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US4992501A Expired / Lapsed US ⏱️ 0.0 years remaining

Repulpable tape

Assignee: Kendall Co
•
Filing: 1989-06-26
•
Granted: 1991-02-12
•
Expires: 2009-06-26
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Abstract

Abstract Repulpable tapes, their composition and the process of making the same, which retain adhesion and tack over a wide range of humidity and temperature, are provided. The improved composition comprises the addition of 10 to 50 parts by weight of a partially to fully hydrogenated rosin and at least 1 part by weight of polyethylene glycol.

Inventors

  • 👤 Robert Hanninen
  • 👤 Shiro G. Takemoto
  • 👤 Mildred C. Richards

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 13:06
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/062; C09J133/064; C09J7/00; C09J7/20; C09J7/21; C09J7/30; C09J7/38; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/26; C08L71/00; C08L71/02; C08L93/00; C08L93/04; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2835; Y10T428/2852; Y10T428/2878; Y10T428/2883

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 260 words
In a pressure-sensitive adhesive composition for preparing repulpable pressure-sensitive tapes comprising (1) 49 to 89 parts by weight of the neutralized reaction product of a C 6 -C 18 alkyl phenol or C 6 -C 18 alkanol containing about 4 to 30 moles combined ethylene oxide with a copolymer obtained by the polymerization of a monomer composition comprising by weight: from about 35 to 85% of acrylate monomer of the formula CH 2 ═C(R)--COOR 1 wherein R is hydrogen or C 1 -C 4 alkyl, and R 1 is C 1 -C 14 alkyl; with the proviso that at least 60% is C 4 substituted (i.e. for R 1 ) acrylates; from about 8 to 30% of an alpha,beta-ethylenically unsaturated di-carboxylic acid anhydride and from about 8 to 30% of monomer selected from vinyl esters, vinyl ethers, vinyl halides, styrene, C 1 -C 4 alkyl styrenes, lower (C 1 to C 6 ) alkyl methacrylates and alpha-olefins, the weight ratio of acrylate to anhydride being from about 1.5:1 to 8:1, the amount of said alkyl phenol or alkanol being sufficient to provide an alkyl phenol or alkanol:anhydride mole ratio of about 0.3 to 1.0 and at least about 0.7 when said acrylate:anhydride weight ratio is below about 4; the improvement wherein said composition further includes (2) from about 10 to about 50 parts by weight of a partially to fully hydrogenated rosin; and (3) at least 1 part by weight of polyethylene glycol; said composition being characterized by retaining its adhesion properties over a wide range of humidity and temperature.
Claim 2
Dependent Claim 260 words
In a pressure-sensitive adhesive composition for preparing repulpable pressure-sensitive tapes comprising (1) 49 to 89 parts by weight of the neutralized reaction product of a C 6 -C 18 alkyl phenol or C 6 -C 18 alkanol containing about 4 to 30 moles combined ethylene oxide with a copolymer obtained by the polymerization of a monomer composition comprising by weight: from about 35 to 85% of acrylate monomer of the formula CH 2 ═C(R)--COOR 1 wherein R is hydrogen or C 1 -C 4 alkyl, and R 1 is C 1 -C 14 alkyl; with the proviso that at least 60% is C 4 substituted (i.e. for R 1 ) acrylates; from about 8 to 30% of an alpha,beta-ethylenically unsaturated di-carboxylic acid anhydride and from about 8 to 30% of monomer selected from vinyl esters, vinyl ethers, vinyl halides, styrene, C 1 -C 4 alkyl styrenes, lower (C 1 to C 6 ) alkyl methacrylates and alpha-olefins, the weight ratio of acrylate to anhydride being from about 1.5:1 to 8:1, the amount of said alkyl phenol or alkanol being sufficient to provide an alkyl phenol or alkanol:anhydride mole ratio of about 0.3 to 1.0 and at least about 0.7 when said acrylate:anhydride weight ratio is below about 4; the improvement wherein said composition further includes (2) from about 10 to about 50 parts by weight of a partially to fully hydrogenated rosin; and (3) at least 1 part by weight of polyethylene glycol; said composition being characterized by retaining its adhesion properties over a wide range of humidity and temperature.
