US5237939A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method and apparatus for reducing NOx emissions
Assignee: WEXFORD MANAGEMENT LLC
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Filing: 1992-08-20
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Granted: 1993-08-24
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Expires: 2012-08-20
Abstract
Abstract An apparatus for reducing NOx pollution in the flue gas produced by a burner includes a heat exchanger wherein at least some of the heat transfer elements are coated with a catalyst. A plurality of reactive gas injectors are arranged to introduce a nitrogeneous compound, preferably a source of ammonia, across a hot-end face of the heat exchanger. A reactive gas flow distribution system permits the distribution of the nitrogeneous compound flowing through at least some of the gas injectors to be varied responsive to the temperature profile of the heat exchanger. Preferably, the apparatus also determines the total NOx flow in the flue gas, and the reactive gas flow distribution system permits the total amount of reactive gas flowing through at least some of the gas injectors to be varied responsive to the total NOx flow in the flue gas. <IMAGE>
Inventors
- 👤 Felix E. Spokoyny
- 👤 Henry V. Krigmont
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 14:00
CPC Classifications
F; F23; F23J; F23J15/00; F23J15/02; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8631; B01D2258/00; B01D2258/02; B01D2258/0283
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
178 words
A method of reducing NOx from a flue gas stream produced from a burner, which flue gas stream passes from the burner through a rotary regenerative heat exchanger which rotates in a direction generally transverse to the direction of the flow of the flue gas stream and wherein at least a portion of the heat transfer elements of the heat exchanger carry a catalyst which, in the presence of a nitrogeneous compound, promote the reduction of NOx from the flue gas stream passing thereby, comprising the steps of: injecting a quantity of a nitrogeneous compound onto the catalyzed heat transfer elements, such injecting being at a plurality of fixed locations along the arcuate path of travel of the catalyzed elements with respect to the flue gas stream; determining the temperature of the portion of the heat transfer elements as such elements travel in an arcuate path with respect to the flow of the flue gas stream; and in response to said step of determining, selectively varying the quantity of nitrogeneous compound injected at each of such fixed locations.
Claim 2
Independent Claim
178 words
A method of reducing NOx from a flue gas stream produced from a burner, which flue gas stream passes from the burner through a rotary regenerative heat exchanger which rotates in a direction generally transverse to the direction of the flow of the flue gas stream and wherein at least a portion of the heat transfer elements of the heat exchanger carry a catalyst which, in the presence of a nitrogeneous compound, promote the reduction of NOx from the flue gas stream passing thereby, comprising the steps of: injecting a quantity of a nitrogeneous compound onto the catalyzed heat transfer elements, such injecting being at a plurality of fixed locations along the arcuate path of travel of the catalyzed elements with respect to the flue gas stream; determining the temperature of the portion of the heat transfer elements as such elements travel in an arcuate path with respect to the flow of the flue gas stream; and in response to said step of determining, selectively varying the quantity of nitrogeneous compound injected at each of such fixed locations.
Claim 3
Dependent Claim
56 words
The method of claim 1, wherein the step of varying includes the steps of adjusting the total flow of the nitrogeneous compound responsive to the total amount of the pollutant in the flue gas, and apportioning the spatial variation of the flow of the nitrogeneous compound responsive to the temperature variation of the heat transfer elements.
Claim 4
Independent Claim
117 words
A method for reducing NOx from a flue gas stream produced from a burner, comprising the steps of: passing a flow of flue gas through a heat exchanger having catalyst-coated heat transfer elements whose temperature varies as a function of position across the lateral face of the heat exchanger; injecting a spatially variable flow of a nitrogeneous compound into the flow of flue gas at a location prior to the entry of the flue gas into the heat exchanger; and varying the spatial distribution of the flow of the nitrogeneous agent responsive to the spatial temperature variation of the heat transfer elements to achieve efficient catalytic reduction of the NOx in the flue gas on the catalyst.
Claim 5
Independent Claim
117 words
A method for reducing NOx from a flue gas stream produced from a burner, comprising the steps of: passing a flow of flue gas through a heat exchanger having catalyst-coated heat transfer elements whose temperature varies as a function of position across the lateral face of the heat exchanger; injecting a spatially variable flow of a nitrogeneous compound into the flow of flue gas at a location prior to the entry of the flue gas into the heat exchanger; and varying the spatial distribution of the flow of the nitrogeneous agent responsive to the spatial temperature variation of the heat transfer elements to achieve efficient catalytic reduction of the NOx in the flue gas on the catalyst.
