Photographic element employing hue correction couplers

Claim 2

A silver halide color negative photographic element comprising a red sensitive silver halide emulsion layer containing a coupler with reacts with oxidized color developer to form a cyan dye, a blue sensitive silver halide emulsion layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive silver halide emulsion layer containing a coupler which upon reaction with oxidized color developer forms a magenta image dye, the element additionally comprising a hue correction coupler associated with said green sensitive layer which hue correction coupler reacts with oxidized developer to form a dye having a peak absorption between 565-600 nm so that the element has a D580/D550 ratio which is greater than that exhibited by the element absent the hue correction coupler.

Claim 3

A photographic element according to claim 1 wherein the element, absent the hue correction coupler, has a D580/D550 at neutral midscale exposure of 0.75 or less.

Claim 4

A photographic element according to claim 1 wherein the element, absent the hue correction coupler dye, has a D580/D550 at neutral midscale exposure of 0.65 or less.

Claim 5

A photographic element according to claim 1 wherein the hue correction coupler increases D580/D550 of the element at neutral midscale exposure by at least 0.01.

Claim 6

A photographic element according to claim 1 wherein the hue correction coupler increases D580/D550 of the element at neutral midscale exposure by at least 0.05.

Claim 7

A photographic element according to claim 4 wherein any increase in D640/D550 of the element at neutral midscale exposure caused by the hue correction coupler is less than the amount the hue correction coupler increases D580/D550 of the element at neutral midscale exposure.

Claim 8

A silver halide color negative photographic element comprising a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a 1-phenyl-3-anilino-5-pyrazolone coupler which upon reaction with oxidized color developer forms a magenta image dye, the element additionally comprising a hue correction coupler associated with a green sensitive layer which hue correction coupler reacts with oxidized developer to form a dye having a peak absorption between 565-600 nm so that the negative has a D580/D550 ratio which is greater than that exhibited by the element absent the hue correction coupler.

Claim 9

A silver halide color negative photographic element comprising a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a 1-phenyl-3-anilino-5-pyrazolone coupler which upon reaction with oxidized color developer forms a magenta image dye, the element additionally comprising a hue correction coupler associated with a green sensitive layer which hue correction coupler reacts with oxidized developer to form a dye having a peak absorption between 565-600 nm so that the negative has a D580/D550 ratio which is greater than that exhibited by the element absent the hue correction coupler.

Claim 10

A photographic element according to claim 7 wherein the element, absent the hue correction coupler, has a D580/D550 at neutral midscale exposure of 0.75 or less.

Claim 11

A photographic element according to claim 7 wherein the element, absent the hue correction coupler has a D580/D550 at neutral midscale exposure of 0.65 or less.

Claim 12

A photographic element according to claim 7 wherein the hue correction coupler increases D580/D550 of the element at neutral midscale exposure by at least 0.01 compared to the same element absent the hue correction coupler.

Claim 13

A photographic element according to claim 7 wherein the hue correction coupler increases D580/D550 of the element at neutral midscale exposure by at least 0.05 compared to the same element absent the hue correction coupler.

Claim 14

A photographic element according to claim 10 wherein any increase in D640/D550 of the element at neutral midscale exposure caused by the hue correction coupler, is less than the amount the hue correction coupler increases D580/D550 of the element at neutral midscale exposure.

Claim 15

A photographic element according to claim 7 wherein the hue correction coupler is located in a green sensitive layer of the element.

Claim 16

A photographic element according to claim 7 wherein the hue correction coupler is located in the least green sensitive layer when two or more green sensitive layers are present.

Claim 17

A silver halide color negative photographic element comprising: a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a coupler which upon reaction with oxidized color developer forms a magenta dye, the magenta dye-forming coupler being of the formula (M): ##STR26## Ar is an unsubstituted aryl group or an aryl group substituted with one or more substituents selected from halogen atoms and cyano, alkylsulfonyl, arylsulfonyl, sulfamoyl, sulfonamido, carbamoyl, carbonamido, alkoxy, acyloxy, aryloxy, alkoxycarbonyl, aryloxycarbonyl, ureido, nitro, alkyl, and trifluoromethyl, or Ar is an aryl group substituted with a group which forms a link to a polymeric chain; R 1 is a substituted or unsubstituted phenyl group, the R 1 substituents being individually selected from halogen atoms, and alkyl, aryl, alkoxy, aryloxy, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylsulfinyl, arylsulfinyl, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, aryloxycarbonyl, acyl, acyloxy, ureido, imido, carbamate, heterocyclic, cyano, trifluoromethyl, alkylthio, nitro, carboxyl and hydroxyl groups, provided that R 1 contains at least 6 carbon atoms or the R 1 substituents may individually comprise a group which forms a link to a polymeric chain; X is hydrogen or a coupling-off group selected from the group consisting of halogens, alkoxy, aryloxy, alkylthio, arylthio, acyloxy, sulfonamido, carbonamido, arylazo, nitrogen-containing heterocyclic and imido groups; and the element additionally comprising a hue correction coupler associated with a green sensitive layer which reacts with oxidized developer to form a dye having a peak absorption between 565-600 nm so that the element has a D580/D550 ratio at neutral midscale exposure which is greater than exhibited by the element absent the hue correction coupler.

