US5049408A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for coating phosphor particles using aluminum isopropoxide precursors and an isothermal fluidized bed
Assignee: Osram Sylvania Inc
•
Filing: 1990-08-24
•
Granted: 1991-09-17
•
Expires: 2010-08-24
Abstract
Abstract Disclosed is a method for applying a continuous protective coating to the surface of individual phosphor particles. The method involves chemical vapor deposition of an aluminum oxide coating on individual particles of a phosphor powder while the particles are suspended in a fluidized bed. The particles in the fluidized bed are exposed to vaporized coating precursor material, preferably aluminum isopropoxide at a temperature above 300° C. The bed is kept at as nearly an isothermal condition as possible. Prior to entering the fluidized bed the aluminum isopropoxide is vaporized and kept at a temperature less than the decomposition temperature of aluminum isopropoxide. Mechanical means are used to help increase the fluidization efficiency of the fluidized bed. After coating the phosphor particles for approximately 30 minutes the vaporized precursor material is shut off from the bed entrance and the oxygen flow rate to the fluidized bed is increased. This carbon reduction step lasts for approximately 15 minutes. The coating step and carbon reduction step can be repeated to increase the thickness of the aluminum oxide coating on the phosphor particles.
Inventors
- 👤 Keith A. Klinedinst
- 👤 Richard A. Gary
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:18
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/02; C09K11/025; B; B01; B01J; B01J2/00; B01J2/006
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
204 words
A method for forming a continuous coating on phosphor particles of a fine phosphor powder comprising: a) vaporizing aluminum isopropoxide into- an inert carrier gas at a temperature below the decomposition temperature of aluminum isopropoxide to form a carrier gas containing vaporized aluminum isopropoxide; b) passing said carrier gas containing aluminum isopropoxide through a mixture of fine phosphor powder and up to 1 weight percent of a fluidizing aid in which the particles are suspended in the carrier gas and to envelop the fluidized particles with vapor of aluminum isopropoxide, said fluidized bed being maintained at a nearly isothermal condition and at a temperature above 300° C.; c) passing an oxidizing gas into said fluidized bed and reacting said oxidizing gas with the vaporized aluminum isopropoxide on the phosphor powder for a period of time sufficient to form a continuous coating of predetermined thickness on the phosphor particles; and d) shutting off the flow of said carrier gas containing vaporized aluminum isopropoxide to said fluidized bed to oxidize any unreacted carbon on the continuous coating of predetermined thickness on the phosphor particles at a temperature of about 300° C. to about 500° C. so that the residual carbon content on the coating is reduced.
Claim 2
Independent Claim
204 words
A method for forming a continuous coating on phosphor particles of a fine phosphor powder comprising: a) vaporizing aluminum isopropoxide into- an inert carrier gas at a temperature below the decomposition temperature of aluminum isopropoxide to form a carrier gas containing vaporized aluminum isopropoxide; b) passing said carrier gas containing aluminum isopropoxide through a mixture of fine phosphor powder and up to 1 weight percent of a fluidizing aid in which the particles are suspended in the carrier gas and to envelop the fluidized particles with vapor of aluminum isopropoxide, said fluidized bed being maintained at a nearly isothermal condition and at a temperature above 300° C.; c) passing an oxidizing gas into said fluidized bed and reacting said oxidizing gas with the vaporized aluminum isopropoxide on the phosphor powder for a period of time sufficient to form a continuous coating of predetermined thickness on the phosphor particles; and d) shutting off the flow of said carrier gas containing vaporized aluminum isopropoxide to said fluidized bed to oxidize any unreacted carbon on the continuous coating of predetermined thickness on the phosphor particles at a temperature of about 300° C. to about 500° C. so that the residual carbon content on the coating is reduced.
Claim 3
Dependent Claim
25 words
The method according to claim 1 wherein said inert carrier gas is selected from the group consisting of nitrogen, argon, helium, neon and mixtures thereof.
Claim 4
Dependent Claim
16 words
The method according to claim 1 wherein said oxidizing gas is diluted with an inert gas.
Claim 5
Dependent Claim
29 words
The method according to claim 1 further comprising: e) annealing the phosphor particles having a continuous coating of predetermined thickness in air at a temperature of approximately 750° C.
Claim 6
Independent Claim
221 words
A method for forming a continuous alumina coating on phosphor particles of a fine phosphor powder comprising: a) vaporizing aluminum isopropoxide into an inert carrier gas at a temperature below the decomposition temperature of the coating precursor material to form a carrier gas containing vaporized aluminum isopropoxide; b) passing said carrier gas containing vaporized aluminum isopropoxide through a mixture of fine phosphor powder in which the particles are suspended in the carrier gas and to envelop the fluidized particles with a vapor of coating precursor material, said fluidized bed being maintained at a nearly isothermal condition and at a temperature above 300° C.; c) passing an oxidizing gas into said fluidized bed and reacting said oxidizing gas with the vaporized aluminum isopropoxide on the phosphor powder for a period of time to form a continuous coating of predetermined thickness on the phosphor particles; d) shutting off the flow of said carrier gas containing vaporized aluminum isopropoxide through the fluidized bed for a period of time sufficient to remove any unreacted hydrocarbons from the continuous coating of predetermined thickness thereby reducing the residual carbon content of the continuous coating, said fluidized bed being maintained at a temperature of about 300° C. to about 500° C.; and e) repeating steps b-d if necessary, in order to increase the thickness of the continuous coating.
Claim 7
Independent Claim
221 words
A method for forming a continuous alumina coating on phosphor particles of a fine phosphor powder comprising: a) vaporizing aluminum isopropoxide into an inert carrier gas at a temperature below the decomposition temperature of the coating precursor material to form a carrier gas containing vaporized aluminum isopropoxide; b) passing said carrier gas containing vaporized aluminum isopropoxide through a mixture of fine phosphor powder in which the particles are suspended in the carrier gas and to envelop the fluidized particles with a vapor of coating precursor material, said fluidized bed being maintained at a nearly isothermal condition and at a temperature above 300° C.; c) passing an oxidizing gas into said fluidized bed and reacting said oxidizing gas with the vaporized aluminum isopropoxide on the phosphor powder for a period of time to form a continuous coating of predetermined thickness on the phosphor particles; d) shutting off the flow of said carrier gas containing vaporized aluminum isopropoxide through the fluidized bed for a period of time sufficient to remove any unreacted hydrocarbons from the continuous coating of predetermined thickness thereby reducing the residual carbon content of the continuous coating, said fluidized bed being maintained at a temperature of about 300° C. to about 500° C.; and e) repeating steps b-d if necessary, in order to increase the thickness of the continuous coating.
Claim 8
Dependent Claim
26 words
The process according to claim 5 further comprising: f) annealing the phosphor powder obtained from step (e) in air at a temperature of approximately 750° C.
Claim 9
Dependent Claim
25 words
The method according to claim 5 wherein the inert carrier gas is selected from the group consisting of nitrogen argon, helium, neon and mixtures thereof.
References Cited (Backward Citations)
US2805965A
Cited
US2972555A
Cited
US3408223A
Cited
US3705055A
Cited
US4585673A
Cited
US4710674A
Cited
US4740643A
Cited
US4803400A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-09-16 | 1995-03-18 | 1995-09-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-09-16 | 1999-03-18 | 1999-09-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-09-16 | 2003-03-18 | 2003-09-17 | $7700.00 | Window Closed / Lapsed |