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US5568316A Expired / Lapsed US ⏱️ 0.0 years remaining

Formable reflective multilayer body

Assignee: 3M Innovative Properties Co
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Filing: 1995-04-13
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Granted: 1996-10-22
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Expires: 2015-04-13
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Abstract

Abstract A formable multilayer reflective polymeric body which has a substantially uniform broad bandwidth reflectance over substantially the entire range of the visible spectrum to provide a substantially uniform reflective appearance is provided. The body includes at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of the first and second polymeric materials such that at least 40% of visible light incident on the body is reflected. A substantial majority of the individual layers of the body have optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of the polymeric materials is greater than about 190 nm, and the first and second polymeric materials differ from each other in refractive index by at least about 0.03.

Inventors

  • 👤 Walter J. Schrenk
  • 👤 Charles B. Arends
  • 👤 Conrad F. Balazs
  • 👤 Ray A. Lewis
  • 👤 John A. Wheatley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 13:34
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/10; G02B5/00; G02B5/20; G02B5/28; G02B5/285; G02B5/287; F; F21; F21S; F21S43/00; F21S43/20; F21S43/26; F21V; F21V3/00; F21V3/04; G02B5/08; G02B5/0816; G02B5/0825; G02B5/0841; G02B5/26

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 280 words
A formable polymeric multilayer reflective body having a substantially uniform reflective appearance over substantially the entire range of the visible spectrum comprising: at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 40% of visible light incident on said body is reflected, a substantial majority of the individual layers of said body having optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of said polymeric materials is between about 190 nm and 1700 nm, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, wherein said layers have a gradient of optical layer repeat unit thicknesses through the thickness of said body which is sufficient to reflect substantially the entire range of visible light up to a predetermined maximum draw ratio ##EQU8## where MDR is the maximum draw ratio; t i is the initial thickness of the optically active layers in the multilayer stack; t f is the final thickness of the layers in the microlayer core in the thermoformed part at MDR; (λ 1 ) max is the maximum reflecting wavelength in the body in nanometers; the summation from i=1 to j of (N i d i ) max is the maximum optical repeat unit thickness in the body in nanometers; N i is the refractive index of the i th layer in the repeat unit; d i is the physical layer thickness of the i th layer in the repeat unit; and the constant 680 nm is the upper wavelength limit of visible light.
Claim 2
Dependent Claim 280 words
A formable polymeric multilayer reflective body having a substantially uniform reflective appearance over substantially the entire range of the visible spectrum comprising: at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 40% of visible light incident on said body is reflected, a substantial majority of the individual layers of said body having optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of said polymeric materials is between about 190 nm and 1700 nm, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, wherein said layers have a gradient of optical layer repeat unit thicknesses through the thickness of said body which is sufficient to reflect substantially the entire range of visible light up to a predetermined maximum draw ratio ##EQU8## where MDR is the maximum draw ratio; t i is the initial thickness of the optically active layers in the multilayer stack; t f is the final thickness of the layers in the microlayer core in the thermoformed part at MDR; (λ 1 ) max is the maximum reflecting wavelength in the body in nanometers; the summation from i=1 to j of (N i d i ) max is the maximum optical repeat unit thickness in the body in nanometers; N i is the refractive index of the i th layer in the repeat unit; d i is the physical layer thickness of the i th layer in the repeat unit; and the constant 680 nm is the upper wavelength limit of visible light.
Claim 3
Dependent Claim 16 words
The formable polymeric multilayer reflective body of claim 1 in which said polymeric materials are elastomers.
Claim 4
Dependent Claim 40 words
The formable polymeric multilayer reflective body of claim 1 in which said gradient of optical layer repeat unit thicknesses is a function which provides substantially continuous wavelength coverage spanning the range of from about 380 nm to about 2000 nm.
Claim 5
Dependent Claim 23 words
The formable polymeric multilayer reflective body of claim 1 in which said gradient of optical layer repeat unit thicknesses is a linear function.
Claim 6
Dependent Claim 22 words
The formable polymeric multilayer reflective body of claim 1 wherein the reflectance of said body changes upon the thinning of said layers.
Claim 7
Dependent Claim 17 words
The formable polymeric multilayer reflective body of claim 1 wherein said body has at least 1000 layers.
Claim 8
Dependent Claim 22 words
The formable polymeric multilayer reflective body of claim 1 wherein at least 80% of visible light incident on said body is reflected.
Claim 9
Dependent Claim 185 words
A formable polymeric multilayer reflective body having a substantially uniform reflective appearance over substantially the entire range of the visible spectrum comprising: at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 40% of visible light incident on said body is reflected, a substantial majority of the individual layers of said body having optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of said polymeric materials is between about 190 nm and 1700 nm, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, wherein said layers have a gradient of optical layer repeat unit thicknesses through the thickness of said body such that said gradient of optical layer repeat unit thicknesses provide continuous wavelength coverage over substantially the entire range of the visible spectrum for said body to maintain a substantially uniform reflective appearance when drawn, and wherein said gradient of optical layer repeat unit thicknesses is a quartic function.
Claim 10
Dependent Claim 185 words
A formable polymeric multilayer reflective body having a substantially uniform reflective appearance over substantially the entire range of the visible spectrum comprising: at least first and second diverse polymeric materials, the body comprising a sufficient number of alternating layers of said first and second polymeric materials such that at least 40% of visible light incident on said body is reflected, a substantial majority of the individual layers of said body having optical thicknesses in the range where the sum of the optical thicknesses in a repeating unit of said polymeric materials is between about 190 nm and 1700 nm, wherein said first and second polymeric materials differ from each other in refractive index by at least about 0.03, wherein said layers have a gradient of optical layer repeat unit thicknesses through the thickness of said body such that said gradient of optical layer repeat unit thicknesses provide continuous wavelength coverage over substantially the entire range of the visible spectrum for said body to maintain a substantially uniform reflective appearance when drawn, and wherein said gradient of optical layer repeat unit thicknesses is a quartic function.
Claim 11
Dependent Claim 30 words
The formable polymeric multilayer reflective body of claim 8 in which said quartic function which defines said gradient of optical layer repeat unit thicknesses is superimposed on a linear gradient.

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