Laminate

Claim 2

A laminate comprising a substrate having a surface and a resin surface layer having a glossiness of not less than 60% when measured at an incidence angle of 60° which is laminated on said surface of the substrate, wherein the substrate consists of a cycloolefin resin composition (B) containing at least one cycloolefin copolymer (A) selected from the group consisting of a random copolymer (a-1) of ethylene and a cycloolefin represented by the following formula (I), a ring opening polymer (a-2) of a cycloolefin represented by the following formula (I), a ring opening copolymer (a-3) of cycloolefins represented by the following formula (I), a hydrogenation product (a-4) of the ring opening polymer (a-2) or the ring opening copolymer (a-3), an unsaturated carboxylic acid graft-modified product (a-5) of the above (a-1), (a-2), (a-3) or (a-4), and a crosslinked produce (a-6) of the above (a-5), and a crystalline polyolefin having a crystallinity of more than 50% ##STR25## wherein n is 0 or 1; m is 0 or a positive integer; q is 0 or 1; R 1 to R 18 , R a and R b independently represent a hydrogen atom, a halogen atom or a hydrocarbon group; R 15 to R 18 may be bonded together to form a monocyclic group or a polycyclic group which may have double bond(s); and R 15 and R 16 , or R 17 and R 18 may form an alkylidene group; and the resin surface layer is formed from at least one resin selected from the group consisting of a polystyrene, an acrylonitrile/butadiene/sytrene copolymer, a polycarbonate, a polyalkylene terephthalate, a polyvinyl chloride, the cycloolefin polymer (A), a polyamide, and a cycloolefin resin composition (C) containing the cycloolefin polymer (A) and an α-olefin elastomeric copolymer having a crystallinity of not more than 25%.

Claim 3

The laminate as claimed in claim 1, wherein the cycloolefin resin composition (B) of the substrate further contains an α-olefin elastomeric copolymer having a crystallinity of not more than 25%.

Claim 4

The laminate as claimed in claim 1, wherein the crystalline polyolefin has a crystallinity of 55 to 85%.

Claim 5

A laminate comprising a substrate having a first surface and a second surface on opposite sides thereof, a resin surface layer having a glossiness of not less than 60% when measured at an incidence angle of 60° provided on said first surface of the substrate and a back surface layer provided on said second surface of the substrate, wherein the substrate consists of at least one cycloolefin copolymer (A) selected from the group consisting of a random copolymer (a-1) of ethylene and a cycloolefin represented by the following formula (I), a ring opening polymer (a-2) of a cycloolefin represented by the following formula (I), a ring opening copolymer (a-3) of cycloolefins represented by the following formula (I), a hydrogenation product (a-4) of the ring opening polymer (a-2) or the ring opening copolymer (a-3), an unsaturated carboxylic acid graft-modified product (a-5) of the above (a-1), (a-2), (a-3) or (a-4), and a crosslinked product (a-6) of the above (a-5), ##STR26## wherein n is 0 or 1; m is 0 or a positive integer; q is 0 or 1; R 1 to R 18 , R a and R b independently represent a hydrogen atom, a halogen atom or a hydrogen group; R 15 or R 18 may be bonded together to form a monocyclic group or a polycyclic group which may have double bond(s); and R 15 and R 16 , or R 17 and R 18 may form an alkylidene group, or the substrate consists of a cycloolefin resin composition (C) containing the cycloolefin polymer (A) and an α-olefin elastomeric copolymer having a crystallinity of not more than 25%; the resin surface layer is formed from at least one resin selected from a polystyrene, an acrylonitrile/butadiene/-styrene copolymer, a polycarbonate, a polyalkylene terephthalate, a polyvinyl chloride, the cycloolefin polymer (A), a polyamide, and a cycloolefin resin composition (C) containing the cycloolefin polymer (A) and an α-olefin elastomeric copolymer having a crystallinity of not more than 25%, said resin for forming the resin surface layer being different from the resin for forming the substrate; and the back surface layer is formed from a cycloolefin resin composition (B) containing the cycloolefin copolymer (A) and a crystalline polyolefin having a crystallinity of more than 50%.

Claim 6

A laminate comprising a substrate having a first surface and a second surface on opposite sides thereof, a resin surface layer having a glossiness of not less than 60% when measured at an incidence angle of 60° provided on said first surface of the substrate and a back surface layer provided on said second surface of the substrate, wherein the substrate consists of at least one cycloolefin copolymer (A) selected from the group consisting of a random copolymer (a-1) of ethylene and a cycloolefin represented by the following formula (I), a ring opening polymer (a-2) of a cycloolefin represented by the following formula (I), a ring opening copolymer (a-3) of cycloolefins represented by the following formula (I), a hydrogenation product (a-4) of the ring opening polymer (a-2) or the ring opening copolymer (a-3), an unsaturated carboxylic acid graft-modified product (a-5) of the above (a-1), (a-2), (a-3) or (a-4), and a crosslinked product (a-6) of the above (a-5), ##STR26## wherein n is 0 or 1; m is 0 or a positive integer; q is 0 or 1; R 1 to R 18 , R a and R b independently represent a hydrogen atom, a halogen atom or a hydrogen group; R 15 or R 18 may be bonded together to form a monocyclic group or a polycyclic group which may have double bond(s); and R 15 and R 16 , or R 17 and R 18 may form an alkylidene group, or the substrate consists of a cycloolefin resin composition (C) containing the cycloolefin polymer (A) and an α-olefin elastomeric copolymer having a crystallinity of not more than 25%; the resin surface layer is formed from at least one resin selected from a polystyrene, an acrylonitrile/butadiene/-styrene copolymer, a polycarbonate, a polyalkylene terephthalate, a polyvinyl chloride, the cycloolefin polymer (A), a polyamide, and a cycloolefin resin composition (C) containing the cycloolefin polymer (A) and an α-olefin elastomeric copolymer having a crystallinity of not more than 25%, said resin for forming the resin surface layer being different from the resin for forming the substrate; and the back surface layer is formed from a cycloolefin resin composition (B) containing the cycloolefin copolymer (A) and a crystalline polyolefin having a crystallinity of more than 50%.

Claim 7

The laminate as claimed in claim 4, wherein the substrate consists of the cycloolefin copolymer (A).

Claim 8

The laminate as claimed in claim 4, wherein the cycloolefin resin composition (C) of the substrate further contains a crystalline polyolefin having a crystallinity of more than 50%.

Claim 9

The laminate as claimed in claim 6, wherein the crystalline polyolefin has a crystallinity of 55 to 85%.

Claim 10

The laminate as claimed in claim 4, wherein the cycloolefin resin composition (B) of the back surface layer further contains an α-olefin elastomeric copolymer having a crystallinity of not more than 25%.

Claim 11

The laminate as claimed in claim 4, wherein the crystalline polyolefin has a crystallinity of 55 to 85%..