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US5073442A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of enhancing the soil- and stain-resistance characteristics of polyamide and wool fabrics, the fabrics so treated, and treating compositions

Assignee: Trichromatic Carpet Inc
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Filing: 1989-11-08
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Granted: 1991-12-17
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Expires: 2009-11-08
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Abstract

Abstract A method for enhancing the soil- and/or stain-resistant characteristics of polyamide and wool fabrics is provided. A variety of combinations of sulfonated resin, sulfonated phenolic compounds, compounds of sulfonated phenolics and aldehydes, fluorochemicals, modified wax emulsions, acrylics and organic acids of low molecular weight provide enhanced soil release and anti-stain properties.

Inventors

  • 👤 Barry R. Knowlton
  • 👤 Yassin Elgarhy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:27
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/004; C11D3/00; C11D3/16; C11D3/24; C11D3/245; C11D3/37; C11D3/3703; C11D3/3746; C11D3/3757; D; D06; D06M; D06M13/00; D06M13/02; D06M15/00; D06M15/19; D06M15/21; D06M15/227; D06M15/244; D06M15/256; D06M15/263; D06M15/277; D06M15/37; D06M15/39; D06M15/41; D06M15/412; D06M2101/00; D06M2101/16; D06M2101/30; D06M2101/34; Y; Y10; Y10T; Y10T428/00; Y10T428/23907; Y10T428/23986; Y10T442/00; Y10T442/20; Y10T442/2279; Y10T442/2287

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 76 words
The method of enhancing soil- and stain-resisting properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid; and at least one material selected from the group consisting of a wax emulsion and a fluorochemical; and a polymer selected from the consisting of acrylic polymer and copolymer.
Claim 2
Independent Claim 76 words
The method of enhancing soil- and stain-resisting properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid; and at least one material selected from the group consisting of a wax emulsion and a fluorochemical; and a polymer selected from the consisting of acrylic polymer and copolymer.
Claim 3
Dependent Claim 19 words
The method according to claim 1, wherein the solution is an aqueous solution having a pH not exceeding 10.
Claim 4
Dependent Claim 35 words
The method according to claim 1 where the solution is an aqueous solution having a pH below 7 applied to the fabric by spraying at room temperature and in the absence of any heat fixation.
Claim 5
Dependent Claim 56 words
The method according to claim 1 wherein the condensation product is a polymer of benzene sulfonic acid and formaldehyde, the fluorochemical is a nonionic or anionic water based fluorochemical, the acrylic polymer is polymerized 2-methyl propenoic acid ethyl ester, and wherein the solution contains citric acid in an amount sufficient to provide a pH below 7.
Claim 6
Dependent Claim 24 words
The method according to claim 1 where the fluorochemical is present in the solution in an amount of between 0.1 percent and 20 percent.
Claim 7
Dependent Claim 13 words
The method according to claim 5 where the solution contains 0.1 percent fluorochemical.
Claim 8
Dependent Claim 48 words
An aqueous solution for enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising in admixture a condensation product of an aromatic sulfonic acid and formaldehyde together with wax emulsion, a nonionic water based fluorochemical, and an acrylic polymer, said admixture having a pH below 10.
Claim 9
Dependent Claim 48 words
An aqueous solution for enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising in admixture a condensation product of an aromatic sulfonic acid and formaldehyde together with wax emulsion, a nonionic water based fluorochemical, and an acrylic polymer, said admixture having a pH below 10.
Claim 10
Dependent Claim 13 words
The aqueous solution according to claim 7 wherein the pH is below 7.
Claim 11
Dependent Claim 67 words
A fibrous material selected from the group consisting of polyamide and wool fibrous materials having applied thereto an aqueous solution containing a polymer of a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone and benzene sulfonic acid with an aldehyde; a fluorochemical and an acrylic polymer together with citric acid in an amount sufficient to provide a pH below 7.
Claim 12
Dependent Claim 67 words
A fibrous material selected from the group consisting of polyamide and wool fibrous materials having applied thereto an aqueous solution containing a polymer of a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone and benzene sulfonic acid with an aldehyde; a fluorochemical and an acrylic polymer together with citric acid in an amount sufficient to provide a pH below 7.
Claim 13
Independent Claim 62 words
The method of enhancing the soil-and stain-resistance of polyamide fabric by immersing or totally wetting out said fabric with an aqueous solution containing a polymer of a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone and benzene sulfonic acid with an aldehyde; a fluorochemical and an acrylic polymer; said solution having a pH below 7.
Claim 14
Independent Claim 62 words
The method of enhancing the soil-and stain-resistance of polyamide fabric by immersing or totally wetting out said fabric with an aqueous solution containing a polymer of a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone and benzene sulfonic acid with an aldehyde; a fluorochemical and an acrylic polymer; said solution having a pH below 7.
Claim 15
Dependent Claim 19 words
The method according to claim 10 where the fabric is subsequently sprayed with a fluorochemical water and oil repellent.
Claim 16
Dependent Claim 31 words
The method according to claim 10 where the fabric is subsequently sprayed with a fluorochemical water and oil repellent which also contains an acrylic polymer or copolymer and a phenolic resin.
Claim 17
Independent Claim 76 words
The method of enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a phenolic compound selected from the group consisting of bis(hydroxy phenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid; and at least one material selected from the group consisting of a wax emulsion and an acrylic polymer; said aqueous solution having a pH below 10.
Claim 18
Independent Claim 76 words
The method of enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a phenolic compound selected from the group consisting of bis(hydroxy phenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid; and at least one material selected from the group consisting of a wax emulsion and an acrylic polymer; said aqueous solution having a pH below 10.
Claim 19
Independent Claim 61 words
The method of enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid, and a wax emulsion; said aqueous solution having a pH below 10.
Claim 20
Independent Claim 61 words
The method of enhancing the soil- and stain-resistant properties of polyamide and wool fabrics comprising applying to the fabric an aqueous solution containing the condensation product of formaldehyde with a phenolic compound selected from the group consisting of bis(hydroxyphenyl) sulfone, phenylsulfonic acid, dihydroxy diphenyl sulfone, and benzene sulfonic acid, and a wax emulsion; said aqueous solution having a pH below 10.

References Cited (Backward Citations)

US3949124A Cited
US4592940A Cited
US4501591A Cited
US4865885A Cited
US4877538A Cited
US4857392A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-12-16 1995-06-17 1995-12-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-12-16 1999-06-17 1999-12-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-12-16 2003-06-17 2003-12-17 $7700.00 Window Closed / Lapsed

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