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US5082578A Expired / Lapsed US ⏱️ 0.0 years remaining

Fabric care compositions containing a polymeric fluorescent whitening agent

Assignee: Lever Brothers Co
•
Filing: 1990-12-11
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Granted: 1992-01-21
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Expires: 2010-12-11
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Abstract

Abstract The present invention pertains to fabric detergent and fabric care compositions comprising a surfactant and a polymeric whitening agent which contains both a fluorescent portion and a hydrophilic portion. The use of these copolymers allows certain substrates, such as polyester or soiled cottons, to be brightened more readily then previously known.

Inventors

  • 👤 Matthew E. Langer
  • 👤 Ferial Khorshahi
  • 👤 Michael P. Aronson
  • 👤 John F. Hessel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 22:33
CPC Classifications
C; C11; C11D; C11D9/00; C11D9/04; C11D9/44; C11D9/448; C11D3/00; C11D3/0005; C11D3/0036; C11D3/16; C11D3/37; C11D3/3703; C11D3/3715; C11D3/40; C11D3/42; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24273

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 233 words
A fabric care composition comprising: (a) from about 1% to about 75% by weight of a surfactant selected from the group consisting of soap, nonionic surfactant, anionic surfactant, ampholytic surfactant, zwitterionic surfactant, cationic surfactant and mixtures thereof; and (b) a copolymer whitening agent having the formula ##STR6## wherein: R is a difunctional aryl group or a difunctional straight or branched alkyl chain having 4 to 16 carbons; R 1 is hydrogen, an aliphatic group having 1 to 20 carbons, an aryl, an alkaryl, a secondary amine, an alkali metal sulfonate, an alkali metal carboxylate, an alkyl ether or a halogen atom; R 2 is a straight or branch chain alkoxy group having 1 to 16 carbons, an aryloxy or a substituted aryloxy group; R 3 is a straight or branch chain alkyl group having 1 to 16 carbons; and R 4 is a difunctional fluorescent moiety; x is selected such that the difunctional hydrophobic group is present at 0-49 mol% of the composition mixture when the copolymer is polymerized; y is selected such that the R 2 group is present at 0-45 mol% of the mixture; z is selected such that the (OR 3 ) n group is present at 5-45 mol% of the mixture wherein n is an integer between 2 and 200; and w is selected such that the R 4 group is present at 1-50 mol% of the reaction mixture.
Claim 2
Dependent Claim 233 words
A fabric care composition comprising: (a) from about 1% to about 75% by weight of a surfactant selected from the group consisting of soap, nonionic surfactant, anionic surfactant, ampholytic surfactant, zwitterionic surfactant, cationic surfactant and mixtures thereof; and (b) a copolymer whitening agent having the formula ##STR6## wherein: R is a difunctional aryl group or a difunctional straight or branched alkyl chain having 4 to 16 carbons; R 1 is hydrogen, an aliphatic group having 1 to 20 carbons, an aryl, an alkaryl, a secondary amine, an alkali metal sulfonate, an alkali metal carboxylate, an alkyl ether or a halogen atom; R 2 is a straight or branch chain alkoxy group having 1 to 16 carbons, an aryloxy or a substituted aryloxy group; R 3 is a straight or branch chain alkyl group having 1 to 16 carbons; and R 4 is a difunctional fluorescent moiety; x is selected such that the difunctional hydrophobic group is present at 0-49 mol% of the composition mixture when the copolymer is polymerized; y is selected such that the R 2 group is present at 0-45 mol% of the mixture; z is selected such that the (OR 3 ) n group is present at 5-45 mol% of the mixture wherein n is an integer between 2 and 200; and w is selected such that the R 4 group is present at 1-50 mol% of the reaction mixture.
Claim 3
Dependent Claim 13 words
A composition according to claim 1, wherein R is difunctional benzene or napthalene.
Claim 4
Dependent Claim 23 words
A composition according to claim 1, wherein R 1 is hydrogen or a straight chain alkyl group having 1 to 12 carbon atoms.
Claim 5
Dependent Claim 18 words
A composition according to claim 1, wherein R 2 is an alkoxy group having 1 to 4 carbons.
Claim 6
Dependent Claim 14 words
A composition according to claim 1 wherein R is ##STR7## and R 1 ═H,
Claim 7
Dependent Claim 15 words
A composition according to claim 1 wherein R 2 is --OCH 2 CH 2 --.
Claim 8
Dependent Claim 15 words
A composition according to claim 1 wherein R 3 is --CH 2 CH 2 --.
Claim 9
Dependent Claim 11 words
A composition according to claim 1 wherein R 4 is ##STR8##
Claim 10
Dependent Claim 11 words
A composition according to claim 1 wherein R 4 is ##STR9##
Claim 11
Dependent Claim 29 words
A composition according to claim 1 wherein ##STR10## and R 1 is H; R 2 ═--OCH 2 CH 2 --; R 3 ═--CH 2 CH 2 --; and ##STR11##
Claim 12
