Siloxane copolymers containing alkenyloxy groups, a process for preparing the same and their use

Claim 2

A siloxane copolymer which contains alkenyloxy groups and contains (a) siloxane units of the formula ##STR17## in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, R 1 is an alkyl radical having from 1 to 4 carbon atom(s) per radical which can be substituted by an ether oxygen atom, a is 0, 1, 2 or 3, b is 0, 1, 2 or 3 and the sum of a+b is not greater than 3, (b) at least one siloxane unit per molecule of the formula ##STR18## in which R is the same as above, c is 0, 1 or 2 and Q represents a radical of the formula --CH.sub.2 CHR.sup.2 CHR.sup.2 OY(OCR.sup.2 ═CR.sup.2 CH.sub.3).sub.x-1 in which R 2 is a radical selected from the group consisting of a hydrogen atom or a methyl radical, Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical having from 2 to 20 carbon atoms per radical which can be substituted with a group from the formula --OH, --OR.sup.3, --OSiR.sup.4.sub.3, ##STR19## --X, or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is a radical selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom, and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR20## and x is 3, 4, 5 or 6 and optionally (c) at least one unit per molecule selected from the group consisting of units of the formula ##STR21## in which R and c are the same as above, Q 1 represents a radical of the formula ##STR22## Q 2 represents a radical of the formula ##STR23## Q 3 represents a radical of the formula ##STR24## in which R 2 , Y and x are the same as above

Claim 3

The siloxane copolymer containing alkenyloxy groups of claim 1, which contains siloxane units of formula (I), at least one siloxane unit per molecule of formula (II) and at least one unit per molecule selected from the group consisting of units of formulas (III), (IV) and (V).

Claim 4

The siloxane copolymer containing alkenyloxy groups of claim 1 which contains (a) siloxane units represented by the formula R.sub.2 SiO (I') (b) at least two siloxane units per molecule represented by the formula QR.sub.2 SiO.sub.1/2 (II') and (c) at least one siloxane unit per molecule represented by formula O.sub.1/2 R.sub.2 SiQ.sup.1 SiR.sub.2 O.sub.1/2 (III') in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, Q is a radical of the formula --CH.sub.2 --CHR.sup.2 CHR.sup.2 OY(OCR.sup.2 ═Cr.sup.2 CH.sub.3).sub.x-1 Q 1 is a radical of the formula ##STR25## R 2 is a radical selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical having from 2 to 20 carbon atoms per radical, which can be substituted by groups of the formula --OH, --OR.sup.3, --OSiR.sup.4.sub.3, ##STR26## or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is a radical selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of ##STR27##

Claim 5

The siloxane copolymer containing alkenyloxy groups of claim 2 which contains (a) siloxane units represented by the formula R.sub.2 SiO (I'), (b) at least two siloxane units per molecule of formula (II) represented by the formula QR.sub.2 SiO.sub.1/2 (II') and (c) at least one siloxane unit per molecule of formula (III) represented by the formula O.sub.1/2 R.sub.2 SiQ.sup.1 SiR.sub.2 O.sub.1/2 (III') in which R is selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, Q is a radical of the formula --CH.sub.2 --CHR.sup.2 CHR.sup.2 OY(OCR.sup.2 ═CR.sup.2 CH.sub.3).sub.x-1 Q 1 is a radical of the formula ##STR28## R 2 is a radical selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical having from 2 to 20 carbon atoms per radical, which can be substituted by groups of the formula --OH, --OR.sup.3, --OSiR.sup.4.sub.3, ##STR29## --X or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═O or .tbd.SiR.sup.5 in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) radical, R 4 is radical selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 is a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from ##STR30## the group consisting of

Claim 6

A process for preparing a siloxane copolymer containing alkenyloxy groups of claim 1, which comprises in a first stage reacting an organic compound (1) containing more than two aliphatic double bonds, of the general formula Y(OCHR.sup.2 CR.sup.2═CH.sub.2).sub.x R 2 is a radical selected from the group consisting of a hydrogen atom and a methyl radical, x is 3, 4, 5 or 6 and Y is a trivalent, tetravalent, pentavalent or hexavalent hydrocarbon radical having from 2 to 20 carbon atoms per radical, which can be substituted by groups of the formula --OH, --OR.sup.3, --OSiR.sup.4.sub.3, ##STR31## --X or can be interrupted by at least one oxygen atom or sulfur atom or one carbonyl group, or Y represents a trivalent radical of the formula .tbd.P, .tbd.P═X or .tbd.SiR.sup.5 in which R 3 is an alkyl radical having from 1 to 6 carbon atom(s) per radical, R 4 is a radical selected from the group consisting of a methyl, ethyl, isopropyl, tert-butyl and phenyl radical, X is a halogen atom and R 5 a monovalent hydrocarbon radical having from 1 to 8 carbon atom(s) per radical, or Y represents a tetravalent element selected from the group consisting of the, elements ##STR32## an organopolysiloxane (2) having at least one Si-bonded hydrogen atom per molecule in the presence of a catalyst (3) which promotes the addition of Si-bonded hydrogen to an aliphatic double bond, in which the ratio of the aliphatic double bond in the organic compound (1) to the Si-bonded hydrogen in the organopolysiloxane (2) is such that siloxane copolymers are obtained which contain alkenyl groups and have an average of more than two alkenyl groups A of the formula --OCHR.sup.2 CR.sup.2 ═CH.sub.2 in which R 2 is the same as above, and in a 2nd stage, shifting the double bond in the alkenyl groups A to the carbon atom adjacent to the either oxygen atom by heating the siloxane copolymer containing alkenyl groups obtained in the 1st stage in the presence of a catalyst (4) which promotes a shift of the double bond, in which siloxane copolymers are obtained which contain alkenyloxy groups and have an average of more than two alkenyloxy groups B of the formula --OCR.sup.2 ═CR.sup.2 CH.sub.3, in which R 2 is the same as above.

Claim 7

The process of claim 5, wherein the organic compound (1) has the formula (R.sup.6 OCH.sub.2).sub.4-k C(CH.sub.2 OCH.sub.2 CH═CH.sub.2).sub.k, in which R 6 is selected from the group consisting of hydrogen and a radical of the formula ##STR33## ##STR34## and k is 3.

Claim 8

The process of claim 5, wherein the organopolysiloxane (2) having at least one Si-bonded hydrogen atom per molecule has the general formula H.sub.d R.sub.3-d SiO(SiR.sub.2 O).sub.o (SiRHO).sub.p SiR.sub.3-d H.sub.d(VII) in which R is a radical selected from the group consisting of hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical and halogenated hydrocarbon radicals having from 1 to 18 carbon atom(s) per radical, d is 0 or 1, o is 0 or an integer of from 1 to 1000 and p is 0 or an integer of from 1 to 6.

Claim 9

A composition which can be crosslinked by means of light comprising the siloxane copolymer containing alkenyloxy groups of claim 1.

Claim 10

A coating which may be obtained by applying a composition which contains the siloxane copolymer containing alkenyloxy groups of claim 1 to a substrate and thereafter the coated substrate is exposed to light.