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US5510502A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst component for use in the polymerization of α-olefins and process for producing α-olefin polymers using the same

Assignee: Mitsubishi Chemical Corp
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Filing: 1994-02-18
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Granted: 1996-04-23
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Expires: 2014-02-18
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Abstract

Abstract A catalyst component for use in the polymerization of alpha -olefins, comprising a compound represented by the following general formula [I]: <IMAGE> [I] wherein R1s represent a hydrogen atom, a C1-6 hydrocarbon group or a C1-12 hydrocarbon group containing silicon; each of R2 and R3 which forms the condensed ring represents a divalent C3-20 saturated or unsaturated hydrocarbon group, provided that at least one of R2 and R3 forms a ring condensed with the cyclopentadiene which is a seven- to twelve-membered ring having an unsaturated bond inherent in R2 or R3; Q represents a C1-20 divalent hydrocarbon group, a silylene group, a silylene group with a C1-20 hydrocarbon group, a germylene group, or a germylene group with a C1-20 hydrocarbon group; X and Y represent H, a halogen, a C1-20 hydrocarbon group, or a C1-20 hydrocarbon group containing oxygen, nitrogen or phosphorus; and M represents a Group IVB to VIB transition metal of the Periodic Table. Production of alpha -olefin polymers having a high melting point and a high molecular weight in a high yield and a process for producing alpha -olefin polymers is made possible upon the use of the catalyst.

Inventors

  • 👤 Toshihiko Sugano
  • 👤 Tomohiko Takahama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:27
CPC Classifications
C; C07; C07F; C07F17/00; C08; C08F; C08F10/00; C08F4/00; C08F4/42; C08F4/44; C08F4/60; C08F4/62; C08F4/64; C08F4/659; C08F4/65908; C08F4/65912; C08F4/6592; C08F4/65922; C08F4/65927

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 243 words
A catalyst component for use in the polymerization of α-olefins which comprises a compound represented by the following general formula I!: ##STR9## wherein R 1 s each independently represent a hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms or a hydrocarbon group having 1 to 12 carbon atoms with a silicon atom contained therein; each of R 2 and R 3 independently represents a divalent saturated or unsaturated hydrocarbon group having 3 to 20 carbon atoms which forms a ring condensed with the five-membered ring to which it is attached, provided that at least one of R 2 and R 3 forms the ring condensed which is a seven- to twelve-membered ring having an unsaturated bond inherent in R 2 or R 3 used; Q represents a divalent hydrocarbon group having 1 to 20 carbon atoms, a silylene group, a silylene group with a hydrocarbon group having 1 to 20 carbon atoms, a germylene group, or a germylene group with a hydrocarbon group having 1 to 20 carbon atoms, which group combines the two five-membered rings with each other; X and Y each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a hydrocarbon group having 1 to 20 carbon atoms with an oxygen atom, a nitrogen atom, a silicon atom or a phosphorus atom contained therein; and M represents a Group IVB to VIB transition metal of the Periodic Table.
Claim 2
Dependent Claim 243 words
A catalyst component for use in the polymerization of α-olefins which comprises a compound represented by the following general formula I!: ##STR9## wherein R 1 s each independently represent a hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms or a hydrocarbon group having 1 to 12 carbon atoms with a silicon atom contained therein; each of R 2 and R 3 independently represents a divalent saturated or unsaturated hydrocarbon group having 3 to 20 carbon atoms which forms a ring condensed with the five-membered ring to which it is attached, provided that at least one of R 2 and R 3 forms the ring condensed which is a seven- to twelve-membered ring having an unsaturated bond inherent in R 2 or R 3 used; Q represents a divalent hydrocarbon group having 1 to 20 carbon atoms, a silylene group, a silylene group with a hydrocarbon group having 1 to 20 carbon atoms, a germylene group, or a germylene group with a hydrocarbon group having 1 to 20 carbon atoms, which group combines the two five-membered rings with each other; X and Y each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, or a hydrocarbon group having 1 to 20 carbon atoms with an oxygen atom, a nitrogen atom, a silicon atom or a phosphorus atom contained therein; and M represents a Group IVB to VIB transition metal of the Periodic Table.
Claim 3
Dependent Claim 26 words
The catalyst component as claimed in claim 1, wherein the metal M in the compound is selected from the group consisting of titanium, zirconium and hafnium.
Claim 4
Dependent Claim 14 words
The catalyst component as claimed in claim 2, wherein the metal M is zirconium.
Claim 5
Dependent Claim 31 words
The catalyst component as claimed in claim 1, wherein R 2 and R 3 are each selected from the group consisting of 1,3-pentadienylene, 1,3-hexadienylene, 5-methyl-1,3-hexadienylene, 1,3,5-hexatrienylene, 1,3,5-heptatrienylene 1,4-pentadienylene, 3-methyl-1,4-pentadienylene and 1,2-dimethyl-1,3,5-hexatrienylene.
Claim 6
Dependent Claim 15 words
The catalyst component as claimed in claim 1, wherein R 1 is a hydrogen atom.
Claim 7
Dependent Claim 21 words
The catalyst component as claimed in claim 1, wherein R 1 is an alkyl group of 1 to 4 carbon atoms.
Claim 8
Dependent Claim 23 words
The catalyst component as claimed in claim 1, wherein Q is selected from the group consisting of alkylene, cycloalkylene, arylene and alkylsilylene groups.
Claim 9
Dependent Claim 12 words
The catalyst component as claimed in claim 1, wherein Q is dimethylsilylene.

References Cited (Backward Citations)

US5120867A Cited
EP0372414A2 Cited
US5145819A Cited
EP0490256A1 Cited
EP0496193A1 Cited
EP0529908A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-04-23 1999-10-23 2000-04-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-04-23 2003-10-23 2004-04-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-04-23 2007-10-23 2008-04-23 $7700.00 Window Closed / Lapsed

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