Claim 18

A silver halide color negative photographic element comprising: a red sensitive layer containing a coupler which reacts with oxidized color developer to form a cyan dye, a blue sensitive layer containing a coupler which reacts with oxidized color developer to form a yellow dye, and a green sensitive layer containing a coupler which upon reaction with oxidized color developer forms a magenta dye, the magenta dye-forming coupler being of the formula (M): ##STR26## Ar is an unsubstituted aryl group or an aryl group substituted with one or more substituents selected from halogen atoms and cyano, alkylsulfonyl, arylsulfonyl, sulfamoyl, sulfonamido, carbamoyl, carbonamido, alkoxy, acyloxy, aryloxy, alkoxycarbonyl, aryloxycarbonyl, ureido, nitro, alkyl, and trifluoromethyl, or Ar is an aryl group substituted with a group which forms a link to a polymeric chain; R 1 is a substituted or unsubstituted phenyl group, the R 1 substituents being individually selected from halogen atoms, and alkyl, aryl, alkoxy, aryloxy, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylsulfinyl, arylsulfinyl, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, aryloxycarbonyl, acyl, acyloxy, ureido, imido, carbamate, heterocyclic, cyano, trifluoromethyl, alkylthio, nitro, carboxyl and hydroxyl groups, provided that R 1 contains at least 6 carbon atoms or the R 1 substituents may individually comprise a group which forms a link to a polymeric chain; X is hydrogen or a coupling-off group selected from the group consisting of halogens, alkoxy, aryloxy, alkylthio, arylthio, acyloxy, sulfonamido, carbonamido, arylazo, nitrogen-containing heterocyclic and imido groups; and the element additionally comprising a hue correction coupler associated with a green sensitive layer which reacts with oxidized developer to form a dye having a peak absorption between 565-600 nm so that the element has a D580/D550 ratio at neutral midscale exposure which is greater than exhibited by the element absent the hue correction coupler.

Claim 19

A photographic element according to claim 15 in which Ar is of the structure: ##STR27## wherein R a is selected from the group consisting of halogen, cyano, alkylsulfonyl, arylsulfonyl, sulfamoyl, sulfonamido, carbamoyl, carbonamido, ureido, atkoxycarbonyl, aryloxycarbonyl, acyloxy, alkoxy, aryloxy, nitro and trifluoromethyl groups; --NHR 1 is of the structure: ##STR28## wherein p is from zero to 2 and each R 2 is in a meta or para position with respect to R 3 ; each R 2 is individually selected from the group consisting of halogen, alkyl, alkoxy, aryloxy, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylsulfinyl, arylsulfinyl, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, ureido, imido, carbamate, heterocyclic, cyano, nitro, acyl, trifluoromethyl, alklythio and carboxyl groups; and R 3 is selected from the group consisting of hydrogen, halogen, alkyl, alkoxy, aryloxy, alkylthio, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, acyloxy, acyl, cyano, nitro and trifluoromethyl groups; and X is of the structure: ##STR29## wherein R 4 and R 5 are individually selected from the group consisting of hydrogen, halogen, alkyl, alkoxy, aryloxy, carbonamido, ureido, carbamate, sulfonamido, carbamoyl, sulfamoyl, acyloxy, alkoxycarbonyl, aryloxycarbonyl, amino and carboxyl groups, and wherein q is 0, 1 or 2 and R 5 may be in the meta or para position with respect to the sulfur atom.

