US5243539A
Expired / Lapsed
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Method for predicting physical parameters in a diffusion process
Assignee: Boeing Co
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Filing: 1989-09-13
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Granted: 1993-09-07
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Expires: 2009-09-13
Abstract
Abstract A method for processing data produced by a chemical sensor to predict a rate of diffusion and steady-state level of a chemical vapor absorbed by a coating applied to the chemical sensor. A chemical sensor (10) includes a surface acoustic wave device (12) in which a polymer coating (34) is provided to absorb a chemical vapor. As the vapor is absorbed by the polymer coating, a resonant frequency associated with the SAW device changes in proportion to the mass of the vapor absorbed. The change in resonant frequency is periodically sampled by a high-speed counter (58), digitized, and filtered by a microprocessor (100). In processing the filtered data, the microprocessor describes each data point as a constraint line in a (τ,C) space, where τ corresponds to the rate of diffusion of the chemical vapor into the polymer and C corresponds to the concentration of the chemical vapor in the polymer at a time t. A minimum energy function L(τ,C) is determined for successive groups of constraint lines, eventually enabling final values for both τ and C to be predicted. The predicted values are used to detect and identify the chemical vapor to which the chemical sensor is exposed, well before the concentration of the chemical vapor in the polymer reaches a steady-state level.
Inventors
- 👤 Fred B. Holt
- 👤 David I. Feinstein
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 10:28
CPC Classifications
G; G01; G01N; G01N29/00; G01N29/02; G01N29/022; G01N2291/00; G01N2291/02; G01N2291/025; G01N2291/0256; G01N2291/04; G01N2291/042; G01N2291/0423
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
276 words
In a diffusion process that evolves with time such that the diffusion of one substance into another substance exponentially approaches a steady-state level at a diffusion rate, a method for predicting both the steady-state level and the diffusion rate substantially before the diffusion process reaches the steady-state level so as to rapidly identify one of the substances, comprising the steps of: (a) producing a signal indicative of the progression of the diffusion process; (b) representing values of the signal at corresponding points in the time during the diffusion process as a succession of constraint lines in a state space, where the constraint lines are defined by the signal and its rate of change about successive points in time; (c) repetitively determining a preliminary steady-state level and preliminary diffusion rate as a point in the state space for successive groups of the constraint lines so as to minimize, for each group, an error that is a function of a distance in the state space between the point and each constraint line in the group, where the state space comprises all possible pairings of diffusion rate and steady-state level; (d) determining the rate of change of at least one of the preliminary steady-state level and the diffusion rate; (e) identifying a predicted steady-state level of the signal and a predicted diffusion rate for the diffusion process as a function of the rate of change of said one of the preliminary steady-state level and the diffusion rate; and (f) based upon at least one of the predicted steady-state level and the predicted diffusion rate, rapidly identifying at least one of the substances substantially before the steady-state level is attained.
Claim 2
Dependent Claim
276 words
In a diffusion process that evolves with time such that the diffusion of one substance into another substance exponentially approaches a steady-state level at a diffusion rate, a method for predicting both the steady-state level and the diffusion rate substantially before the diffusion process reaches the steady-state level so as to rapidly identify one of the substances, comprising the steps of: (a) producing a signal indicative of the progression of the diffusion process; (b) representing values of the signal at corresponding points in the time during the diffusion process as a succession of constraint lines in a state space, where the constraint lines are defined by the signal and its rate of change about successive points in time; (c) repetitively determining a preliminary steady-state level and preliminary diffusion rate as a point in the state space for successive groups of the constraint lines so as to minimize, for each group, an error that is a function of a distance in the state space between the point and each constraint line in the group, where the state space comprises all possible pairings of diffusion rate and steady-state level; (d) determining the rate of change of at least one of the preliminary steady-state level and the diffusion rate; (e) identifying a predicted steady-state level of the signal and a predicted diffusion rate for the diffusion process as a function of the rate of change of said one of the preliminary steady-state level and the diffusion rate; and (f) based upon at least one of the predicted steady-state level and the predicted diffusion rate, rapidly identifying at least one of the substances substantially before the steady-state level is attained.
Claim 3
Dependent Claim
49 words
The method of claim 1, wherein said constraint line in the state space is defined by an equation of the form: C=fτ+f where: C is the preliminary steady-state level; f is the rate of change of the signal; τ is the preliminary diffusion rate; and f is the signal.
Claim 4
Dependent Claim
35 words
The method of claim 2, wherein the error is the square of the distance, d, between a point in the state space and a constraint line, as defined by an equation of the form: d=|fτ+f-c|.
Claim 5
Dependent Claim
42 words
The method of claim 1, wherein the preliminary steady-state level is generally defined by a differential equation: ##EQU5## in which, at a time t: f(t) is the signal; C(t) is the steady-state level; and τ(t) is the reciprocal of the diffusion rate.