Claim 3
Dependent Claim 14 words
The composition as described in claim 1, wherein said acrylate monomer is butyl acrylate.
Claim 4
Dependent Claim 13 words
The composition as described in claim 1, wherein said anhydride is maleic anhydride.
Claim 5
Dependent Claim 14 words
The composition as described in claim 1, wherein the auxiliary monomer is vinyl acetate.
Claim 6
Dependent Claim 13 words
The composition as described in claim 4, wherein the vinyl acetate is hydrolized.
Claim 7
Dependent Claim 18 words
The composition as described in claim 1, wherein said partially to fully hydrogenated rosin is a wood rosin.
Claim 8
Dependent Claim 14 words
The composition as described in claim 6, wherein said wood rosin is abietic acid.
Claim 9
Dependent Claim 19 words
The composition as described in claim 1, wherein said polyethylene glycol has a molecular weight of at least 200.
Claim 10
Dependent Claim 13 words
The composition as described in claim 8, wherein said polyethylene glycol is liquid.
Claim 11
Dependent Claim 17 words
A repulpable tape comprising a support carrying a layer of a composition as described in claim 1.
Claim 12
Dependent Claim 15 words
The repulpable tape as described in claim 10, wherein said acrylate monomer is butyl acrylate.
Claim 13
Dependent Claim 14 words
The repulpable tape as described in claim 10 wherein said anhydride is maleic anhydride.
Claim 14
Dependent Claim 15 words
The repulpable tape as described in claim 10, wherein the auxiliary monomer is vinyl acetate.
Claim 15
Dependent Claim 14 words
The repulpable tape as described in claim 13, wherein the vinyl acetate is hydrolized.
Claim 16
Dependent Claim 19 words
The repulpable tape as described in claim 10, wherein said partially to fully hydrogenated rosin is a wood rosin.
Claim 17
Dependent Claim 15 words
The repulpable tape as described in claim 15, wherein said wood rosin is abietic acid.
Claim 18
Dependent Claim 20 words
The repulpable tape as described in claim 10, wherein said polyethylene glycol has a molecular weight of at least 200.
Claim 19
Dependent Claim 14 words
The repulpable tape as described in claim 10, wherein said polyethylene glycol is liquid.
Claim 20
Dependent Claim 84 words
A process for making the adhesive composition as described in claim 1, comprising the steps of (1) polymerizing said monomer composition to form a polymer; (2) esterifying said resultant polymer with a sufficient amount of alkanol or alkyl phenol; (3) neutralizing said esterified polymer with an alkaline material; (4) adding 10-50 parts by weight of a partially to fully hydrogenated rosin to 100 parts by weight of the resultant neutralized polymer; and thereafter (5) adding at least 1 part by weight of polyethylene glycol.
Claim 21
Dependent Claim 21 words
The process as described in claim 19 wherein polymerization was promoting by adding a catalyst solution of Azobis-isobutyronitrile and ethyl acetate.
Claim 22
Dependent Claim 15 words
The process as described in claim 19, wherein esterification is effected by adding Igepal Co-630.
Claim 23
Dependent Claim 14 words
The process as described in claim 19, wherein the alkaline material is sodium hydroxide.
Claim 24
Dependent Claim 14 words
The process as described in claim 19, wherein the rosin is a wood rosin.
Claim 25
Dependent Claim 14 words
The process as described in claim 23, wherein the wood rosin is abietic acid.
Claim 26
Dependent Claim 19 words
The process as described in claim 19, wherein the polyethylene glycol has a molecular weight of at least 200.
Claim 27
Dependent Claim 13 words
The process as described in claim 19, wherein the polyethylene glycol is liquid.

References Cited (Backward Citations)

US3441430A Cited
US3838079A Cited
US3865770A Cited
US4442258A Cited
US4482675A Cited
US4569960A Cited
US4913080A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-02-11 1994-08-13 1995-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-02-11 1998-08-13 1999-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-02-11 2002-08-13 2003-02-12 $7700.00 Window Closed / Lapsed

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