US4957590A
Expired / Lapsed
US
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Method for forming local interconnects using selective anisotropy
Assignee: Texas Instruments Inc
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Filing: 1989-09-05
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Granted: 1990-09-18
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Expires: 2009-09-05
Abstract
Abstract A method for etching titanium nitride local interconnects is disclosed. A layer of titaniun nitride is either formed as a by-product of the formation of titanium silicide by direct reaction or by deposition. The location of the interconnects is defined by patterning photoresist at the desired locations. A plasma etch using a chlorine-bearing agent such as CCl4 as the etchant etches the titanium nitride anisotropically at those locations covered by photoresist, and isotropically elsewhere, so that filaments of the titanium nitride are removed without undercutting the photoresist mask. The etch is selective relative to the underlying material, such as a refractory metal silicide, refractory metals, or silicon, due to the passivation of the underlying material by the carbon atoms of the CCl4. The selectivity, together with the selective anisotropy, even allows significant overetch of the material to remove the filaments without undercutting the masked interconnect material.
Inventors
- 👤 Monte A. Douglas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 04:36
CPC Classifications
H; H10; H10P; H10P95/00; H10P50/00; H10P50/20; H10P50/28; H10P50/282; H10P50/283; H10P50/26; H10P50/264; H10P50/266; H10P50/267; H10P50/268; H10P50/71; H10W; H10W20/00; H10W20/01; H10W20/031; H10W20/0698; H10W20/40; H10W20/41; H10W20/44; H10W20/4403; H10W20/4437; H10W20/4441
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
140 words
A method for forming a connection of a conductive titanium compound, over a dielectric and a conductor, on a semiconductor surface of a body, comprising: forming a layer comprising a conductive titanium compound in contact with said conductor and said dielectric, said layer of said conductive titanium compound disposed over a step near said surface; covering a portion of said conductive titanium compound with photoresist, said portion of said conductive titanium compound disposed over said step not covered by said photoresist; and exposing said body to a chlorine bearing agent in a plasma reactor to etch said conductive titanium compound from said conductor and said dielectric at locations not covered by said photoresist; wherein said exposing step substantially removes said conductive titanium compound from the location of said step without substantially removing said conductive titanium compound from under said photoresist.
Claim 2
Independent Claim
140 words
A method for forming a connection of a conductive titanium compound, over a dielectric and a conductor, on a semiconductor surface of a body, comprising: forming a layer comprising a conductive titanium compound in contact with said conductor and said dielectric, said layer of said conductive titanium compound disposed over a step near said surface; covering a portion of said conductive titanium compound with photoresist, said portion of said conductive titanium compound disposed over said step not covered by said photoresist; and exposing said body to a chlorine bearing agent in a plasma reactor to etch said conductive titanium compound from said conductor and said dielectric at locations not covered by said photoresist; wherein said exposing step substantially removes said conductive titanium compound from the location of said step without substantially removing said conductive titanium compound from under said photoresist.
Claim 3
Dependent Claim
13 words
The method of claim 1, wherein the conductive titanium compound comprises titanium nitride.
Claim 4
Dependent Claim
14 words
The method of claim 2, wherein said conductive titanium compound further comprises titanium oxide.
Claim 5
Dependent Claim
13 words
The method of claim 1, wherein said conductive titanium compound comprises titanium oxynitride.
Claim 6
Dependent Claim
13 words
The method of claim 1, wherein said conductive titanium compound comprises titanium oxide.
Claim 7
Dependent Claim
21 words
The method of claim 1, further comprising: mixing a chlorine scavenging reagent with the chlorine bearing agent in said flowing step.
Claim 8
Dependent Claim
13 words
The method of claim 1, wherein the chlorine bearing agent is carbon tetrachloride.
Claim 9
Dependent Claim
20 words
The method of claim 7, wherein the step of flowing further includes mixing an inert gas with said carbon tetrachloride.
Claim 10
Dependent Claim
19 words
The method of claim 1, wherein the step of igniting comprises passing radio frequency energy through said plasma etcher.
