Thermoplastic multilayer composites

Claim 2

A thermoplastic multilayer composite which comprises at least: (I) a layer formed from a polyvinylidene fluoride molding composition, and (II) a second layer adjacent to said layer (I) formed from a molding composition consisting essentially of a mixture of (a) from 40-90% by weight polyamide, and (b) from 60-10% by weight polyglutarimide, wherein the two layers (I) and (II) adhesively bond to each other, said polyglutarimide component (IIb) consisting of the following building blocks: i) a maximum of 98.8% by weight, based on the total weight of component (IIb) of ##STR5## ii) greater than 0% by weight to a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR6## iii) <20% by weight, based on the total weight of component (IIb), of ##STR7## iv) from 1.2 to 20% by weight, based on the total weight of component (IIb), of ##STR8## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 3

The thermoplastic multilayer composite of claim 1, wherein said component (IIb) consists of the following basic building blocks: i) from 10 to 60% by weight, based on the total weight of component (IIb) of ##STR9## ii) from 30 to 80% by weight, based on the total weight of component (IIb), of ##STR10## iii) from 2 to 10% by weight, based on the total weight of component (IIb), of ##STR11## iv) from 1.5 to 12% by weight, based on the total weight of component (IIb), of ##STR12## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 4

The thermoplastic multilayer composite of claim 1, wherein said layer (I) comprising a polyvinylidene fluoride molding composition has a melt flow index of <17 g/10 min.

Claim 5

The thermoplastic multilayer composite of claim 3, wherein said melt flow index of said polyvinylidene fluoride molding composition ranges from 2 to 13 g/10 min.

Claim 6

The thermoplastic multilayer composite of claim 1, wherein the polyvinylidene fluoride of the molding composition which forms layer (I) is a polyvinylidene fluoride copolymer.

Claim 7

The thermoplastic multilayer composite of claim 5, wherein a comonomer polymerized with vinylidene fluoride for the preparation of said polyvinylidene fluoride copolymer is trifluoroethylene, ethylene, propene or hexafluoropropene.

Claim 8

The thermoplastic multilayer composite of claim 1, wherein the relative amounts of said components (IIa) and (IIb) are 60 to 80% by weight and 20 to 40% by weight respectively.

Claim 9

The thermoplastic multilayer composite of claim 1 wherein the amount of building block (iv) ranges from 2 to 10% by weight of the components of polyglutarimide (IIb).

Claim 10

The thermoplastic multilayer composite of claim 1, wherein said alkyl group and groups R 1 to R 5 are each methyl.

Claim 11

The thermoplastic multilayer composite of claim 1, which further comprises a polyamide 12 layer (III) directly adjacent to layer (II), on the side opposite layer (I), wherein said layers (II) and (III) are adhesively bonded to each other.

Claim 12

The thermoplastic multilayer composite of claim 10, wherein said layer (III) is formed of a polyamide 12/polyglutarimide blended composition.

Claim 13

The thermoplastic multilayer composite of claim 1, wherein said layer (I) is electrically conductive and has a surface resistance of <10 9 Ω.

Claim 14

The thermoplastic multilayer composite of claim 1, wherein the polyamide component (IIa) contains an impact modifier selected from the group consisting of ethylene/propylene copolymer, ethylene/propylene/diene copolymer, polypentenylene, polyoctenylene, random or block copolymers formed of alkenylaromatic compounds with aliphatic olefins or dienes, and a core/shell rubber having a core of (meth)acrylate, butadiene or styrene/butadiene rubber.

Claim 15

A molding comprising a thermoplastic multilayer composite which comprises at least: (I) a layer formed from a polyvinylidene fluoride molding composition, and (II) a second layer adjacent to said layer (I) formed from a molding composition consisting essentially of a mixture of (a) from 40-90% by weight polyamide, and (b) from 60-10% by weight polyglutarimide, wherein the two layers (I) and (II) adhesively bond to each other, said polyglutarimide component (IIb) consisting of the following building blocks: i) a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR13## ii) greater than 0% by weight to a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR14## iii) <20% by weight, based on the total weight of component (IIb), of ##STR15## iv) from 1.2 to 20% by weight, based on the total weight of component (IIb), of ##STR16## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 16

A molding comprising a thermoplastic multilayer composite which comprises at least: (I) a layer formed from a polyvinylidene fluoride molding composition, and (II) a second layer adjacent to said layer (I) formed from a molding composition consisting essentially of a mixture of (a) from 40-90% by weight polyamide, and (b) from 60-10% by weight polyglutarimide, wherein the two layers (I) and (II) adhesively bond to each other, said polyglutarimide component (IIb) consisting of the following building blocks: i) a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR13## ii) greater than 0% by weight to a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR14## iii) <20% by weight, based on the total weight of component (IIb), of ##STR15## iv) from 1.2 to 20% by weight, based on the total weight of component (IIb), of ##STR16## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 17

The molding of claim 14, wherein said component (IIb) consists of the following basic building blocks: i) from 10 to 60% by weight, based on the total weight of component (IIb) of ##STR17## ii) from 30 to 80% by weight, based on the total weight of component (IIb), of ##STR18## iii) from 2 to 10% by weight, based on the total weight of component (IIb), of ##STR19## iv) from 1.5 to 12% by weight, based on the total weight of component (IIb), of ##STR20## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 18

A hollow article comprising a thermoplastic multilayer composite which comprises at least: (I) a layer formed from a polyvinylidene fluoride molding composition, and (II) a second layer adjacent to said layer (I) formed from a molding composition consisting essentially of a mixture of (a) from 40-90% by weight polyamide, and (b) from 60-10% by weight polyglutarimide, wherein the two layers (I) and (II) adhesively bond to each other, said polyglutarimide component (IIb) consisting of the following building blocks: i) a maximum of 98.8% by weight, based on the total weight of component (IIb) of ##STR21## ii) a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR22## iii) <20% by weight, based on the total weight of component (IIb), of ##STR23## iv) from 1.2 to 20% by weight, based on the total weight of component (IIb), of ##STR24## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.

Claim 19

A hollow article comprising a thermoplastic multilayer composite which comprises at least: (I) a layer formed from a polyvinylidene fluoride molding composition, and (II) a second layer adjacent to said layer (I) formed from a molding composition consisting essentially of a mixture of (a) from 40-90% by weight polyamide, and (b) from 60-10% by weight polyglutarimide, wherein the two layers (I) and (II) adhesively bond to each other, said polyglutarimide component (IIb) consisting of the following building blocks: i) a maximum of 98.8% by weight, based on the total weight of component (IIb) of ##STR21## ii) a maximum of 98.8% by weight, based on the total weight of component (IIb), of ##STR22## iii) <20% by weight, based on the total weight of component (IIb), of ##STR23## iv) from 1.2 to 20% by weight, based on the total weight of component (IIb), of ##STR24## wherein alkyl is methyl, ethyl, propyl, butyl, or hexyl; and R 1 to R 5 , identical or different, are hydrogen or (C n H 2n+1 ) where n is an integer of from 1 to 6.