Composition for plastic lenses

Claim 2

A composition for plastic lenses which comprises (A) 10 to 60 parts by weight of a polybutylene glycol di(meth)acrylate represented by the general formula (I): ##STR8## where R 1 is hydrogen or methyl, and n is an integer of 5 to 16; (B) 20 to 80 parts by weight of at least one compound selected from the group consisting of a urethane poly(meth)acrylate having two or more (meth)acryloyloxy groups in the molecule, and an epoxy poly(meth)acrylate having two or more (meth)acryloyloxy groups in the molecule; (C) 5 to 60 parts by weight of at least one mono(meth)acrylate selected from the group consisting of compounds represented by the general formulae (II), (III), (IV) and (V): ##STR9## where R 2 is hydrogen or methyl, R 3 is an alicyclic hydrocarbon radical having 5 to 16 carbon atoms, R 4 is hydrogen or methyl, R 5 is --CH 2 --, --CH 2 CH 2 --O--, ##STR10## or --CH 2 CH 2 CH 2 CH 2 --O--, X is chlorine, bromine or iodine, m is an integer of 0 to 3, p is an integer of 0 to 5, q is an integer of 0 to 4, and r is an integer of 0 to 3; and (D) 0 to 60 parts by weight of a compound having at least one polymerizable double bond in the molecule, with the total amount of components (A), (B), (C) and (D) being 100 parts by weight.

Claim 3

A composition for plastic lenses as claimed in claim 1 wherein the polybutylene glycol di(meth)acrylate is at least one member selected from the group consisting of heptabutylene glycol di(meth)acrylate, octabutylene glycol di(meth)acrylate, nonabutylene glycol di(meth)acrylate, decabutylene glycol di(meth)acrylate, undecabutylene glycol di(meth)acrylate and dodecabutylene glycol di(meth)acrylate.

Claim 4

A composition for plastic lenses as claimed in claim 1 wherein the urethane poly(meth)acrylate having two or more (meth)acryloyloxy groups in the molecule is an adduct of 2-hydroxyethyl (meth)acrylate or 2-hydroxypropyl (meth)acrylate with isophorone diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, dicyclohexylmethane diisocyanate, xylylene diisocyanate, 1,3-bis(α, α-dimethylisocyanatomethyl)benzene, tolylene diisocyanate or naphthalene diisocyanate.

Claim 5

A composition for plastic lenses as claimed in claim 1 wherein the epoxy poly(meth)acrylate having two or more (meth)acryloyloxy groups in the molecule is a reaction product of acrylic acid or methacrylic acid with 1,6-hexanediol diglycidyl ether, diethylene glycol diglycidyl ether, trimethylolpropane diglycidyl ether, trimethylolpropane triglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, triglycidyl ether of tris(2-hydroxyethyl) isocyanurate, 2,2-bis(4-glycidyloxycyclohexyl)propane, 2,2-bis(4-glycidyloxyphenyl)propane, 2,2-bis(4-glycidyloxyphenyl)sulfone or 2,2-bis(4-glycidyloxy-3,5-dibromophenyl)propane.

Claim 6

A composition for plastic lenses as claimed in claim 1 wherein the mono(meth)acrylate is at least one member selected from the group consisting of cyclohexyl (meth)acrylate, norbornyl (meth)acrylate, isobornyl (meth)acrylate, tricyclo[5.2.1.0 2 ,6 ]decan-8-yl (meth)acrylate, phenyl (meth)acrylate, benzyl (meth)acrylate, phenoxyethyl (meth)acrylate, -phenoxy-2-hydroxypropyl (meth)acrylate, 2-phenylphenyl (meth)acrylate, 4-phenylphenyl (meth)acrylate, 3-(2-phenylphenyl)-2-hydroxypropyl (meth)acrylate, 3-(4-phenylphenyl)-2-hydroxypropyl (meth)acrylate, 1-naphthyloxyethyl (meth)acrylate, 2-naphthyloxyethyl (meth)acrylate, 2,4,6-tribromophenyl (meth)acrylate, 2,4,6-tribromophenoxyethyl (meth)acrylate, 2,4,6-tribromophenyl-di(oxyethyl) (meth)acrylate and 2,4,6-tribromobenzyl (meth)acrylate.

Claim 7

A composition for plastic lenses as claimed in claim 1 which comprises (A) 20 to 50 parts by weight of at least one polybutylene glycol di(meth)acrylate selected from the group consisting of octabutylene glycol di(meth)acrylate, nonabutylene glycol di(meth)acrylate and decabutylene glycol di(meth)acrylate; (B) 30 to 60 parts by weight of a urethane poly(meth)acrylate having two or more (meth)acryloyloxy groups in the molecule that is an adduct of 2-hydroxypropyl (meth)acrylate with isophorone diisocyanate, dicyclohexylmethane diisocyanate, xylylene diisocyanate, 1,3-bis(α,α-dimethylisocyanatomethyl)benzene or tolylene diisocyanate; (C) 10 to 40 parts by weight of at least one compound selected from the group consisting of isobornyl (meth)acrylate, norbornyl (meth)acrylate, tricyclo[5.2.1.0 2 ,6 ]decan-8-yl (meth)acrylate, phenyl (meth)acrylate, benzyl (meth)acrylate, 2-phenylphenyl (meth)acrylate, 3-(2-phenylphenyl)-2-hydroxypropyl (meth)acrylate and 2,4,6-tribromophenoxyethyl (meth)acrylate; and (D) 5 to 30 parts by weight of at least one compound selected from the group consisting of 1,6-hexamethylene di(meth)acrylate, dicyclopentanyl di(meth)acrylate, trimethylolpropane tri(meth)acrylate, 2,2-bis[4-(meth)acryloyloxyethoxyphenyl]-propane, 2,2-bis[4-(meth)acryloyloxydiethoxyphenyl]propane, 2,2-bis[4-(meth)acryloyloxyethoxy-3,5-dibromophenyl]propane, 2,2-bis[4-(meth)acryloyloxyethoxyphenyl]sulfone, 2,2-bis[4-(meth)acryloyloxyethoxyphenyl]sulfide, styrene, divinylbenzene, diethylene glycol bisallyl carbonate and diallyl phthalate.

Claim 8

A composition for plastic lenses as claimed in claim 1 which further contains 0.005 to 5 parts by weight of a polymerization initiator.

Claim 9

A composition for plastic lenses as claimed in claim 1 which further contains 0.005 to 0.1 part by weight of a polymerization initiator.