Claim 11
Dependent Claim
19 words
The method of claim 9, wherein the step of igniting further includes shining ultraviolet light through said plasma etcher.
Claim 12
Dependent Claim
12 words
The method of claim 1, wherein the conductor comprises a refractory metal.
Claim 13
Dependent Claim
15 words
The method of claim 11, wherein the conductor comprises a refractory metal other than titanium.
Claim 14
Dependent Claim
10 words
The method of claim 12, wherein the conductor comprises molybdenum.
Claim 15
Dependent Claim
10 words
The method of claim 12, wherein the conductor comprises tungsten.
Claim 16
Dependent Claim
10 words
The method of claim 1, wherein the conductor comprises silicon.
Claim 17
Dependent Claim
12 words
The method of claim 15, wherein the conductor comprises a silicide compound.
Claim 18
Dependent Claim
12 words
The method of claim 16, wherein the silicide compound is cobalt silicide.
Claim 19
Independent Claim
89 words
A method for forming a local interconnect at a silicon surface, comprising the steps of: forming an insulating layer over a selected location of said surface; forming an interconnect layer of material comprising titanium in contact with a conductor near said silicon surface and said insulating layer; covering a portion of said interconnect layer with a masking layer to define an interconnect; and etching said interconnect layer with a chlorine bearing agent in a plasma reactor to remove portions of said interconnect layer not covered by said masking layer.
Claim 20
Independent Claim
89 words
A method for forming a local interconnect at a silicon surface, comprising the steps of: forming an insulating layer over a selected location of said surface; forming an interconnect layer of material comprising titanium in contact with a conductor near said silicon surface and said insulating layer; covering a portion of said interconnect layer with a masking layer to define an interconnect; and etching said interconnect layer with a chlorine bearing agent in a plasma reactor to remove portions of said interconnect layer not covered by said masking layer.
Claim 21
Dependent Claim
85 words
The method of claim 18, wherein the step of forming said interconnect layer comprises: depositing a layer of titanium over said conductor, said insulating layer, and in contact with a location of said silicon surface; reacting said titanium in a nitrogen and argon ambient at a temperature sufficient to cause the titanium layer to react with said silicon surface to form a layer of titanium silicide covered with a layer of titanium nitride, and to form a layer of titanium nitride over said insulating layer.
Claim 22
Dependent Claim
27 words
The method of claim 18, wherein the step of forming said interconnect layer comprises: depositing a layer of titanium nitride over said conductor and said insulating layer.
Claim 23
Dependent Claim
16 words
The method of claim 18, wherein the step of etching comprises plasma etching with carbon tetrachloride.
Claim 24
Dependent Claim
21 words
The method of claim 21, wherein the step of etching further includes mixing a chlorine scavenging reagent with said carbon tetrachloride.
Claim 25
Dependent Claim
12 words
The method of claim 18, wherein the conductor comprises a refractory metal.
Claim 26
Dependent Claim
15 words
The method of claim 23, wherein the conductor comprises a refractory metal other than titanium.
Claim 27
Dependent Claim
10 words
The method of claim 24, wherein the conductor comprises molybdenum.
Claim 28
Dependent Claim
10 words
The method of claim 24, wherein the conductor comprises tungsten.
Claim 29
Dependent Claim
10 words
The method of claim 18, wherein the conductor comprises silicon.
Claim 30
Dependent Claim
12 words
The method of claim 27, wherein the conductor comprises a silicide compound.
Claim 31
Dependent Claim
12 words
The method of claim 28, wherein the silicide compound is cobalt silicide.
References Cited (Backward Citations)
US4574177A
Cited
US4657628A
Cited
US4676866A
Cited
US4690730A
Cited
US4784973A
Cited
US4793896A
Cited
US4793896C1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-09-17 | 1994-03-19 | 1994-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-09-17 | 1998-03-19 | 1998-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-09-17 | 2002-03-19 | 2002-09-18 | $7700.00 | Window Closed / Lapsed |