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US5059269A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of making an article having a hemocompatible surface

Assignee: Becton Dickinson and Co
•
Filing: 1990-03-09
•
Granted: 1991-10-22
•
Expires: 2010-03-09
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Abstract

Abstract An article has a blood-contacting hemocompatible surface layer of a urethane-siloxane copolymer on a thermoplastic polymeric base material. The copolymer has siloxane segments prepared from hydroxyalkyl terminated polysiloxane glycols. The article is prepared by coextrusion of the base material and the copolymer.

Inventors

  • 👤 Can B. Hu
  • 👤 Donald D. Solomon
  • 👤 Stanley C. Wells

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:06
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/61; A; A61; A61L; A61L33/00; A61L33/06; A61L33/068

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 60 words
A method of preparing an article comprising coextruding a thermoplastic polymer and a copolymer having urethane and hydroxyalkyl-terminated siloxane segments whereby there is formed an article having a layer of said copolymer on said polymer, said layer being from about 5 to 50% by weight of said thermoplastic polymer, said copolymer providing said article with a surface which is hemocompatible.
Claim 2
Independent Claim 60 words
A method of preparing an article comprising coextruding a thermoplastic polymer and a copolymer having urethane and hydroxyalkyl-terminated siloxane segments whereby there is formed an article having a layer of said copolymer on said polymer, said layer being from about 5 to 50% by weight of said thermoplastic polymer, said copolymer providing said article with a surface which is hemocompatible.
Claim 3
Dependent Claim 23 words
The method in accordance with claim 1 wherein said polymer is selected from the group consisting of a polyurethane, polyolefin, polyester and polyurethaneurea.
Claim 4
Dependent Claim 22 words
The method in accordance with claim 2 wherein said polyurethane is selected from the group consisting of a polyetherurethane and a polyesterurethane.
Claim 5
Dependent Claim 19 words
The method in accordance with claim 2 wherein said polyurethane has a Shore hardness of about 50A to 75D.
Claim 6
Dependent Claim 21 words
The method in accordance with claim 1 wherein said copolymer has a tensile strength of about 1000-5000 pounds per square inch.
Claim 7
Dependent Claim 14 words
The method in accordance with claim 1 wherein said polysiloxane segment is hydroxybutyl terminated.
Claim 8
Dependent Claim 28 words
The method in accordance with claim 1 further comprising coextruding a tie layer whereby said article has a tie layer between said polymer and said layer of copolymer.
Claim 9
Independent Claim 68 words
A method of preparing an article comprising coextruding a thermoplastic polyurethane of Shore hardness about 50A to 75D and a copolymer having polyurethane segments and hydroxyalkyl-terminated polydimethyl siloxane segments whereby there is formed an article having a layer of said copolymer on said polyurethane, said layer being from about 5 to 50% by weight of said polyurethane, said copolymer providing said article with a surface which is hemocompatible.
Claim 10
Independent Claim 68 words
A method of preparing an article comprising coextruding a thermoplastic polyurethane of Shore hardness about 50A to 75D and a copolymer having polyurethane segments and hydroxyalkyl-terminated polydimethyl siloxane segments whereby there is formed an article having a layer of said copolymer on said polyurethane, said layer being from about 5 to 50% by weight of said polyurethane, said copolymer providing said article with a surface which is hemocompatible.

References Cited (Backward Citations)

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US4057595A Cited
GB2140437A Cited
US4675361A Cited
US4613517A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-10-21 1995-04-22 1995-10-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-10-21 1999-04-22 1999-10-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-10-21 2003-04-22 2003-10-22 $7700.00 Window Closed / Lapsed

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