Claim 6
Dependent Claim
56 words
The method of claim 3, wherein the step of varying includes the steps of adjusting the total flow of the nitrogeneous compound responsive to the total amount of the pollutant in the flue gas, and apportioning the spatial variation of the flow of the nitrogeneous compound responsive to the temperature variation of the heat transfer elements.
Claim 7
Dependent Claim
14 words
The method of claim 3, wherein the heat exchanger is a rotating-wheel heat exchanger.
Claim 8
Dependent Claim
107 words
Apparatus for reducing NOx from a flue gas stream produced from a burner, comprising: means for reacting a flow of flue gas with a nitrogeneous compound in the presence of a catalyst to react and reduce NOx in the flue gas, the means for reacting exhibiting a variation of temperature therein; means for adding a spatially controllably variable flow of a nitrogeneous compound to the flow of flue gas prior to the entry of the flue gas into the means for reacting; and means for adjusting the spatial distribution of the flow of the nitrogeneous compound responsive to the variation of temperature within the means for reacting.
Claim 9
Dependent Claim
107 words
Apparatus for reducing NOx from a flue gas stream produced from a burner, comprising: means for reacting a flow of flue gas with a nitrogeneous compound in the presence of a catalyst to react and reduce NOx in the flue gas, the means for reacting exhibiting a variation of temperature therein; means for adding a spatially controllably variable flow of a nitrogeneous compound to the flow of flue gas prior to the entry of the flue gas into the means for reacting; and means for adjusting the spatial distribution of the flow of the nitrogeneous compound responsive to the variation of temperature within the means for reacting.
Claim 10
Dependent Claim
32 words
The apparatus of claim 6, wherein the means for reacting includes a heat exchanger having heat exchange elements therein and a catalyst coated onto at least some of the heat exchange elements.
Claim 11
Dependent Claim
14 words
The apparatus of claim 7, wherein the heat exchanger is a rotating-wheel heat exchanger.
Claim 12
Dependent Claim
33 words
The apparatus of claim 6, wherein the means for adding includes a plurality of gas injectors disposed adjacent to a portion of the means for reacting through which the flue gas first passes.
Claim 13
Dependent Claim
26 words
The apparatus of claim 9, wherein the means for adding includes at least two gas manifolds, and the gas injectors are supplied by the gas manifolds.
Claim 14
Dependent Claim
31 words
The apparatus of claim 10, further including a gas flow distribution system that adjusts the total flow of the nitrogeneous compound to the manifold pipes responsive to the total NOx level.
Claim 15
Dependent Claim
34 words
The apparatus of claim 10, further including a gas flow distribution system that adjusts the flow of the nitrogeneous compound in each gas manifold responsive to the temperature distribution within the means for reacting.
Claim 16
Dependent Claim
18 words
The apparatus of claim 6, further including means for determining the total NOx level in the flue gas.
Claim 17
Dependent Claim
29 words
The apparatus of claim 13, wherein the means for determining includes means for measuring the pollutant level of the flue gas before it has entered the means for reacting.
Claim 18
Dependent Claim
25 words
The apparatus of claim 13, wherein the means for determining includes means for measuring the operating conditions of a burner that produces the flue gas.
Claim 19
Dependent Claim
18 words
The apparatus of claim 6, further including means for determining the temperature distribution within the means for reacting.
Claim 20
Dependent Claim
27 words
The apparatus of claim 16, wherein the means for determining includes a plurality of temperature measuring devices that measure the temperature distribution within the means for reacting.
Claim 21
Dependent Claim
16 words
The apparatus of claim 17, wherein at least some of the temperature measuring devices are thermocouples.
Claim 22
Dependent Claim
60 words
The apparatus of claim 13, wherein the means for adjusting includes means for controlling the total flow of the nitrogeneous compound flowing to the means for adding responsive to the total NOx level of the flue gas, and means for controlling the spatial distribution of the flow of nitrogeneous agent responsive to the temperature variation of the means for reacting.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-08-23 | 1997-02-22 | 1997-08-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-08-23 | 2001-02-22 | 2001-08-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-08-23 | 2005-02-22 | 2005-08-24 | $7700.00 | Window Closed / Lapsed |