Claim 20

A photographic element according to claim 15 wherein the hue correction coupler has a formula selected from formulas I, II, III, IV, V, VI and VII: ##STR30## where: Ar is a unsubstituted aryl group or an aryl group substituted wit one or more substituents selected from halogen atoms and cyano, alkylsulfonyl, arylsulfonyl, sulfamol, sulfonamido, carbamoyl, carbonamido, alkoxy, acyloxy, aryloxy, alkoxycarbonyl, aryloxycarbonyl, ureido, nitro, alkyl, and trifluoromethyl, or Ar is an aryl group substituted with a group which forms a link to a polymeric chain; R 1 is any substituent with a para Hammett constant value (σ p ) of zero or greater; X is a hydrogen atom or any coupling-off group known in the art; and wherein the combination of Ar and R 1 are chosen to give a dye with λ max of 565-600 nm after development; ##STR31## where Ar and X are as previously defined for Formula (I); R 6 is a unsubstituted or substituted alkyl or phenyl group the substituents of R 6 being individually selected from halogen atoms, and alkyl, aryl, alkoxy, aryloxy, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylslfinyl, arylsulfinyl, alkylsulfonyl, arylsulfonyl, alkoxycarbonyl, aryloxycarbonyl, acyl, acyloxy, ureido, imido, carbamate, heterocyclic, cyano, trifluoromethyl, alkylthio, nitro, carboxyl and hydroxyl groups, provided that R 6 contains at least 6 carbon atoms or the R 6 substitutents may individually comprise a group which forms a link to a polymeric chain; R 7 is an alkyl, alkoxy, aryl, aryloxy or amino group; and wherein the combination of Ar and R 6 are chosen to give a dye with λ max of 565-600 nm after development; ##STR32## where: X is as defined previously for Formula (I); Q represents a group of non-metallic atoms necessary to form a nitrogen containing heterocyclic ring which has a substituent R 9 ; R 8 and R 9 are either an alkyl or aryl group or any substituent with a para Hammett constant value (σ p ) of zero or greater; at least one of R 8 or R 9 is either a phenyl group or a substituent with a para Hammett constant value (σ p ) of zero or greater and together provide a dye with λ max of 565-600 nm after development; ##STR33## where: X and R 1 are as defined previously; R 10 is selected from the same group as R 1 ; and m is 0-5; with the proviso that the substituents are chosen as to provide a dye with peak absorbency of 565 nm-600 nm after development; ##STR34## where: R 10 , m, and X are as previously defined; R 11 is selected from the group consisting of alkyl, alkyloxy, acylamino, amino, and aryl; with the proviso that the substituents are chosen as to provide a dye with peak absorbency of 565 nm-600 nm after development. ##STR35## where; X and R 11 as defined previously; R 15 and R 16 are each individually hydrogen or a substituent as defined for R 11 or may be joined together to form a ring system; and with the proviso that the substituents are chosen as to provide a dye with peak absorbency of 565 nm-600 nm after development; ##STR36## where: X and R 11 are as previously defined; R 17 and R 18 are each independently from the same group as R 1 ; R 19 is a substituent with a para Hammett sigma constant value of at least 0.3; q is 1-5 and p is 0-4 such that (q+p) is less than or equal to 5; and wherein the substituents are chosen as to provide a dye with λ max of 565-600 nm after development.

Claim 21

A photographic element according to claim 15 wherein the image coupler level in said green-sensitive layer is 0.01 to 5 g/m 2 and the hue correction coupler level is 0.0002 to 5 g/m 2 .

Claim 22

A photographic element according to claim 15 wherein said green sensitive layer contains the image coupler level at a laydown of 0.02 to 2 g/m 2 and the hue correction coupler level at a laydown or 0.001 to 2 g/m 2 .

Claim 23

A photographic element according to claim 15 wherein the laydown of the image dye-forming coupler in said green sensitive layer is 0.05 to 1 g/m 2 and of the hue correction coupler is 0.01 to 1 g/m 2 .

Claim 24

A photographic element according to claim 15 wherein the element, absent the hue correction coupler, has a D580/D550 at neutral midscale exposure of 0.75 or less.

Claim 25

A silver halide photographic element according to claim 15 wherein the element, absent the hue correction coupler, has D580/D550 at neutral midscale exposure of 0.65 or less.

Claim 26

A silver halide photographic element according to claim 15 wherein the hue correction coupler increases D 580 /D550 of the element at neutral midscale exposure by at least 0.01 compared to the same element absent the hue correction coupler.

Claim 27

A silver halide photographic element according to claim 15 wherein the hue correction coupler increased D580/D550 of the element at neutral midscale exposure by at least 0.05 compared to the same element absent the hue correction coupler.

Claim 28

A silver halide photographic element according to claim 15 wherein the hue correction coupler has the following structure: ##STR37## where X and Ar are as defined in claim 15 and R 6 is a substitutent with para Hammett sigma constant of greater than zero.