Claim 6
Dependent Claim
75 words
The method of claim 4, wherein at each of the points in time during the diffusion process, the value of the signal and its rate of change determine a point in a phase plane defined by f(t) and df(t)/dt, and wherein least-squared distances between N such points and one of the constraint lines at a time t determine each of the constraint lines, said constraint lines having a slope of -1/τ(t) and an intercept c(t)/τ(t).
Claim 7
Dependent Claim
33 words
The method of claim 1, wherein there are N constraint lines in each group, the next group of constraint lines including a successive constraint line and the preceding N-1 constraint lines in time.
Claim 8
Dependent Claim
30 words
The method of claim 1, wherein the error includes a penalty term that penalizes a successive preliminary diffusion rate in proportion to its difference from a previous preliminary diffusion rate.
Claim 9
Dependent Claim
37 words
The method of claim 1, wherein said step of identifying includes the step of determining that the rate of change of said one of the preliminary steady-state level and diffusion rate is less than a predetermined value.
Claim 10
Independent Claim
278 words
A method for detecting and identifying a chemical substance from its effect on a surface acoustic wave device, comprising the steps of: (a) producing a signal using the surface acoustic wave device that is indicative of a parameter, which changes due to an increase in mass of a material coating on the surface acoustic wave device caused by diffusion of the chemical substance into the material coating, said change in the parameter generally being defined by an exponential curve; (b) filtering the signal to minimize effects of a random variation in the parameter, producing filtered data; (c) mapping the filtered data into a two-dimensional space defined by the steady state level and the diffusion rate, as a plurality of constraint lines that are defined by a linear relationship between the rate of change of the parameter during a finite interval of time, the diffusion rate, the resonant frequency and the steady-state level of the chemical substance of the material coating at the time each datum was monitored; (d) using the constraint lines in the two-dimensional space to determine coefficients of an equation defining the parameter by repetitively determining a plurality of points in the two-dimensional space so as to minimize an error based on distances between successive groups of the constraint lines and the points; (e) determining predicted values for the steady-state level and diffusion rate of the chemical substance in the material coating, based on the coefficients of the time varying equation; and (f) identifying the chemical substance from among a plurality of chemical substances having predefined characteristic steady-state and diffusion rate values as a function of the predicted values of the steady-state level and diffusion rate.
Claim 11
Independent Claim
278 words
A method for detecting and identifying a chemical substance from its effect on a surface acoustic wave device, comprising the steps of: (a) producing a signal using the surface acoustic wave device that is indicative of a parameter, which changes due to an increase in mass of a material coating on the surface acoustic wave device caused by diffusion of the chemical substance into the material coating, said change in the parameter generally being defined by an exponential curve; (b) filtering the signal to minimize effects of a random variation in the parameter, producing filtered data; (c) mapping the filtered data into a two-dimensional space defined by the steady state level and the diffusion rate, as a plurality of constraint lines that are defined by a linear relationship between the rate of change of the parameter during a finite interval of time, the diffusion rate, the resonant frequency and the steady-state level of the chemical substance of the material coating at the time each datum was monitored; (d) using the constraint lines in the two-dimensional space to determine coefficients of an equation defining the parameter by repetitively determining a plurality of points in the two-dimensional space so as to minimize an error based on distances between successive groups of the constraint lines and the points; (e) determining predicted values for the steady-state level and diffusion rate of the chemical substance in the material coating, based on the coefficients of the time varying equation; and (f) identifying the chemical substance from among a plurality of chemical substances having predefined characteristic steady-state and diffusion rate values as a function of the predicted values of the steady-state level and diffusion rate.
Claim 12
Dependent Claim
104 words
The method of claim 9, wherein the step of mapping comprises the steps of: (a) determining the rate of change of the filtered data over the finite interval of time; and (b) defining each constraint line by an equation having the form of: C=fτ+f wherein; C is the steady-state level of the chemical substance in the material coating during the finite interval of time; f is the rate of change of the parameter during the finite interval of time; τ is the diffusion rate during the finite interval of time; and f is a value of the parameter during the finite interval of time.
Claim 13
Dependent Claim
43 words
The method of claim 10, wherein the error is defined by the square of a distance between one of the constraint lines and one of the points in the two-dimensional space measured in a direction aligned with an axis defining the two-dimensional space.
Claim 14
Dependent Claim
68 words
The method of claim 9, wherein the step of determining coefficients includes the step of minimizing the affect of relatively large random variations in the diffusion rates by including a penalty term with the error, said penalty term having a magnitude that is a function of the difference between values of one of the diffusion rates and the steady-state levels for successive points determined in the state space.
References Cited (Backward Citations)
US3069654A
Cited
US4882781A
Cited
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| 3.5 Years (Year 4) | 1996-09-06 | 1997-03-08 | 1997-09-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-09-06 | 2001-03-08 | 2001-09-07 | $3760.00 | Window Closed / Lapsed |
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