherein said aliphatic saturated dicarboxylic acid is selected from the group consisting of: succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, heptadecanedioic acid, octadecanedioic acid, and nonadecanedioic acid.
Claim 13
Dependent Claim
40 words
The reversible thermosensitive recording material as claimed in claim 11, wherein said aliphatic saturated dicarboxylic acid is selected from the group consisting of: suberic acid, azelaic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, and pentadecanedioic acid.
References Cited (Backward Citations)
US4695528A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-04-16 | 1993-10-16 | 1994-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-16 | 1997-10-16 | 1998-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-16 | 2001-10-16 | 2002-04-17 | $7700.00 | Window Closed / Lapsed |