Dependent Claim 29 words
A composition according to claim 1 wherein ##STR12## and R 1 is H; R 2 ═--OCH 2 CH 2 --; R 3 ═--CH 2 CH 2 --; and ##STR13##
Claim 13
Dependent Claim 27 words
A composition according to claim 1 containing a polymer prepared by polymerizing a mixture of dimethyl terephthalate, ethylene glycol, polyethylene glycol of MW 200-3000 and 4,4'-bis(carbomethoxy stilbene).
Claim 14
Dependent Claim 28 words
A composition according to claim 1 containing a polymer prepared by polymerizing a mixture of dimethyl terephthalate, ethylene glycol, polyethylene glycol of MW 200-3000 and 1,4-bis (2(-4'-carbomethoxystyrenyl)) benzene.
Claim 15
Dependent Claim 121 words
A composition according to claim 1, wherein the composition is a heavy duty liquid detergent comprising: from 1-75% by weight of a detergent-active compound, wherein the detergent active compound includes 0 to 40% of an anionic surfactant selected from the group consisting of alkyl benzene sulfonates, alkyl sulfates, and alkyl ethoxy sulfates in combination with 0 to 40% of a nonionic surfactant selected from the group consisting of alcohol alkoxylates, alkyl phenol alkoxylates, alkyl polyglucosides, and alkyl glycerol ethers; and from 0 to 30% of a detergent builder selected from the group consisting of alkali metal salts of citric acid, copolymers of acrylic and maleic acid, oxydisuccinate, tartrate monosuccinate/tartrate disuccinate, C8 to C18 carboxylic acids, zeolites, condensed phosphates, and combinations thereof.
Claim 16
Dependent Claim 58 words
A composition according to claim 14 comprising: ______________________________________ C.sub.11.5 (Average Alkyl benzene Sulfonate 25 to 30% C.sub.12 -C.sub.15 Alcohol Ethoxylate (9 E.O.) 10 to 14% Sodium Citrate 2H.sub.2 O 6 to 15% Sodium Borate 10H.sub.2 O 3 to 8% Glycerol 3 to 8% Proteolytic Enzyme 0.1 to 2% Detergent Adjuncts 0.1 to 10% Water balance to 100% ______________________________________
Claim 17
Dependent Claim 13 words
A composition according to claim 1, wherein the composition is a powdered detergent.
Claim 18
Dependent Claim 137 words
A composition according to claim 16 comprising: a) from 0 to about 40% anionic surfactant selected from the group consisting of alkali metal or ammonium salts of alkyl benzene sulfonates, alkyl sulfates, alkyl ether sulfates; b) from 0 to about 40% of a nonionic surfactant selected from the group consisting of alkyl alkoxylates, alkylphenol alkoxylates, alkyl polyglucosides, and alkyl glycerol ethers; c) from 5 to about 70% of a detergent builder selected from the group consisting of sodium tripolyphosphate, sodium aluminosilicates, sodium C 8 -C 18 alkyl carboxylates, poly(acrylic) acid and copolymers of acrylic and maleic acid, alkyl ether carboxylates, citric acid and combinations thereof; d) from 2 to about 40% of an alkalinity buffer selected from the group consisting of sodium silicate, sodium carbonate, and organic amines; and e) from 0 to about 40% sodium sulfate.
Claim 19
Dependent Claim 14 words
A composition according to claim 1, wherein the composition is a fabric softener composition.
Claim 20
Dependent Claim 97 words
A composition according to claim 1 comprising from 2 to about 40% of a mixture comprising: a) from 0 to about 95% of a cationic ammonium salt selected from the group consisting of alkyl or alkaryl quaternary ammonium salts, alkylpyridinium salts, and substituted immidazolinium salts; b) from 0 to about 95% of primary, secondary or tertiary amines; c) from 0 to about 95% of the condensation product of a C 8 to C 18 alkyl carboxylic acid and an alkylpolyamine; and d) from 0 to about 40% of a polysiloxane or alkyl, alkoxy, or alkylamine modified polysiloxane.
Claim 21
Dependent Claim 14 words
A composition according to claim 1, wherein the composition is a fabric dryer sheet.
Claim 22
Dependent Claim 82 words
A composition according to claim 20 comprising a) from 5 to 40% of a fabric softening or antistatic agent selected from the group consisting of cationic alkyl or alkaryl ammonium salts, alkyl pyridium salts, alkyl amines, clays and poly siloxanes; b) from 2 to about 90% of a dispersing agent selected from group consisting of urea, ammonium carbonate, ethoxylated alkonols, polyethylene glycols, and block copolymers of a polyethylene glycol and polypropylene glycol; and c) a backing strip or sheet carrying said composition.
Claim 23
Dependent Claim 14 words
A composition according to claim 1 comprising one or more additional fluorescent whitening agents.

References Cited (Backward Citations)

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US4702857A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-01-20 1995-07-22 1996-01-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-01-20 1999-07-22 2000-01-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-01-20 2003-07-22 2004-01-21 $7700.00 Window Closed / Lapsed

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