Magnetorheological fluids

Claim 2

A magnetorheological fluid comprising low coercivity, generally spherical magnetic particles dispersed in a liquid vehicle, said particles consisting essentially of a first group of particles having a first range of diameter sizes with a first mean diameter having a standard deviation no greater than about two-thirds of the value of said first mean diameter and a second group of particles with a second range of diameter sizes and a second mean diameter having a standard deviation no greater than about two-thirds of said second mean diameter, such that the major portion of all particle sizes fall within the range of one to 100 microns and the weight ratio of each of said first group and said second group to the total weight of said magnetic particles is in the range of 0.1 to 0.9, and the ratio of said first mean diameter to said second mean diameter is five to ten.

Claim 3

A fluid as recited in claim 1 in which said first and second groups of particles comprise one or more metals selected from the group consisting of iron, nickel and cobalt.

Claim 4

A fluid as recited in claim 1 in which said first and second groups of particles comprise carbonyl iron particles having a mean diameter in the range of one to ten microns.

Claim 5

A fluid as recited in claim 1 in which said first and second groups of particles are of the same composition.

Claim 6

A fluid as recited in claim 1 in which said particles are dispersed in a polyalphaolefin containing liquid.

Claim 7

A fluid as recited in claim 1 in which said particles are dispersed in an esterified fatty acid containing liquid.

Claim 8

A fluid that is pourable at ambient conditions in the absence of an applied magnetic field but has a yield stress in excess of 10 psi in an applied magnetic field one Tesla or more, said fluid comprising generally spherical, low coercivity, ferromagnetic or paramagnetic metal particles of particle sizes substantially in the range of one micron to 100 microns dispersed in a liquid vehicle with a dispersing agent, said particles consisting essentially of a first group of particles having a first range of diameter sizes with a first mean diameter having a standard deviation no greater than about two-thirds of the value of said first mean diameter and a second group of particles with a second range of diameter sizes and a second mean diameter having a standard deviation no greater than about two-thirds of the value of said mean diameter such that the ratio of said first mean diameter to said second mean diameter is five to ten and the weight ratio of each of said first group and said second group to the total weight of spherical metal particles is in the range of 0.1 to 0.9.

Claim 9

A fluid that is pourable at ambient conditions in the absence of an applied magnetic field but has a yield stress in excess of 10 psi in an applied magnetic field one Tesla or more, said fluid comprising generally spherical, low coercivity, ferromagnetic or paramagnetic metal particles of particle sizes substantially in the range of one micron to 100 microns dispersed in a liquid vehicle with a dispersing agent, said particles consisting essentially of a first group of particles having a first range of diameter sizes with a first mean diameter having a standard deviation no greater than about two-thirds of the value of said first mean diameter and a second group of particles with a second range of diameter sizes and a second mean diameter having a standard deviation no greater than about two-thirds of the value of said mean diameter such that the ratio of said first mean diameter to said second mean diameter is five to ten and the weight ratio of each of said first group and said second group to the total weight of spherical metal particles is in the range of 0.1 to 0.9.

Claim 10

A fluid as recited in claim 7 where said particles are carbonyl iron particles and said first mean diameter is greater then seven microns and said second mean diameter is less than three microns.

Claim 11

A fluid as recited in claim 1 in which at least said first group of particles comprises surfactant coated carbonyl iron particles.

Claim 12

A fluid as recited in claim 1 in which said fluid additionally comprises particles of fumed silica.

Claim 13

A fluid as recited in claim 9 in which said fluid additionally comprises particles of fumed silica.

Claim 14

A magnetorheological fluid comprising low coercivity, generally spherical magnetic particles dispersed in a liquid vehicle, said particles consisting essentially of a first group of surfactant coated carbonyl iron particles having a first range of diameter sizes with a first mean diameter having a standard deviation no greater than about two-thirds of the value of said first mean diameter and a second group of particles with a second range of diameter sizes and a second mean diameter having a standard deviation no greater than about two-thirds of said second mean diameter, such that the major portion of all particle sizes fall within the range of one to 100 microns and the weight ratio of each of said first group and said second group to the total weight of said magnetic particles is in the range of 0.1 to 0.9, and the ratio of said first mean diameter to said second mean diameter is five to ten, said liquid vehicle comprising at least one liquid selected from the group consisting of a polyalphaolefin, an alkyl ester of a tall oil fatty acid, and dioctyl sebacate, and said fluid additionally comprising dispersed fumed silica.

Claim 15

A magnetorheological fluid comprising low coercivity, generally spherical magnetic particles dispersed in a liquid vehicle, said particles consisting essentially of a first group of surfactant coated carbonyl iron particles having a first range of diameter sizes with a first mean diameter having a standard deviation no greater than about two-thirds of the value of said first mean diameter and a second group of particles with a second range of diameter sizes and a second mean diameter having a standard deviation no greater than about two-thirds of said second mean diameter, such that the major portion of all particle sizes fall within the range of one to 100 microns and the weight ratio of each of said first group and said second group to the total weight of said magnetic particles is in the range of 0.1 to 0.9, and the ratio of said first mean diameter to said second mean diameter is five to ten, said liquid vehicle comprising at least one liquid selected from the group consisting of a polyalphaolefin, an alkyl ester of a tall oil fatty acid, and dioctyl sebacate, and said fluid additionally comprising dispersed fumed silica.