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US5068259A Expired / Lapsed US ⏱️ 0.0 years remaining

Resin composition curbable with an active energy ray containing epoxy resin and monomer with ethylenically unsaturated bond

Assignee: Canon Inc
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Filing: 1988-09-15
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Granted: 1991-11-26
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Expires: 2008-09-15
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Abstract

Abstract An improved active energy ray-curing resin composition comprising (i) a graft copolymerized polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less: (ii) a linear polymer having a number average molecular weight of 5,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60° C. or more: (iii) an epoxy resin containing at least one compound having one or more epoxy groups in one molecule, (iv) a monomer having an ethylenically unsaturated bond and (v) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray. The resin composition can be desirably cured with an active energy ray such as ultraviolet ray or electron beam and it is capable of being laminated in a desired pattern on a copper-coated laminate for use as a printed board or on a plate of metal, glass, ceramics or plastic.

Inventors

  • 👤 Hiromichi Noguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:50
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/039; C; C08; C08F; C08F283/00; C08F283/10; C08F285/00; C08G; C08G59/00; C08G59/18; C08G59/68; C08L; C08L51/00; C08L51/003; C08L63/00; G03F7/027; G03F7/032; G03F7/033; G03F7/038; G03F7/0388; H; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/285; H05K3/287

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 351 words
A resin composition curable with an active energy ray comprising: (i) a graft copolymerized polymer having a number molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less which comprises a trunk chain composed mainly of structural units derived from at least one monomer selected from the group consisting of alkyl methacrylates, acrylonitrile and styrene and has graft chains having structural units derived from at least one monomer selected from the group consisting of the monomers represented by the following formula I and other monomers presented by the formula II: ##STR8## (wherein R 1 is hydrogen or an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms, R 2 is hydrogen or an alkyl or acyl group having 1 to 4 carbon atoms which may have hydroxy group, R 3 is an alkyl group having 2 to 6 carbon atoms, a halogen-substituted alkyl group having 2 to 6 carbon atoms, an alkylether group represented by the formula: --CH.sub.2n O--CH.sub.2m (wherein 2≦m+n≦6, n≠0 and m≠0), or a phenylalkyl group represented by the formula: ##STR9## (wherein 2≦m+n≦4, or the case where n=0 or m=0 is contained), added to said trunk chain; (ii) a linear polymer having a number average molecular weight of 50,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60° C. or more which comprises structural units derived from at least one monomer selected from the group consisting of methyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t-butyl methacrylate, benzyl methacrylate, acrylonitile, isobornyl methacrylate, isobornyl acrylate, tricyclodecaneacrylate, tricyclodecane methacrylate, tricyclodecaneoxyethyl methacrylate, styrene, dimethylaminoethyl methacrylate and cyclohexyl methacrylate and other structural units derived from at least one monomer in amounts from 5 to 30 mole percent selected from the group consisting of the monomers represented by said formula (I) and the monomers represented by said formula (II); (iii) an epoxy resin containing at least one compound having one or more epoxy groups in one molecule; (iv) a monomer having (v) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
Claim 2
Dependent Claim 351 words
A resin composition curable with an active energy ray comprising: (i) a graft copolymerized polymer having a number molecular weight of 5,000 or more and a weight average molecular weight of 50,000 or less which comprises a trunk chain composed mainly of structural units derived from at least one monomer selected from the group consisting of alkyl methacrylates, acrylonitrile and styrene and has graft chains having structural units derived from at least one monomer selected from the group consisting of the monomers represented by the following formula I and other monomers presented by the formula II: ##STR8## (wherein R 1 is hydrogen or an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms, R 2 is hydrogen or an alkyl or acyl group having 1 to 4 carbon atoms which may have hydroxy group, R 3 is an alkyl group having 2 to 6 carbon atoms, a halogen-substituted alkyl group having 2 to 6 carbon atoms, an alkylether group represented by the formula: --CH.sub.2n O--CH.sub.2m (wherein 2≦m+n≦6, n≠0 and m≠0), or a phenylalkyl group represented by the formula: ##STR9## (wherein 2≦m+n≦4, or the case where n=0 or m=0 is contained), added to said trunk chain; (ii) a linear polymer having a number average molecular weight of 50,000 or more and a weight average molecular weight of 350,000 or less and having a glass transition temperature of 60° C. or more which comprises structural units derived from at least one monomer selected from the group consisting of methyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t-butyl methacrylate, benzyl methacrylate, acrylonitile, isobornyl methacrylate, isobornyl acrylate, tricyclodecaneacrylate, tricyclodecane methacrylate, tricyclodecaneoxyethyl methacrylate, styrene, dimethylaminoethyl methacrylate and cyclohexyl methacrylate and other structural units derived from at least one monomer in amounts from 5 to 30 mole percent selected from the group consisting of the monomers represented by said formula (I) and the monomers represented by said formula (II); (iii) an epoxy resin containing at least one compound having one or more epoxy groups in one molecule; (iv) a monomer having (v) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
Claim 3
Dependent Claim 39 words
The resin composition according to claim 1, wherein the weight ratio of said graft copolymerized polymer (i) to said linear polymer (ii) to said linear polymer (ii) is such that (i):(ii) is in the range from 80:20 to 50:50.
Claim 4
Dependent Claim 52 words
The resin composition according to claim 1 or claim 2, wherein the weight ratio of the sum of said graft copolymerized polymer (i) and said linear polymer (ii) to the sum of said epoxy resin (iii) and said monomer (iv) is such that [(i)+(ii)]:(iii)+(iv)] is in the range from 100:50 to 100:200.
Claim 5
Dependent Claim 32 words
The resin composition according to claim 3, wherein the weight ratio of said epoxy resin (iii) to said monomer (iv) is such that (iii):(iv) is in the range from 25:75 to 75:25.
Claim 6
Dependent Claim 49 words
The resin composition according to claim 1, wherein the weight ratio of the sum of said graft copolymerized polymer (i), said linear polymer (ii), said epoxy resin (iii) and said monomer (iv) to said polymerization initiator (v) is such that [(i)+(ii)+(iii)+(iv)]:(v) is in the range from 100:1 to 100:10.
Claim 7
Dependent Claim 40 words
The resin composition according to claim 1, wherein said polymerization initiator (v) comprises an aromatic halonium salt compound or an aromatic onium salt compound having photosensitivity containing an element belonging to group VIa or group Va, of the periodic table.

References Cited (Backward Citations)

US4688056A Cited
US4688053A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-11-25 1995-05-27 1995-11-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-11-25 1999-05-27 1999-11-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-11-25 2003-05-27 2003-11-26 $7700.00 Window Closed / Lapsed

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