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US5073195A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous silane water repellent compositions

Assignee: Dow Silicones Corp
•
Filing: 1991-02-04
•
Granted: 1991-12-17
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Expires: 2011-02-04
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Abstract

Abstract A water repellent composition for treating surfaces which is an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane. The alkyltrialkoxysilane is either an alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon or a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon. A treatmetn method for wood and masonry is disclosed.

Inventors

  • 👤 Robert L. Cuthbert
  • 👤 Edwin P. Plueddemann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 07:13
CPC Classifications
C; C04; C04B; C04B41/00; C04B41/60; C04B41/61; C04B41/62; C04B41/64; C04B41/45; C04B41/46; C04B41/49; C04B41/4905; C04B41/4922; C04B41/4944; C09; C09D; C09D4/00; Y; Y10; Y10T; Y10T428/00; Y10T428/12; Y10T428/12014; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 76 words
A composition comprising an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solutions in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 2
Dependent Claim 76 words
A composition comprising an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solutions in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 3
Dependent Claim 40 words
The composition of claim 1 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about two to about forty percent by weight based on the weight of the aqueous solution.
Claim 4
Dependent Claim 37 words
The composition of claim 2 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about 2.5-20.0 percent by weight based on the weight of the aqueous solution.
Claim 5
Dependent Claim 29 words
The composition of claim 1 wherein the silane coupling agent is an aminofunctional silane coupling agent selected from the group consisting of N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-(2-aminoethyl)-3-aminopropyltris(2-ethyl-hexoxy)-silane, 3-aminopropyltrimethoxysilane, trimethoxysilylpropyldiethylenetriamine, aminopropyltriethoxysilane, and bis(2-hydroxyethyl)-3-aminopropyltrimethoxysilane.
Claim 6
Dependent Claim 12 words
The composition of claim 4 wherein the silane coupling agent is N-(2-aminoethyl)-3-aminopropyltrimethoxysilane.
Claim 7
Dependent Claim 18 words
The composition of claim 1 wherein the alkyltrialkoxysilane is selected from the group consisting of methyltrimethoxysilane and isobutyltrimethoxysilane.
Claim 8
Dependent Claim 32 words
The composition of claim 1 wherein the silane coupling agent is a quaternary ammonium functional silane coupling agent selected from the group consisting of 2-methacryloxyethyldimethyl[3-trimethoxysilylpropyl] ammonium chloride and 2-hydroxyethyldimethyl [3-trimethoxysilylpropyl] ammonium chloride.
Claim 9
Independent Claim 95 words
A method of treating a surface in order to render the surface water repellent comprising applying to the surface to be treated an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solution in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 10
Independent Claim 95 words
A method of treating a surface in order to render the surface water repellent comprising applying to the surface to be treated an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solution in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 11
Dependent Claim 40 words
The method of claim 8 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about two to about forty percent by weight based on the weight of the aqueous solution.
Claim 12
Dependent Claim 37 words
The method of claim 9 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about 2.5-20.0 percent by weight base on the weight of the aqueous solution.
Claim 13
Dependent Claim 28 words
The method of claim 8 wherein the silane coupling agent is an aminofunctional silane coupling agent selected from the group consisting of N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, 3-aminopropyltrimethoxysilane, trimethoxysilylpropyldiethylenetriamine, aminopropyltriethoxysilane, and bis(2-hydroxyethyl)-3-aminopropyltrimethoxysilane.
Claim 14
Dependent Claim 13 words
The method of claim 11 where in the silane coupling agent is N-(2-aminoethyl)-3-aminopropyltrimethoxysilane.
Claim 15
Dependent Claim 18 words
The method of claim 8 wherein the alkyltrialkoxysilane is selected from the group consisting of methyltrimethoxysilane and isobutyltrimethoxysilane.
Claim 16
Dependent Claim 32 words
The method of claim 8 wherein the silane coupling agent is a quaternary ammonium functional silane coupling agent selected from the group consisting of 2-methacryloxyethyldimethyl [3-trimethoxysilylpropyl] ammonium chloride and 2-hydroxyethyldimethyl[3-trimethoxysilylpropyl] ammonium chloride.
Claim 17
Dependent Claim 42 words
The composition of claim 1 in which the alkyltrialkoxysilane is selected from the group consisting of methyltrimethoxysilane and isobutyltrimethoxysilane, and the silane coupling agent is selected from the group consisting of aminofunctional silane coupling agents and quaternary ammonium functional silane coupling agents.
Claim 18
Dependent Claim 42 words
The method of claim 8 in which the alkyltrialkoxysilane is selected from the group consisting of methyltrimethoxysilane and isobutyltrimethoxysilane, and the silane coupling agent is selected from the group consisting of aminofunctional silane coupling agents and quaternary ammonium functional silane coupling agents.
Claim 19
Dependent Claim 31 words
The composition of claim 1 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution in the mole ratio of between about 1.5:1.0 to about 2.0:1.0.
Claim 20
Dependent Claim 31 words
The method of claim 8 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution in the mole ratio of between about 1.5:1.0 to about 2.0:1.0.
Claim 21
Independent Claim 97 words
A method of treating a cellulosic surface in order to render the surface water repellent comprising applying to the cellulosic surface to be treated an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solution in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 22
Independent Claim 97 words
A method of treating a cellulosic surface in order to render the surface water repellent comprising applying to the cellulosic surface to be treated an aqueous solution of a water soluble silane coupling agent and an alkyltrialkoxysilane, the alkyltrialkoxysilane being selected from the group consisting of alkyltrialkoxysilanes with C 1 to C 6 alkyl groups on silicon and a blend of alkyltrialkoxysilanes each with C 1 to C 6 alkyl groups on silicon, the alkyltrialkoxysilane and the silane coupling agent being present in the aqueous solution in the mole ratio of between about 0.5:1.0 to about 3.0:1.0.
Claim 23
Dependent Claim 40 words
The method of claim 19 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about two to about forty percent by weight based on the weight of the aqueous solution.
Claim 24
Dependent Claim 37 words
The method of claim 20 in which the alkyltrialkoxysilane and the silane coupling agent are present in the aqueous solution at a level of about 2.5-20.0 percent by weight base on the weight of the aqueous solution.
Claim 25
Dependent Claim 28 words
The method of claim 19 wherein the silane coupling agent is an aminofunctional silane coupling agent selected from the group consisting of N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, 3-aminopropyltrimethoxysilane, trimethoxysilylpropyldiethylenetriamine, aminopropyltriethoxysilane, and bis(2-hydroxyethyl)-3-aminopropyltrimethoxysilane.
Claim 26
Dependent Claim 13 words
The method of claim 22 where in the silane coupling agent is N-(2-aminoethyl)-3-aminopropyltrimethoxysilane.
Claim 27
Dependent Claim 18 words
The method of claim 19 wherein the alkyltrialkoxysilane is selected from the group consisting of methyltrimethoxysilane and isobutyltrimethoxysilane.
Claim 28
Dependent Claim 32 words
The method of claim 19 wherein the silane coupling agent is a quaternary ammonium functional silane coupling agent selected from the group consisting of 2-methacryloxyethyldimethyl [3-trimethoxysilylpropyl] ammonium chloride and 2-hydroxyethyldimethyl[3-trimethoxysilylpropyl] ammonium chloride.

References Cited (Backward Citations)

US4877654A Cited

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