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US5338399A Expired / Lapsed US ⏱️ 0.0 years remaining

Dry etching method

Assignee: Sony Corp
•
Filing: 1992-02-12
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Granted: 1994-08-16
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Expires: 2012-02-12
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Abstract

Abstract A method for dry etching for forming a contact hole in a silicon oxide interlayer insulating film is proposed, by which high etchrate, high selectivity, low pollution and low damage may be achieved. An etching gas containing cyclic saturated fluorocarbon compounds, such as octafluorocyclobutane (c-C 4 F 8 ), or cyclic unsaturated fluorocarbon compounds, such as hexafluorocyclobutene (c-C 4 F 6 ), is used, and the wafer temperature is controlled to be 50° C. or lower. Both of the compounds are higher fluorocarbon compounds having three or more carbon atoms and yield more CF x + radicals per molecule than does CF 4 or the like compound to enable etching with a high etch rate. Besides, as compared with straight-chain saturated fluorocarbon compounds having the same number of carbon atoms, the above compounds exhibit a higher C/F ratio (the ratio of the number of carbon atoms to that of fluorine atoms per molecule) to permit carbonaceous polymers to be deposited effectively. In this manner, high selectivity and low damage basically may be achieved without using deposition gases simultaneously, with the result that low pollution may also be achieved.

Inventors

  • 👤 Toshiharu Yanagida

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:42
CPC Classifications
H; H10; H10P; H10P50/00; H10P50/20; H10P50/28; H10P50/282; H10P50/283; H10W; H10W20/00; H10W20/01; H10W20/071; H10W20/081

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 67 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a saturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching, wherein said etching gas also contrives a straight chain unsaturated fluorocarbon compound.
Claim 2
Dependent Claim 67 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a saturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching, wherein said etching gas also contrives a straight chain unsaturated fluorocarbon compound.
Claim 3
Dependent Claim 24 words
A dry etching method as claimed in claim 1 wherein said cyclic portion of the saturated fluorocarbon compound includes a 3- to 7-membered ring.
Claim 4
Dependent Claim 21 words
A dry etching method as claimed in claim 1 wherein said saturated fluorocarbon compound consists of 3 to 8 carbon atoms.
Claim 5
Dependent Claim 31 words
A dry etching method as claimed in claim 1 wherein the layer of the silicon compound is a layer of a silicon oxide based material or a silicon nitride based material.
Claim 6
Dependent Claim 20 words
A dry etching method as claimed in claim 1 wherein said etching gas also contains a straight-chain saturated fluorocarbon compound.
Claim 7
Dependent Claim 55 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a unsaturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching.
Claim 8
Dependent Claim 55 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a unsaturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching.
Claim 9
Dependent Claim 33 words
A dry etching method as claimed in claim 6 wherein said cyclic portion of said unsaturated fluorocarbon compound contains an unsaturated bond and wherein said cyclic portion includes a 3- to 6-membered ring.
Claim 10
Dependent Claim 31 words
A dry etching method as claimed in claim 6 wherein the layer of the silicon compound is a layer of a silicon oxide based material or a silicon nitride based material.
Claim 11
Dependent Claim 20 words
A dry etching method as claimed in claim 6 wherein said etching gas also contains a straight-chain saturated fluorocarbon compound.
Claim 12
Dependent Claim 74 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a saturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof and an unsaturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching.
Claim 13
Dependent Claim 74 words
A dry etching method comprising etching a layer of a silicon compound formed on a substrate using an etching gas plasma containing a saturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof and an unsaturated fluorocarbon compound having a cyclic portion in at least a portion of a molecular structure thereof, said substrate being controlled to a temperature of not higher than 50° C. during etching.
Claim 14
Dependent Claim 24 words
A dry etching method as claimed in claim 10 wherein said cyclic portion of the saturated fluorocarbon compound includes a 3- to 7-membered ring.
Claim 15
Dependent Claim 21 words
A dry etching method as claimed in claim 10 wherein said saturated fluorocarbon compound consists of 3 to 8 carbon atoms.
Claim 16
Dependent Claim 33 words
A dry etching method as claimed in claim 10 wherein said cyclic portion of said unsaturated fluorocarbon compound contains an unsaturated bond and wherein said cyclic portion includes a 3- to 6-membered ring.
Claim 17
Dependent Claim 31 words
A dry etching method as claimed in claim 10 wherein the layer of the silicon compound is a layer of a silicon oxide based material or a silicon nitride based material.

References Cited (Backward Citations)

US4162185A Cited
JPS57108267A Cited
JPS6077429A Cited
US4581101A Cited
US4807016A Cited
US4956043A Cited
US5038713A Cited
US5176790A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-08-15 1998-02-14 1998-08-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-08-15 2002-02-14 2002-08-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-08-15 2006-02-14 2006-08-16 $7700.00 Window Closed / Lapsed

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