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US5135604A Expired / Lapsed US ⏱️ 0.0 years remaining

Analysis of radiofrequency discharges in plasma

Assignee: Louisiana State University
•
Filing: 1990-12-04
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Granted: 1992-08-04
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Expires: 2010-12-04
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Abstract

Abstract Separation of laser optogalvanic signals in plasma into two components: (1) an ionization rate change component, and (2) a photoacoustic mediated component. This separation of components may be performed even when the two components overlap in time, by measuring time-resolved laser optogalvanic signals in an rf discharge plasma as the rf frequency is varied near the electrical resonance peak of the plasma and associated driving/detecting circuits. A novel spectrometer may be constructed to make these measurements. Such a spectrometer would be useful in better understanding and controlling such processes as plasma etching and plasma deposition.

Inventors

  • 👤 Devendra Kumar
  • 👤 Sean P. McGlynn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:30
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/62; G01N27/626; G01N27/628

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 189 words
A method, in a plasma coupled by a driving circuit to a radiofrequency discharge source, for extracting from a laser optogalvanic ("LOG") signal its photoacoustic mediated ("PAM") component, comprising the steps of: (a) irradiating the plasma with a pulsed laser, with the radiofrequency discharge source at a first frequency equal to or close to the resonant frequency of the plasma and driving circuit; (b) measuring a first LOG signal as a function of time following at least one pulse of said laser irradiating, with the radiofrequency discharge source at said first frequency; (c) irradiating the plasma with a pulsed laser, with the radiofrequency discharge source at a second frequency equal to or close to the resonant frequency of the plasma and driving circuit; wherein said first and second frequencies are not equal; (d) measuring a second LOG signal as a function of time following at least one pulse of said laser irradiating, with the radiofrequency discharge source at said second frequency; and (e) extracting the PAM component as that part of said LOG signals which does not vary, or which varies slightly, between said first and second LOG signals.
Claim 2
Independent Claim 189 words
A method, in a plasma coupled by a driving circuit to a radiofrequency discharge source, for extracting from a laser optogalvanic ("LOG") signal its photoacoustic mediated ("PAM") component, comprising the steps of: (a) irradiating the plasma with a pulsed laser, with the radiofrequency discharge source at a first frequency equal to or close to the resonant frequency of the plasma and driving circuit; (b) measuring a first LOG signal as a function of time following at least one pulse of said laser irradiating, with the radiofrequency discharge source at said first frequency; (c) irradiating the plasma with a pulsed laser, with the radiofrequency discharge source at a second frequency equal to or close to the resonant frequency of the plasma and driving circuit; wherein said first and second frequencies are not equal; (d) measuring a second LOG signal as a function of time following at least one pulse of said laser irradiating, with the radiofrequency discharge source at said second frequency; and (e) extracting the PAM component as that part of said LOG signals which does not vary, or which varies slightly, between said first and second LOG signals.
Claim 3
Dependent Claim 46 words
A method as recited in claim 1 for additionally extracting from the LOG signal its ionization rate change ("IRC") component, additionally comprising the step of extracting the IRC component as that part of said LOG signals which varies significantly between said first and second LOG signals.
Claim 4
Dependent Claim 25 words
A method as recited in claim 2, wherein said first frequency is substantially equal to the resonant frequency peak of the plasma and driving circuit.
Claim 5
Dependent Claim 54 words
A method as recited in claim 2, additionally comprising the step of estimating the magnitude of any change in the equilibrium ionization rate of the plasma by comparing: (a) the magnitude of said IRC component to (b) a calibration of the magnitude of the IRC component with known or measured changes in ionization rates.
Claim 6
Dependent Claim 20 words
A method as recited in claim 2, wherein said method is carried out in an apparatus suitable for plasma etching.
Claim 7
Dependent Claim 20 words
A method as recited in claim 2, wherein said method is carried out in an apparatus suitable for plasma deposition.
Claim 8
Dependent Claim 109 words
A spectrometer comprising: (a) means for generating a radiofrequency discharge plasma at a plurality of frequencies equal to or near the resonance frequency of the plasma and radiofrequency discharge; (b) a laser having a pulsed output which can be absorbed by the plasma; (c) means for making time-resolved measurements of the optogalvanic signal from the plasma following absorption of an output pulse from the laser; and (d) means for determining that part of said optogalvanic signal which varies relatively slowly as the frequency of said radiofrequency discharge is varied near the resonance frequency, said slowly varying part of said optogalvanic signal being a measure of the photoacoustic mediated effect.
Claim 9
Dependent Claim 109 words
A spectrometer comprising: (a) means for generating a radiofrequency discharge plasma at a plurality of frequencies equal to or near the resonance frequency of the plasma and radiofrequency discharge; (b) a laser having a pulsed output which can be absorbed by the plasma; (c) means for making time-resolved measurements of the optogalvanic signal from the plasma following absorption of an output pulse from the laser; and (d) means for determining that part of said optogalvanic signal which varies relatively slowly as the frequency of said radiofrequency discharge is varied near the resonance frequency, said slowly varying part of said optogalvanic signal being a measure of the photoacoustic mediated effect.
Claim 10
Dependent Claim 52 words
A spectrometer as recited in claim 7, additionally comprising means for determining that part of said optogalvanic signal which varies relatively rapidly as the frequency of said radiofrequency discharge is varied near the resonance frequency, said rapidly varying part of said optogalvanic signal being a measure of the ionization rate change effect.
Claim 11
Dependent Claim 16 words
An apparatus comprising: (a) plasma etching means, and (b) a spectrometer as recited in claim 8.
Claim 12
Dependent Claim 16 words
An apparatus comprising: (a) plasma deposition means, and (b) a spectrometer as recited in claim 8.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-08-04 1996-02-03 1996-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-08-04 2000-02-03 2000-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-08-04 2004-02-03 2004-08-04 $7700.00 Window Closed / Lapsed

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